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The superconducting pyrochlore oxide Cd2Re2O7 (Tc = 1 K), which is now considered as a candidate of the spin-orbit-coupled metal, shows an inversion-symmetry-breaking structural transition at Ts1 = 200 K. Ts1 decreases with increasing…

强关联电子 · 物理学 2018-04-30 Yasuhito Matsubayashi , Takumi Hasegawa , Norio Ogita , Jun-ichi Yamaura , Zenji Hiroi

The 5d pyrochlore oxide superconductor Cd2Re2O7 (CRO) has attracted significant interest as a spin-orbit-coupled metal (SOCM) that spontaneously undergoes a phase transition to an odd-parity multipole phase by breaking the spatial inversion…

强关联电子 · 物理学 2023-09-18 Daigorou Hirai , Atsuhito Fukui , Hajime Sagayama , Takumi Hasegawa , Zenji Hiroi

The superconducting pyrochlore oxide Cd2Re2O7 shows a structural transition with inversion symmetry breaking (ISB) at Ts1 = 200 K. A recent theory [L. Fu, Phys. Rev. Lett. 115, 026401 (2015)] suggests that the origin is an electronic…

Superconducting and structural phase transitions in a pyrochlore oxide Cd2Re2O7 are studied under high pressure by x-ray diffraction and electrical resistivity measurements. A rich P-T phase diagram is obtained, which contains at least two…

The pyrochlore oxide Pb2Re2O7-{\delta} (PRO) is a candidate spin-orbit-coupled metal (SOCM) that exhibits a structural phase transition with inversion symmetry breaking. In this study, we report the results of detailed X-ray diffraction…

We report a structural phase transition found at Ts = 200 K in a pyrochlore oxide Cd2Re2O7 which shows superconductivity at Tc = 1.0 K. X-ray diffractionexperiments indicate that the phase transition is of the second order, from a…

超导电性 · 物理学 2009-11-07 M. Hanawa , J. Yamaura , Y. Muraoka , F. Sakai , Z. Hiroi

Evidence for another phase transition at 120 K in the metallic pyrochlore oxide Cd2Re2O7, following the structural transition at 200 K and followed by the superconducting transition at 1.0 K, is given through resistivity, magnetoresistance,…

强关联电子 · 物理学 2009-11-07 Zenji Hiroi , Jun-Ichi Yamaura , Yuji Muraoka , Masafumi Hanawa

The superconducting pyrochlore oxide Cd2Re2O7 is revisited with a particular emphasis on the sample-quality issue. The compound has drawn attention as the only superconductor (Tc = 1.0 K) that has been found in the family of…

We report a density-functional theory study of the structural and electronic properties of Cd2V2O7 under high-pressure conditions. The calculations have been performed by using first-principle calculations with the CRYSTAL program. The…

材料科学 · 物理学 2022-05-23 Daniel Diaz-Anichtchenko , Daniel Errandonea

Iridium-based 5d transition-metal oxides are attractive candidates for the study of correlated electronic states due to the interplay of enhanced crystal-field, Coulomb and spin-orbit interaction energies. At ambient pressure, these…

The high pressure structural properties of bismuth oxide Bi2SiO5 have been investigated up to 28 GPa using in situ powder synchrotron X-ray diffraction and up to 50 GPa with DFT calculations. The monoclinic structure is found to persist up…

The spin-orbit Mott insulator Sr3Ir2O7 provides a fascinating playground to explore insulator-metal transition driven by intertwined charge, spin, and lattice degrees of freedom. Here, we report high pressure electric resistance and…

We study the structural evolution of Sr$_3$Ir$_2$O$_7$ as a function of pressure using x-ray diffraction. At a pressure of 54 GPa at room temperature, we observe a first-order structural phase transition, associated with a change from…

Tb2Ti2O7, a pyrochlore system, has garnered significant interest due to its intriguing structural and physical properties and their dependence on external physical parameters. In this study, utilizing high-brilliance synchrotron X-ray…

Single crystal X-ray diffraction measurements have been carried out on Cd_2Re_2O_7 near and below the phase transition it exhibits at Tc' ~195 K. Cd_2Re_2O_7 was recently discovered as the first, and to date only, superconductor with the…

强关联电子 · 物理学 2009-11-07 J. P. Castellan , B. D. Gaulin , J. van Duijn , M. J. Lewis , M. D. Lumsden , R. Jin , J. He , S. E. Nagler , D. Mandrus

Rattling-induced superconductivity in the {\beta}-pyrochlore oxide KOs2O6 is investigated under high pressure up to 5 GPa. Resistivity measurements in a high-quality single crystal reveal a gradual decrease in the superconducting transition…

High-pressure x-ray absorption spectroscopy was performed at the Ir $L_3$ and $L_2$ absorption edges of Sr$_3$Ir$_2$O$_7$. The branching ratio of white line intensities continuously decreases with pressure, reflecting a reduction in the…

We study \textit{ab initio} a pyrochlore compound, CsW$_{2}$O$_{6}$, which exhibits a yet unexplained metal-insulator transition. We find that (1) the reported low-$T$ structure is likely inaccurate and the correct structure has a twice…

超导电性 · 物理学 2017-01-10 S. V. Streltsov , I. I. Mazin , R. Heid , K. -P. Bohnen

The 5d pyrochlore oxide Cd2Re2O7 exhibits successive phase transitions from a cubic pyrochlore structure (phase I) to a tetragonal structure without inversion symmetry below Ts1 of ~200 K (phase II) and further to another noncentrosymmetric…

Strong electron interactions can drive metallic systems toward a variety of well-known symmetry-broken phases, but the instabilities of correlated metals with strong spin-orbit coupling have only recently begun to be explored. We uncovered…

强关联电子 · 物理学 2017-04-26 J. W. Harter , Z. Y. Zhao , J. -Q. Yan , D. G. Mandrus , D. Hsieh
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