相关论文: Spin-Frustrated Pyrochlore Chains in the Volcanic …
The calculation of the sign and strength of magnetic interactions in two noncentrosymmetric minerals (klyuchevskite, K3Cu3(Fe0.82Al0.18)O2(SO4)4 and piipite, K4Cu4O2(SO4)4Cu0.5Cl) has been performed based on the structural data. As seen…
The objective of the present work was to analyze the possibility of realization of quantum spin liquid in three volcanic minerals - averievite (Cu5O2(VO4)2(CuCl)), ilinskite (NaCu5O2(SeO3)2Cl3), and avdononite (K2Cu5Cl8(OH)4 2H2O - from the…
Magnetic frustration, the competition among exchange interactions, often leads to novel magnetic ground states with unique physical properties which can hinge on details of interactions that are otherwise difficult to observe. Such states…
Spin-frustrated systems are one avenue for inducing macroscopic quantum states in materials. However, experimental realization of this goal has been difficult because of the lack of simple materials and, if available, the separation of the…
We show that pharmacosiderite is a novel cluster antiferromagnet comprising frustrated regular tetrahedra made of spin-5/2 Fe3+ ions that are arranged in the primitive cubic lattice. The connectivity of the tetrahedra and the inter-cluster…
The temperature dependent ac and dc magnetization and heat capacity data of Ca$_3$CoIrO$_6$, a spin-chain compound crystallizing in a K$_4$CdCl$_6$-derived rhombohedral structure, show the features due to magnetic ordering of a…
We present the crystal structure and magnetic properties of Y$_{3}$Cu$_{9}$(OH)$_{19}$Cl$_{8}$, a stoichiometric frustrated quantum spin system with slightly distorted kagome layers. Single crystals of Y$_{3}$Cu$_{9}$(OH)$_{19}$Cl$_{8}$…
We present a microscopic magnetic model for the spin-liquid candidate volborthite Cu3V2O7(OH)2(H2O)2. The essentials of this DFT-based model are (i) the orbital ordering of Cu(1) 3d 3z2-r2 and Cu(2) 3d 3x2-y2, (ii) three relevant couplings…
Geometric frustration inhibits magnetic systems from ordering, opening a window to unconventional phases of matter. The paradigmatic frustrated lattice in three dimensions to host a spin liquid is the pyrochlore, although there remain few…
A structural-magnetic models of the orthorhombic and triclinic modifications of the arsenates Cu4O(AsO4)2 and isotypic phosphates Cu4O(PO4)2 has been built and analyzed. Their base elements are the complicated ribbons composed of…
Different from other magnetically frustrated spinel systems, GeCu$_{2}$O$_{4}$ is a strongly tetragonal distorted spinel cuprate in which edge-sharing CuO$_{2}$ ribbons are running along alternating directions perpendicular to the $c$-axis.…
Here we report crystallographic and magnetic studies on high quality samples of the magnetically frustrated S = 1/2 kagome antiferromagnet vesignieite, BaCu3V2O8(OD)2. Powder neutron diffraction data collected from samples obtained by a new…
In this joint experimental and theoretical work magnetic properties of the Cu$^{2+}$ mineral szenicsite Cu$_3$(MoO$_4$)(OH)$_4$ are investigated. This compound features isolated triple chains in its crystal structure, where the central…
We analyzed the magnetic susceptibilities of several Cr spinels using two recent models for the geometrically frustrated pyrochlore lattice, the Quantum Tetrahedral Mean Field model and a Generalized Constant Coupling model. Both models can…
We report the crystal growth, crystal structure and basic magnetic properties of a new cobalt-based pyrochlore, NaSrCo$_2$F$_7$. Na and Sr are completely disordered on the non-magnetic large atom A sites, while magnetic S=3/2 Co$^{2+}$…
The crystal structure of the copper(II) tellurium(IV) oxochloride Cu$_{4}$Te$_{5}$O$_{12}$Cl$_{4}$ (Cu-45124) is composed of weakly coupled tetrahedral Cu clusters and shows crystallographic similarities with the intensively investigated…
In frustrated magnetic systems, the competition amongst interactions can introduce extremely high degeneracy and prevent the system from readily selecting a unique ground state. In such cases, the magnetic order is often exquisitely…
Neutron diffraction on the double perovskite Sr2YRuO6 with a quasi-face-centered cubic (FCC) lattice of Ru moments reveals planar magnetic correlations that condense into a partial long-range ordered state with coupled alternate…
Pyrochlore lattices, which are found in two important classes of materials -- the $A_2B_2X_7$ pyrochlore family and the $AB_2X_4$ spinel family -- are the quintessential 3-dimensional frustrated lattice architecture. While historically…
We report the magnetic characterization of the frustrated transition metal pyrochlore NaCaCo$_2$F$_7$. This material has high spin Co$^{2+}$ in CoF$_6$ octahedra in a pyrochlore lattice, and disordered non-magnetic Na and Ca on the…