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Transition of molecular hydrogen to atomic ionized state with increase of temperature and pressure poses still unresolved problems for experimental methods and theory. Here we analyze the dynamics of this transition and show its…

材料科学 · 物理学 2020-03-25 Ilya D. Fedorov , Nikita D. Orekhov , Vladimir V. Stegailov

The first-principle method of mathematical modeling was used to calculate the structural, electronic, phonon, and other characteristics of the normal metallic phase of hydrogen at a pressure of 500 GPa. It has been shown that metal hydrogen…

超导电性 · 物理学 2016-07-06 Nikolay Degtyarenko , Evgeny Mazur

The Meissner effect, magnetic field expulsion, is a hallmark of superconductivity. Associated with it, superconductors exclude applied magnetic fields. Recently Minkov et al. presented experimental results reportedly showing "definitive…

超导电性 · 物理学 2022-07-21 J. E. Hirsch , F. Marsiglio

Two new phases of hydrogen have been discovered at room temperature in Ref.1: phase IV above 220 GPa and phase V above ~270 GPa. In the present work we have found a new phase VI at P~360 GPa and T<200 K. This phase is likely metallic as…

材料科学 · 物理学 2016-01-19 M. I. Eremets , I. A. Troyan , A. P. Drozdov

Hydrogen exhibits unusual behaviors at megabar pressures, with consequences for planetary science, condensed matter physics and materials science. Experiments at such extreme conditions are challenging, often resulting in hard-to-interpret…

材料科学 · 物理学 2022-01-05 Bingqing Cheng , Guglielmo Mazzola , Michele Ceriotti

Liquid atomic metallic hydrogen is the simplest, lightest, and most abundant of all liquid metals. The role of nucleon motions or ion dynamics has been somewhat ignored in relation to the dissociative insulator-metal transition. Almost all…

其他凝聚态物理 · 物理学 2018-09-12 Mohamed Zaghoo , Rachel Husband , Isaac F. Silvera

Hydrogen-rich compounds have been extensively studied both theoretically and experimentally in the quest for novel high-temperature superconductors. Reports on sulfur-hydride attaining metallicity under pressure and exhibiting…

Recently, several research groups announced reaching the point of metallization of hydrogen above 400 GPa. Following the mainstream of extensive investigations of compressed polyhydrides, in this work we demonstrate that small (4 atom %)…

Due to its low atomic mass hydrogen is the most promising element to search for high-temperature phononic superconductors. However, metallic phases of hydrogen are only expected at extreme pressures (400 GPa or higher). The measurement of a…

超导电性 · 物理学 2016-03-23 José A. Flores-Livas , Antonio Sanna , E. K. U. Gross

Since the discovery of superconductivity at 200 K in H3S [1] similar or higher transition temperatures, Tcs, have been reported for various hydrogen-rich compounds under ultra-high pressures [2]. Superconductivity was experimentally proved…

Ab initio random structure searching with density functional theory was used to determine the zero-temperature structures of atomic metallic hydrogen from 500 GPa to 5 TPa. Including zero point motion in the harmonic approximation, we…

材料科学 · 物理学 2015-05-20 Jeffrey M. McMahon , David M. Ceperley

Noble metals adopt close-packed structures at ambient pressure and rarely undergo structural transformation at high pressures. Platinum (Pt), in particular, is normally considered to be unreactive and is therefore not expected to form…

超导电性 · 物理学 2015-03-19 Duck Young Kim , Ralph H. Scheicher , Chris J. Pickard , R. J. Needs , R. Ahuja

The search for room-temperature superconducting materials has been at the center of modern research for decades. The recent discovery of high-temperature superconductivity, under extreme pressure in hydrogen-rich materials, is a tremendous…

超导电性 · 物理学 2021-07-27 Theja N. De Silva

Re-entrant melting (in which a substance's melting point starts to decrease beyond a certain pressure) is believed to be an unusual phenomenon. Among the elements, it has so far only been observed in a very limited number of species, e.g.,…

材料科学 · 物理学 2020-05-06 Qi-Jun Hong , Axel van de Walle

Recent experimental developments in hydrogen-rich materials in high pressures have put this class of materials above others in the race toward room temperature superconductivity. As it is the basis of all the materials in this class, the…

超导电性 · 物理学 2022-02-03 Mehmet Dogan , Sehoon Oh , Marvin L. Cohen

Hydrogen sulfide (H2S) is a prototype molecular system and a sister molecule of water. The phase diagram of solid H2S at high pressures remains largely unexplored arising from the challenges in dealing with the looser S-H bond and larger…

超导电性 · 物理学 2015-03-26 Yinwei Li , Jian Hao , Yanling Li , Yanming Ma

Being the simplest element with just one electron and proton the electronic structure of the Hydrogen atom is known exactly. However, this does not hold for the complex interplay between them in a solid and in particular not at high…

材料科学 · 物理学 2014-06-23 Sam Azadi , Thomas D. Kühne

In their paper arXiv:2405.08189, Supercond. Sci. Technol. 37 (2024) 065010 [1], Bud'ko et al. present experimental results for trapped magnetic flux for a tiny sample of a type II superconductor. The paper aims to provide evidence in…

超导电性 · 物理学 2025-04-17 J. E. Hirsch , F. Marsiglio

The preceding Comment [1], previously posted as arXiv:2312.04495 [2], on our paper J. Supercond. Nov. Mag. 35, 3141 (2022) [3] provides a welcome opportunity to clarify what we understand to be pervading misconceptions by Eremets, Minkov…

超导电性 · 物理学 2024-12-10 J. E. Hirsch , F. Marsiglio

Recent dynamic compression experiments [M. D. Knudson et al., Science 348, 1455 (2015); P. M. Celliers et al., Science 361, 677 (2018)] have observed the insulator-metal transition in dense liquid deuterium, but with an approximately 95 GPa…

材料科学 · 物理学 2020-04-01 M. P. Desjarlais , M. D. Knudson , R. Redmer