相关论文: Spectroscopic signatures of molecular orbitals on …
Based on the refined crystal structure comprised of columns of 3*4 planar blocks of NbO6 octahedra and first principles electronic structure methods, we find that orthorhombic (o)-Nb$_{12}$O$_{29}$ introduces a new class of transition metal…
An emergent $\mathrm{SU}(4)$ symmetry discovered in the microscopic model for $d^1$ honeycomb materials [M.~G.~Yamada, M.~Oshikawa, and G.~Jackeli, Phys. Rev. Lett. \textbf{121}, 097201 (2018).] has enabled us to tailor exotic…
The physics of spin-orbit entangled magnetic moments of $4d$ and $5d$ transition metal ions on a honeycomb lattice has been much explored in search for unconventional magnetic orders or quantum spin liquids expected for compass spin models,…
The synthesis, structure, and basic magnetic properties of Na2Co2TeO6 and Na3Co2SbO6 are reported. The crystal structures were determined by neutron powder diffraction. Na2Co2TeO6 has a two-layer hexagonal structure (space group P6322)…
The orbital excitations of a series of transition-metal compounds are studied by means of optical spectroscopy. Our aim was to identify signatures of collective orbital excitations by comparison with experimental and theoretical results for…
We study the strong coupling model of $d^1$ transition metal tri-halides in the large spin-orbit coupled limit. By considering ab-initio-calculation-inspired hierarchy of hopping pathways of these compounds, SU(4) symmetry is found to…
Two-dimensional honeycomb lattices, characterized by their low coordination numbers, provide a fertile platform for exploring various quantum phenomena due to the intricate interplay between competing magnetic interactions, spin-orbit…
A pseudo honeycomb system Li2RuO3 exhibits a second-order-like transition at temperature T=Tc=540 K to a low-T nonmagnetic phase with a significant lattice distortion forming Ru-Ru pairs. For this system, we have calculated the band…
Muffin-tin methods have been instrumental in the design of honeycomb lattices that show, in contrast to graphene, separated s and in-plane p bands, a p orbital Dirac cone, and a p orbital flat band. Recently, such lattices have been…
The recent progress towards production of near-ground state quantum-degenerate molecules raises the issue of how such "small" molecules behave in an optical lattice. In this Letter we show that the coupling of the molecular orientation to…
We have explored the hidden symmetries of a generic four-parameter nearest-neighbor spin model, allowed in honeycomb lattice compounds under trigonal compression. Our method utilizes a systematic algorithm to identify all dual…
The relation between crystal symmetries, electron correlations, and electronic structure steers the formation of a large array of unconventional phases of matter, including magneto-electric loop currents and chiral magnetism. Detection of…
The $t_{2g}$ orbitals of an edge-shared transition-metal oxide with a honeycomb lattice structure form dispersionless electronic bands when only hopping mediated by the edge-sharing oxygens is accessible. This is due to the formation of…
Correlated materials with competing spin-orbit and crystal-field interactions can host composite spin-orbital magnons that are highly susceptible to structural and electronic perturbations, enabling the control of magnetic dynamics beyond…
Single crystals of a honeycomb lattice antiferromagnet, Tb$_2$Ir$_3$Ga$_9$ were synthesized, and the physical properties have been studied. From magnetometry, a long-range antiferromagnetic ordering at $\approx$12.5 K with highly…
The momentum-dependent orbital character in crystalline solids, referred to as orbital texture, is of capital importance in the emergence of symmetry-broken collective phases such as charge density waves as well as superconducting and…
With angle resolved photoemission experiments and \emph{ab-initio} electronic structure calculations, the pentacene monolayers on Ag(110) and Cu(110) are compared and contrasted allowing the molecular orientation and an unambiguous…
In this paper, we describe the formation of local resonances in graphene in the presence of magnetic adatoms containing localized orbitals of arbitrary symmetry, corresponding to any given angular momentum state. We show that quantum…
Ilmenites $AB$O$_3$ provide a platform for electron correlation and magnetism on alternatively stacked honeycomb layers of edge-sharing $A$O$_6$ or $B$O$_6$ octahedra. When $A$ and $B$ are $3d$ transition metals, strong electron correlation…
Transition metal oxides with 4d or 5d metals are of great interest due to the competing interactions, of the Coulomb repulsion and the itineracy of the d-electrons, opening a possibility of building new quantum ground states. Particularly…