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The fundamental role of hydrophobic interactions in nature and technology has motivated decades long research aimed at measuring the distance-dependent hydrophobic force and identifying its origin. This quest has nevertheless proved more…

软凝聚态物质 · 物理学 2016-03-29 Itai Schlesinger , Uri Sivan

The long range attractive force between two hydrophobic surfaces immersed in water is observed to decrease exponentially with their separation -- this distance-dependence of effective force is known as the hydrophobic force law (HFL). We…

软凝聚态物质 · 物理学 2015-06-24 Saikat Banerjee , Rakesh S. Singh , Biman Bagchi

Liquid water, at ambient conditions, has short-range density correlations which are well known in literature. Surprisingly, large scale molecular dynamics simulations reveal an unusually long-distance correlation in `longitudinal' part of…

软凝聚态物质 · 物理学 2013-05-29 J. M. Pradeep Kanth , Satyavani Vemparala , Ramesh Anishetty

Thermodynamics tells us to expect underwater contact between two hydrophobic surfaces to result in stronger adhesion compared to two hydrophilic surfaces. However, presence of water changes not only energetics, but also the dynamic process…

软凝聚态物质 · 物理学 2022-11-22 Mengyue Sun1 , Nityanshu Kumar1 , Ali Dhinojwala , Hunter King

The properties of liquid water are known to change drastically in confined geometries. A most interesting and intriguing phenomenon is that the diffusion of water is found to be strongly enhanced by the proximity of a hydrophobic confining…

软凝聚态物质 · 物理学 2024-12-06 Lorenzo Agosta , Kersti Hermansson , Mikhail Dzugutov

We present a probabilistic approach to water-water hydrogen bonding that allows one to obtain an analytic expression for the number of bonds per water molecule as a function of both its distance to a hydrophobic particle and hydrophobe…

软凝聚态物质 · 物理学 2013-03-20 Yuri S. Djikaev , Eli Ruckenstein

We examine the effective force between two nanometer scale solutes in water by Molecular Dynamics simulations. Macroscopic considerations predict a strong reduction of the hydrophobic attraction between solutes when the latter are charged.…

统计力学 · 物理学 2009-11-10 J. Dzubiella , J. -P. Hansen

We present results from extensive molecular dynamics simulations of collapse transitions of hydrophobic polymers in explicit water focused on understanding effects of lengthscale of the hydrophobic surface and of attractive interactions on…

统计力学 · 物理学 2007-05-23 Manoj V. Athawale , Gaurav Goel , Tuhin Ghosh , Thomas M. Truskett , Shekhar Garde

We use molecular simulations to demonstrate the connection between transverse water-water correlations and wetting phenomena for a range of hydrophobic to hydrophilic solid surfaces.Near superhydrophobic surfaces, the correlations are long…

软凝聚态物质 · 物理学 2014-09-10 Rahul Godawat , Sumanth N. Jamadagni , Vasudevan Venkateshwaran , Shekhar Garde

We calculate analytically the forces between two solvophobic solutes, considering a model system. We show that the effective interaction forces between two solvophobic solutes, mediated by the solvent, is attractive for short ranges, which…

软凝聚态物质 · 物理学 2015-06-01 J. Chakrabarti , Suman Dutta

The physics of air-water interfaces plays a central role in modern theories of the hydrophobic effect. Implementing these theories, however, has been hampered by the difficulty of addressing fluctuations in the shape of such soft…

统计力学 · 物理学 2016-05-27 Suriyanarayanan Vaikuntanathan , Phillip L Geissler

Flagellated bacteria are hydrodynamically attracted to rigid walls, yet past work shows a 'hovering' state where they swim stably at a finite height above surfaces. We use numerics and theory to reveal the physical origin of hovering.…

生物物理 · 物理学 2024-09-17 Pyae Hein Htet , Debasish Das , Eric Lauga

We report results of investigations of a high-speed drainage of thin aqueous films squeezed between randomly nanorough surfaces. A significant decrease in hydrodynamic resistance force as compared with predicted by Taylor's equation is…

软凝聚态物质 · 物理学 2009-11-11 Olga I. Vinogradova , Gleb E. Yakubov

We investigate the curvature-dependence of water dynamics in the vicinity of hydrophobic spherical solutes using molecular dynamics simulations. For both, the lateral and perpendicular diffusivity as well as for H-bond kinetics of water in…

软凝聚态物质 · 物理学 2016-01-22 R. Gregor Weiß , Matthias Heyden , Joachim Dzubiella

We analyze theoretically a high-speed drainage of liquid films squeezed between a hydrophilic sphere and a textured super-hydrophobic plane, that contains trapped gas bubbles. A super-hydrophobic wall is characterized by parameters $L$…

流体动力学 · 物理学 2014-01-23 Evgeny S. Asmolov , Aleksey V. Belyaev , Olga I. Vinogradova

The long-range contribution to dispersion forces is known to have a major impact on the properties of inhomogeneous fluids, and its correct treatment is increasingly recognized as being a necessary requirement to avoid cutoff-related…

软凝聚态物质 · 物理学 2016-12-13 Marcello Sega , Christoph Dellago

The hydrophobic interaction, often combined with the hydrophilic or ionic interactions, makes the behavior of aqueous solutions very rich and plays an important role in biological systems. Theoretical and computer simulation studies haven…

软凝聚态物质 · 物理学 2024-11-05 Hidefumi Naito , Tomonari Sumi , Kenichiro Koga

When a high voltage is applied between two beakers filled with deionized water, a bridge of water may be formed in between exceeding the length of 2 cm when the beakers are pulled apart. We construct experiments in which the geometry and…

流体动力学 · 物理学 2013-09-27 Reza Montazeri Namin , Ahmad Amjadi , Shiva Azizpour Lindi , Nima Jafari , Peyman Irajizad

We report results of direct measurements of velocity profiles in a microchannel with hydrophobic and hydrophilic walls, using a new high precision method of double-focus spacial fluorescence cross-correlation under a confocal microscope. In…

软凝聚态物质 · 物理学 2009-11-13 Olga I. Vinogradova , Kaloian Koynov , Andreas Best , François Feuillebois

Fish swimming style and schooling behaviour are two important aspects of underwater locomotion. How swimming style affects fish schooling is investigated by a representative problem setup consisting of two tethered NACA0012 hydrofoils…

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