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When a liquid freezes, a change in the local atomic structure marks the transition to the crystal. When a liquid is cooled to form a glass, however, no noticeable structural change marks the glass transition. Indeed, characteristic features…

软凝聚态物质 · 物理学 2015-11-24 Samuel S. Schoenholz , Ekin D. Cubuk , Daniel M. Sussman , Efthimios Kaxiras , Andrea J Liu

Despite the use of glasses for thousands of years, the nature of the glass transition is still mysterious. On approaching the glass transition, the growth of dynamic heterogeneity has long been thought to play a key role in explaining the…

软凝聚态物质 · 物理学 2018-03-23 Lijin Wang , Ning Xu , W. H. Wang , Pengfei Guan

While deeply supercooled liquids exhibit divergent viscosity and increasingly heterogeneous dynamics as the temperature drops, their structure shows only seemingly marginal changes. Understanding the nature of relaxation processes in this…

材料科学 · 物理学 2022-11-03 Matthias Lerbinger , Armand Barbot , Damien Vandembroucq , Sylvain Patinet

The glass transition, extensively studied in dense fluids, polymers, or colloids, corresponds to a dramatic evolution of equilibrium transport coefficients upon a modest change of control parameter, like temperature or pressure. A similar…

统计力学 · 物理学 2013-05-06 Ludovic Berthier , Jorge Kurchan

The rapid rise of viscosity or relaxation time upon supercooling is universal hallmark of glassy liquids. The temperature dependence of the viscosity, however, is quite non universal for glassy liquids and is characterized by the system's…

软凝聚态物质 · 物理学 2022-10-12 Indrajit Tah , Sean A. Ridout , Andrea J. Liu

The dynamical behavior of a kind of models with hierarchically constrained dynamics is investigated. The models exhibit many properties resembling real structural glasses. In particular, we focus on the study of time-dependent temperature…

统计力学 · 物理学 2009-11-07 A. Prados , J. J. Brey

We explore the relationship between a machine-learned structural quantity (softness) and excess entropy in simulations of supercooled liquids. Excess entropy is known to scale well the dynamical properties of liquids, but this…

软凝聚态物质 · 物理学 2023-06-07 Ian R. Graham , Paulo E. Arratia , Robert A. Riggleman

Measuring, characterizing and modelling the slow dynamics of glassy soft matter is a great challenge, with an impact that ranges from industrial applications to fundamental issues in modern statistical physics, such as the glass transition…

软凝聚态物质 · 物理学 2009-11-11 Luca Cipelletti , Laurence Ramos

If quenched fast enough, a liquid is able to avoid crystallization and will remain in a metastable supercooled state down to the glass transition, with an important increase in viscosity upon further cooling. There are important differences…

无序系统与神经网络 · 物理学 2016-06-01 C. Yildirim , J. -Y. Raty , M. Micoulaut

We examine the structural relaxation of glassy materials at finite temperatures, considering the effect of activated rearrangements and long-range elastic interactions. Our three-dimensional mesoscopic relaxation model shows how the…

软凝聚态物质 · 物理学 2023-12-20 Gieberth Rodriguez-Lopez , Kirsten Martens , Ezequiel E. Ferrero

We theoretically investigate glass transition behaviors of the glassy graphene in a wide range of temperature, where this amorphous graphene is described as a hard-sphere fluid. The dynamic arrest of a particle is assumingly caused by…

软凝聚态物质 · 物理学 2020-03-11 Tran Dinh Cuong , Anh D. Phan , Katsunori Wakabayashi , Pham Thanh Huy

Amorphous solids, or glasses, are distinguished from crystalline solids by their lack of long-range structural order. At the level of two-body structural correlations, glassformers show no qualitative change upon vitrifying from a…

软凝聚态物质 · 物理学 2015-06-11 C. Patrick Royall , Stephen R. Williams

Glassy systems are disordered systems characterized by extremely slow dynamics. Examples are supercooled liquids, whose dynamics slow down under cooling. The specific pattern of slowing-down depends on the material considered. This…

无序系统与神经网络 · 物理学 2016-04-12 Le Yan

The most puzzling aspect of the glass transition observed in laboratory is an apparent decoupling of dynamics from structure. In this paper we recount the implication of various theories of glass transition for the static correlation length…

无序系统与神经网络 · 物理学 2017-02-08 S. Davatolhagh

We introduce a new quantity to probe the glass transition. This quantity is a linear generalized compressibility which depends solely on the positions of the particles. We have performed a molecular dynamics simulation on a glass forming…

无序系统与神经网络 · 物理学 2009-11-07 Herve M. Carruzzo , Clare C. Yu

We provide a theoretical perspective on the glass transition in molecular liquids at thermal equilibrium, on the spatially heterogeneous and aging dynamics of disordered materials, and on the rheology of soft glassy materials. We start with…

统计力学 · 物理学 2011-06-22 Ludovic Berthier , Giulio Biroli

Elastic models of the glass transition relate the relaxation dynamics and the elastic properties of structural glasses. They are based on the assumption that the relaxation dynamics occurs through activated events in the energy landscape…

软凝聚态物质 · 物理学 2015-08-20 M. Pica Ciamarra , Peter Sollich

We combine the swap Monte Carlo algorithm to long multi-CPU molecular dynamics simulations to analyse the equilibrium relaxation dynamics of model supercooled liquids over a time window covering ten orders of magnitude for temperatures down…

软凝聚态物质 · 物理学 2022-12-16 Camille Scalliet , Benjamin Guiselin , Ludovic Berthier

The interrelation of dynamic processes active on separated time-scales in glasses and viscous liquids is investigated using a model displaying two time-scale bifurcations both between fast and secondary relaxation and between secondary and…

无序系统与神经网络 · 物理学 2015-03-19 Andrea Crisanti , Luca Leuzzi , Matteo Paoluzzi

We explore the glassy dynamics of soft colloids using microgels and charged particles interacting by steric and screened Coulomb interactions, respectively. In the supercooled regime, the structural relaxation time $\tau_\alpha$ of both…

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