相关论文: Exploring molecular complexity with ALMA (EMoCA): …

The detection of a branched alkyl molecule in the high-mass star forming protocluster Sgr B2(N) permitted by the advent of ALMA revealed a new dimension of interstellar chemistry. Astrochemical simulations subsequently predicted that beyond…

Straight-chain (normal-propyl cyanide, n - C3H7CN) and branched-chain (iso-propyl cyanide, i - C3H7CN) alkyl cyanides are recently identified in the massive star-forming regions (Sgr B2(N) and Orion). These branched-chain molecules indicate…

We used the EMoCA survey data to search for isocyanides in Sgr B2(N2) and their corresponding cyanide analogs. We then used the coupled three-phase chemical kinetics code MAGICKAL to simulate their chemistry. Several new species, and over…

In recent years, organic molecules of increasing complexity have been found toward the prolific Galactic center source Sagittarius B2. We wish to explore the degree of complexity that the interstellar chemistry can reach in star-forming…

The search for complex organic molecules (COMs) in the ISM has revealed chemical species of ever greater complexity. This search relies heavily on the progress made in the laboratory to characterize the rotational spectra of these…

Numerous complex organic molecules have been detected in the universe among which amides are considered as models for species containing the peptide linkage. Acrylamide bears in its backbone not only the peptide bond, but also the vinyl…

The largest non-cyclic molecules detected in the interstellar medium (ISM) are organic with a straight-chain carbon backbone. We report an interstellar detection of a branched alkyl molecule, iso-propyl cyanide (i-C3H7CN), with an abundance…

We used ALMA to perform a line survey of the high-mass star forming region Sgr B2(N), called ReMoCA. We modeled under the assumption of LTE the spectra obtained toward the sources embedded in the secondary hot core Sgr B2(N2). We compared…

Over the past five decades, radio astronomy has shown that molecular complexity is a natural outcome of interstellar chemistry, in particular in star forming regions. However, the pathways that lead to the formation of complex molecules are…

The saturated n-propyl cyanide was recently detected in Sagittarius B2(N). The next larger unbranched alkyl cyanide is n-butyl cyanide. We provide accurate rest frequency predictions beyond the millimeter wave range to search for this…

We report the first spectroscopic detection of ethyl cyanide (C$_2$H$_5$CN) in Titan's atmosphere, obtained using spectrally and spatially resolved observations of multiple emission lines with the Atacama Large Millimeter/submillimeter…

Complex organic molecules are readily detected in the inner regions of the gaseous envelopes of forming protostars. In particular, molecules that contain nitrogen are interesting due to the role nitrogen plays in the development of life and…

The studies of the complex organic molecular lines towards the hot molecular cores at millimeter and submillimeter wavelengths provide instructive knowledge about the chemical complexity in the interstellar medium (ISM). We present the…

Deuteration is a powerful tracer of the history of the cold prestellar phase in star forming regions. Apart from methanol, little is known about deuterium fractionation of complex organic molecules in the interstellar medium, especially in…

Linear carbon chains are common in various types of astronomical molecular sources. Possible formation mechanisms involve both bottom-up and top-down routes. We have carried out a combined observational and modeling study of the formation…

The peptide-like molecules, cyanoformamide (NCCONH2), is the cyano (CN) derivative of formamide (NH2CHO). It is known to play a role in the synthesis of nucleic acid precursors under prebiotic conditions. In this paper, we present a…

The rotational line survey by ALMA (Atacama Large Millimeter/submillimeter Array) recently revealed the presence of i-C3H7CN (i-PrCN) and n-C3H7CN (n-PrCN) in 3-mm atmospheric window between 84 to 111 GHz towards the hot core region…

Observations of chemical species can provide an insight into the physical conditions of the emitting gas but it is important to understand how their abundances and excitation vary within different heating environments. C$_2$H is a molecule…

Acetamide (CH$_{3}$CONH$_{2}$), a key interstellar amide and a methyl derivative of formamide (NH$_{2}$CHO), has been sparsely detected, limiting insights into its prebiotic relevance. We present the first systematic survey for acetamide…

Amines, in particular primary amines (R-NH$_2$) are closely related to the primordial synthesis of amino acids since they share the same structural backbone. However, only limited number of amines has been identified in the ISM which…