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Kinetics of phase decomposition accompanied by precipitation of sigma-phase in a Fe73.7Cr26.3 alloy isothermally annealed at 832 K was studied by means of M\"ossbauer spectroscopy. Two stage decomposition process has been revealed by three…

材料科学 · 物理学 2019-11-01 Stanisław M. Dubiel , Jan Żukrowski

Concentration of Cr in the Fe-rich alpha-phase, x, resulted from a phase decomposition caused by an isothermal annealing at T = 415 and 450 C of a non-irradiated (NR) Fe-Cr14 EFDA sample and that of a He-ions irradiated (IR) one annealed at…

材料科学 · 物理学 2013-07-05 S. M. Dubiel , J. Zukrowski

The study was aimed at determination of the position of the Fe-rich border of the metastable miscibility gap (MMG) and of the solubility limit of Cr in iron at 858 K. Towards this end a Fe73.7Cr26.3 alloy was isothermally annealed at 858 K…

材料科学 · 物理学 2023-06-14 Stanisław M. Dubiel , Jan Żukrowski

A Fe89.15Cr10.75 alloy in a heavily strained (by cold rolling) and strain-relaxed states was studied by means of the conversion electrons M\"ossbauer spectroscopy (CEMS). Analysis of the spectra in terms of a two-shell model revealed…

材料科学 · 物理学 2017-11-23 S. M. Dubiel , J. Zukrowski

A redistribution of Cr atoms related to a phase decomposition (PD) caused by an isothermal annealing at 415 C in a 15.15 at%Cr Fe-Cr alloy was studied in an ex-situ way by the conversion electrons M\"ossbauer spectroscopy. Analysis of the…

材料科学 · 物理学 2013-08-23 Stanislaw M. Dubiel , Jan Zukrowski

Segregation, precipitation, and phase separation in Fe-Cr systems is investigated. Monte Carlo simulations using semiempirical interatomic potential, first-principles total energy calculations, and experimental spectroscopy are used. In…

Effect of He ion irradiation on three model Fe(100-x)Cr(x) alloys (x =5.8, 10.75 and 15.15) was investigated with the conversion electron M\"ossbauer spectroscopy. The study of the alloys irradiated with 25 keV ions revealed that the…

材料科学 · 物理学 2014-11-21 S. M. Dubiel , J. Cieslak , H. Reuther

Iron-pnictides Ca(Fe1-xRhx)2As2 (x = 0, 0.035, and 0.19) were studied across the tetragonal-orthorhombic and uncollapsed to collapsed tetragonal phase transitions using Raman spectroscopy. The effect of the phase separation was observed in…

超导电性 · 物理学 2023-08-21 V. P. Gnezdilov , A. Yu. Glamazda , P. Lemmens , K. Kudo , M. Nohara

57Fe Mossbauer spectroscopy was used to perform a microscopic study on the extremely pressure and strain sensitive compound, CaFe2As2, with different degrees of strain introduced by grinding and annealing. At the base temperature, in the…

材料科学 · 物理学 2015-08-13 Xiaoming Ma , Sheng Ran , Paul C. Canfield , Sergey L. Bud'ko

Fe-gluconate was studied by means of the M\"ossbauer spectroscopy in the temperature interval of 80-305K. The measured spectra were analyzed in terms of two subspectra and, alternatively, two distributions of the quadrupole splitting. The…

材料科学 · 物理学 2016-03-01 S. M. Dubiel , J. Cieslak

Issues pertinent to the miscibility gap at 800K in a Fe73.7Cr26.3 alloy viz. the kinetics of the phase decomposition and borders of the latter were investigated by means of the M\"ossbauer-effect spectroscopy. The kinetics was revealed to…

材料科学 · 物理学 2018-11-30 Stanislaw M. Dubiel , Jan Zukrowski

Fe-Cr binary alloys serve as simplified model systems to study irradiation damage relevant to fusion structural materials. Here, Fe-3%Cr and Fe-5%Cr samples were irradiated with 4 MeV Fe ions under a dose rate of 4x10^5 dpa/s across a…

Two intermetallic FeAl compounds with Al content of 70.68 and 72.17 at.pct were studied using M\"ossbauer spectroscopy (5 to 296 K) and X-ray diffraction (15 to 300 K). The compounds were found to crystallize in the orthorhombic Cmcm space…

材料科学 · 物理学 2021-05-19 Stanisław M. Dubiel , Łukasz Gondek , Tilo Zienert , Jan Żukrowski

A series on nanocrystalline Fe100-xCrx alloys prepared by mechanical alloying was investigated with X-ray diffraction (XRD), scanning electron microscopy (SEM) and M\"ossbauer spectroscopy (MS) techniques. XRD and SEM were used to…

强关联电子 · 物理学 2015-08-10 S. M. Dubiel , B. F. O. Costa , J. Cieslak , A. C. Batista

Applications of the M\"ossbauer spectroscopy (MS) in the investigation of Fe-Cr alloys are reviewed. A high sensitivity of the hyperfine magnetic field to the presence of Cr atoms in the vicinity of the probe Fe atoms permits quantitative…

材料科学 · 物理学 2023-11-21 Stanislaw M. Dubiel

This work gives insights into processing and characterisation of bulk nanocrystalline FeCr materials. The investigated FeCr alloys, consisting of 30, 50 and 70 at.% ferromagnetic Fe and remaining anti-ferromagnetic Cr, are processed by arc…

This work is motivated by the need for large-scale simulations to extract physical information on the iron-chromium system that is a binary model alloy for ferritic steels used or proposed in many nuclear applications. From first-principles…

Experimental investigation as well as theoretical calculations, of the Fe-partial phonon density-of-states (DOS) for nominally Fe_52.5Cr_47.5 alloy having (a) alpha- and (b) sigma-phase structure were carried out. The former at sector 3-ID…

材料科学 · 物理学 2015-05-14 S. M. Dubiel , J. Cieslak , W. Sturhahn , M. Sternik , P. Piekarz , S. Stankov , K. Parlinski

57Fe-M\"ossbauer studies of superconducting Rb0.8Fe1.6Se2.0 with TC = 32.4 K were performed on single-crystalline and polycrystalline samples in the temperature range 4.2 K to 295 K. They reveal the presence of 88% magnetic and 12%…

超导电性 · 物理学 2011-08-16 V. Ksenofontov , G. Wortmann , S. Medvedev , V. Tsurkan , J. Deisenhofer , A. Loidl , C. Felser

X-ray diffraction (XRD) and M\"ossbauer spectroscopy techniques combined with theoretical calculations based on the Korringa-Kohn-Rostoker (KKR) electronic structure calculation method were used to investigate \sigma-phase Fe_{100-x}Re_{x}…

材料科学 · 物理学 2014-09-18 J. Cieslak , S. M. Dubiel , J. Zukrowski , J. Tobola
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