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Long-range macrodimers formed by D-state cesium Rydberg atoms are studied in experiments and in calculations. Cesium 62DJ-62DJ Rydberg-atom macrodimers, bonded via long-range multipole interaction, are prepared by two-color…

We report the observation of cold Cs Rydberg atom molecules bound at internuclear separations of R~3-9 um. The bound states result from avoided crossings between Rydberg atom pair interaction potentials in an applied electric field. The…

Controlling molecular binding at the level of single atoms is one of the holy grails of quantum chemistry. Rydberg macrodimers -- bound states between highly excited Rydberg atoms -- provide a novel perspective in this direction. Resulting…

原子物理 · 物理学 2023-06-14 Simon Hollerith , Johannes Zeiher

We present an overview of our recent investigations of long-range interactions in an ultracold Cs Rydberg gas. These interactions are studied by high-resolution photoassociation spectroscopy, using excitation close to one-photon transitions…

原子物理 · 物理学 2016-07-15 Heiner Saßmannshausen , Johannes Deiglmayr , Frédéric Merkt

The coupling of an isolated quantum state to a continuum is typically associated with decoherence and decreased lifetime. Here, we demonstrate that Rydberg macrodimers, weakly bound pairs of Rydberg atoms, can overcome this dissipative…

We consider ultralong-range polyatomic Rydberg molecules formed by combining a Rydberg cesium atom and a ground-state RbCs molecule. We explore the regime where the charge-dipole interaction due to the Rydberg electron with the diatomic…

A microscopic understanding of molecules is essential for many fields of natural sciences but their tiny size hinders direct optical access to their constituents. Rydberg macrodimers - bound states of two highly-excited Rydberg atoms -…

We propose a novel type of Rydberg dimer, consisting of a Rydberg-state atom bound to a distant positive ion. The molecule is formed through long-range electric-multipole interaction between the Rydberg atom and the point-like ion. We…

原子物理 · 物理学 2021-05-14 A. Duspayev , X. Han , M. A. Viray , L. Ma , J. Zhao , G. Raithel

The internal electric field of a Rydberg atom electron can bind a polar molecule to form a giant ultralong-range stable polyatomic molecule. Such molecules not only share their properties with Rydberg atoms, they possess huge permanent…

原子物理 · 物理学 2015-05-27 Seth T. Rittenhouse , M. Mayle , P. Schmelcher , H. R. Sadeghpour

We propose a new approach to excite ion-pair states of ultracold dimers. The central idea is a two-step process where first long-range Rydberg molecules are formed by photoassociation, which are then driven by stimulated emission towards…

原子物理 · 物理学 2020-02-25 Michael Peper , Johannes Deiglmayr

We observe ultralong-range blue-shifted Cs$_{2}$ molecular states near $ns_{1/2}$ Rydberg states in an optical dipole trap, where $31\leq n\leq34$. The accidental near degeneracy of $(n-4)l$ and $ns$ Rydberg states for $l>2$ in Cs, due to…

原子物理 · 物理学 2015-06-05 J. Tallant , S. T. Rittenhouse , D. Booth , H. R. Sadeghpour , J. P. Shaffer

We predict the existence of a class of ultracold giant molecules formed from trapped ultracold Rydberg atoms and polar molecules. The interaction which leads to the formation of such molecules is the anisotropic charge-dipole interaction…

原子物理 · 物理学 2015-05-18 Seth T. Rittenhouse , H. R. Sadeghpour

Long-range $(n+2)D_{5/2} \, nF_J$ Rydberg macro-dimers are observed in an ultracold cesium Rydberg gas for $39\leq n\leq48$. Strong dipolar "flip" ($\langle D_{5/2} F_{5/2} \vert \hat{V}_{dd} \vert F_{5/2} D_{5/2} \rangle$, $\langle D_{5/2}…

原子物理 · 物理学 2024-11-05 Jingxu Bai , Yuechun Jiao , Rong Song , Georg Raithel , Suotang Jia , Jianming Zhao

Pulsed laser excitation of a dense ultracold Cs vapor has been used to study the pairwise interactions between Cs atoms excited to $n$p$_{3/2}$ Rydberg states of principal quantum numbers in the range $n=22-36$. Molecular resonances were…

原子物理 · 物理学 2015-09-14 Heiner Saßmannshausen , Frédéric Merkt , Johannes Deiglmayr

The ability to control and tune interactions in ultracold atomic gases has paved the way towards the realization of new phases of matter. Whereas experiments have so far achieved a high degree of control over short-ranged interactions, the…

Sufficiently high densities in Bose-Einstein condensates provide favorable conditions for the production of ultralong-range polyatomic molecules consisting of one Rydberg atom and a number of neutral ground state atoms. The chemical binding…

原子物理 · 物理学 2017-05-10 Matthew T Eiles , Jesus Perez-Rios , F Robicheaux , Chris H Greene

Cs$_2$ Rydberg-ground molecules consisting of a Rydberg, $nD_{J}$ (33 $\leq$ $n$ $\leq$ 39), and a ground state atom, 6$S_{1/2} (F=$3 or 4$)$, are investigated by photo-association spectroscopy in a cold atomic gas. We observe vibrational…

原子与分子团簇 · 物理学 2020-10-07 Suying Bai , Xiaoxuan Han , Jingxu Bai , Yuechun Jiao , Jianming Zhao , Suotang Jia , Georg Raithel

We study long range interactions between two Rydberg atoms and predict the existence of ultralong range Rydberg dimers with equilibrium distances of many thousand Bohr radii. We calculate the dispersion coefficients $C_{5}$, $C_{6}$ and…

原子物理 · 物理学 2009-11-07 Christophe Boisseau , Ionel Simbotin , Robin Cote

We investigate the interaction between two rubidium atoms in highly excited Rydberg states, and find that very long-range potential wells exist. These wells are shown to support many bound states. We calculate the properties of the wells…

原子物理 · 物理学 2011-03-30 Nolan Samboy , Jovica Stanojevic , Robin Côté

Precise control and study of molecules is challenging due to the variety of internal degrees of freedom and local coordinates that are typically not controlled in an experiment. Employing quantum gas microscopy to position and resolve the…

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