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The long-range electrostatic interactions between molecules depend strongly on their relative orientation, which manifests as a rotational state dependence. Interactions between molecules in the same rotational quantum state are well-known…

原子物理 · 物理学 2024-05-16 Etienne F. Walraven , Tijs Karman

The paper discusses a model of Van der Waals crystals in which band-gap structures do not form. An effect of strong and chaotic electron-electron repulsion, which was excluded from consideration in the traditional approach, is taken into…

超导电性 · 物理学 2007-05-23 V. N. Bogomolov

We study the shift of rotational levels of a diatomic polar molecule due to its van der Waals (vdW) interaction with a gently curved dielectric surface at temperature $T$, and submicron separations. The molecule is assumed to be in its…

量子物理 · 物理学 2016-08-18 Giuseppe Bimonte , Thorsten Emig , Robert L. Jaffe , Mehran Kardar

Alkaline-earth-like transition-metal atoms such as Zn and Cd are promising candidates for precision measurements and quantum many-body physics experiments. Here, we theoretically investigate the properties of diatomic molecules containing…

原子物理 · 物理学 2021-11-02 Klaudia Zaremba-Kopczyk , Michał Tomza

We consider the interatomic van der Waals interaction energy between two neutral ground-state atoms moving in the vacuum space with the same uniform acceleration. We assume the acceleration orthogonal to their separation, so that their…

量子物理 · 物理学 2013-07-25 Antonio Noto , Roberto Passante

Zero-point quantum fluctuations of the electromagnetic vacuum create the widely known London-van der Waals attractive force between two atoms. Recently, there was a revived interest in the interaction of rotating matter with the quantum…

介观与纳米尺度物理 · 物理学 2015-09-01 Hervé Bercegol , Roland Lehoucq

Van der Waals forces as interactions between neutral and polarisable particles act at small distances between two objects. Their theoretical origin lies in the electromagnetic interaction between induced dipole moments caused by the vacuum…

化学物理 · 物理学 2019-06-05 Johannes Fiedler , Clas Persson , Mathias Boström , Stefan Y. Buhmann

We investigate the influence of the appearance of excitonic states on van der Waals interactions among two Rydberg atoms. The atoms are assumed to be in different Rydberg states, e.g., in the $|ns\rangle$ and $|np\rangle$ states. The…

原子物理 · 物理学 2015-08-12 Hashem Zoubi

Mutual Coulomb interactions between electrons lead to a plethora of interesting physical and chemical effects, especially if those interactions involve many fluctuating electrons over large spatial scales. Here, we identify and study in…

We consider a molecule in the Born-Oppenheimer approximation interacting with a plate of infinite thickness, i.e, a half--space, which is perfectly conducting or dielectric. It is well--known in the physics literature that in this case the…

数学物理 · 物理学 2022-08-17 Ioannis Anapolitanos , Mariam Badalyan , Dirk Hundertmark

We investigate the van der Waals interactions in solid molecular hydrogen structures. We calculate enthalpy and the Gibbs free energy to obtain zero and finite temperature phase diagrams, respectively. We employ density functional theory…

材料科学 · 物理学 2019-05-10 Sam Azadi , Graeme J. Ackland

Using fourth-order perturbation theory, a general formula for the van der Waals potential of two neutral, unpolarized, ground-state atoms in the presence of an arbitrary arrangement of dispersing and absorbing magnetodielectric bodies is…

量子物理 · 物理学 2007-05-23 Hassan Safari , Stefan Yoshi Buhmann , Dirk-Gunnar Welsch , Ho Trung Dung

In this paper, we consider an unusual connection between different fluids. Having established a research goal we would like to consider a toy model of the Universe and investigate its behavior, especially for later time evolution for well…

综合物理 · 物理学 2015-07-28 M. Khurshudyan , B. Pourhassan

In this Letter, we show that at low temperatures, zero-point fluctuations of the plasmon modes of two mutually coupled 2-D planar Wigner crystals give rise to a novel long-range attractive force. For the case where the distance $d$ between…

软凝聚态物质 · 物理学 2016-08-31 A. W. C. Lau , Dov Levine , P. Pincus

We describe a novel type of interaction between open-shell polar molecules at sub-millikelvin temperatures. This hyperfine van der Waals interaction occurs between two molecules in two rotational states that differ by one quantum. Normally,…

原子物理 · 物理学 2025-09-23 Etienne F. Walraven , Tijs Karman

The van der Waals potential of two atoms in the presence of an arbitrary arrangement of dispersing and absorbing magnetodielectric bodies is studied. Starting from a polarizable atom placed within a given geometry, its interaction with a…

量子物理 · 物理学 2007-09-11 Stefan Yoshi Buhmann , Hassan Safari , Ho Trung Dung , Dirk-Gunnar Welsch

We have calculated the isotropic $C\_6$ coefficients characterizing the long-range van der Waals interaction between two identical heteronuclear alkali-metal diatomic molecules in the same arbitrary vibrational level of their ground…

原子物理 · 物理学 2015-02-20 R. Vexiau , M. Lepers , M. Aymar , N. Bouloufa-Maafa , O. Dulieu

The quantum theory of the fluctuations of the van der Waals (vdW) force between macroscopic bodies is developed. Unlike the mean vdW force that is determined by all quantum states that contribute to the optical absorption, the energies of…

材料科学 · 物理学 2007-05-23 Shulim Kogan

Neutral atoms interact through a van der Waals potential which asymptotically falls off as r^{-6}. In ultracold gases, this interaction can be described to a good approximation by the atom-atom scattering length. However, corrections arise…

其他凝聚态物理 · 物理学 2009-11-13 Ryan M. Kalas , D. Blume

We show that the usual sum of $R^{-6}$ contributions from elements separated by distance $R$ can give \emph{qualitatively} wrong results for the electromagnetically non-retarded van der Waals interaction between non-overlapping bodies. This…

软凝聚态物质 · 物理学 2009-11-11 John F. Dobson , Angela White , Angel Rubio
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