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The organic conductor $\alpha$-(BEDT-TTF)$_2$I$_3$ provides the prime example of a charge-order-driven metal-insulator transition. Restricted chemical substitution of S atoms by Se in the constituent molecules allows us to modify the…

The organic charge-transfer salt $\kappa$-(BEDT-TTF)$_{2}$Hg(SCN)$_{2}$Br is a quasi two-dimensional metal with a half-filled conduction band at ambient conditions. When cooled below $T=80$ K it undergoes a pronounced transition to an…

The organic salt $\alpha$-(BEDT-TTF)$_2$I$_3$ is considered a model system for metal-insulator transition due to electronic charge ordering at $T_{\rm CO}=135$~K. The optical properties obtained from polarized reflection measurements above…

强关联电子 · 物理学 2016-03-25 T. Peterseim , M. Dressel

The spatial charge arrangement of a typical quasi-two-dimensional organic conductor alpha-(BEDT-TTF)2I3 is revealed by single crystal structure analysis using synchrotron radiation. The results show that the horizontal stripe type…

强关联电子 · 物理学 2009-11-13 Toru Kakiuchi , Yusuke Wakabayashi , Hiroshi Sawa , Toshihiro Takahashi , Toshikazu Nakamura

We explore the nature of the metal-insulator transition in $\beta^{\prime\prime}$-(BEDT-TTF)$_{2}$Hg(SCN)$_{2}$Cl by x-ray, electrical transport, ESR, Raman and infrared investigations. Magnetic and vibrational spectroscopy concurrently…

The charge-ordered insulator $\alpha$-(BEDT-TTF)$_2$I$_3$ gradually evolves to a metal when pressure is applied, and at low temperatures the electronic bands form tilted Dirac-like cones. A metallic state with a frequency-independent…

强关联电子 · 物理学 2019-05-22 Weiwu Li , Ece Uykur , Christine A. Kuntscher , Martin Dressel

(BEDT-TFF)$_2$I$_3$ charge transfer salts are reported to show superconductivity and pressure induced quasi two-dimensional Dirac cones at the Fermi level. By performing state of the art ab initio calculations in the framework of density…

We utilize a glass-like structural transition in order to induce a Mott metal-insulator transition in the quasi-two-dimensional organic charge-transfer salt $\kappa$-(BEDT-TTF)$_2$Cu[N(CN)$_2$]Br. In this material, the terminal ethylene…

强关联电子 · 物理学 2014-12-19 B. Hartmann , J. Müller , T. Sasaki

Infrared optical investigations of $\alpha$-(BEDT-TTF)$_2$I$_3$ have been performed in the spectral range from 80 to 8000~cm$^{-1}$ down to temperatures as low as 10~K by applying hydrostatic pressure. In the metallic state, $T > 135$~K, we…

强关联电子 · 物理学 2016-05-10 R. Beyer , A. Dengl , T. Peterseim , S. Wackerow , T. Ivek , A. V. Pronin , D. Schweitzer , M. Dressel

The charge response of charge-ordered state in the organic conductor alpha-(BEDT-TTF)2I3 is characterized by dc resistivity, dielectric and optical spectroscopy in different crystallographic directions within the two-dimensional conduction…

强关联电子 · 物理学 2010-05-27 T. Ivek , B. Korin-Hamzic , O. Milat , S. Tomic , C. Clauss , N. Drichko , D. Schweitzer , M. Dressel

Infrared reflection measurements of the half-filled two-dimensional organic conductors $\kappa$-(BEDT-TTF)$_2$Cu[N(CN)$_{2}$]Br$_{x}$Cl$_{1-x}$ were performed as a function of temperature ($5 {\rm K}<T<300$ K) and Br-substitution ($x=0%$,…

By applying measurements of the dielectric constants and relative length changes to the dimerized molecular conductor $\kappa$-(BEDT-TTF)$_2$Hg(SCN)$_2$Cl, we provide evidence for order-disorder type electronic ferroelectricity which is…

We have demonstrated transient charge localization effects with a driving high-frequency field of 7-fs, 1.5-cycle near infrared light in correlated organic conductors. In a layered organic conductor alpha-(BEDT-TTF)2I3 (BEDT-TTF:…

强关联电子 · 物理学 2018-08-29 Yohei Kawakami , Hirotake Itoh , Kenji Yonemitsu , Shinichiro Iwai

We report electrical transport, skin depth, and magnetocaloric measurements in the tau-series of organic conductors at very high magnetic fields. Above 36 T these materials show a magnetic field induced first order phase transition from a…

凝聚态物理 · 物理学 2009-11-07 J. S. Brooks , D. Graf , E. S. Choi , L. Balicas , K. Storr , C. H. Mielke , G. C. Papavassiliou

We present measurements of the infrared response of the quasi-one-dimensional organic conductor (TMTSF)2$SO3 along (E||a) and perpendicular (E||b') to the stacking axis as a function of temperature. Above the metal-insulator transition…

强关联电子 · 物理学 2007-06-13 A. Pashkin , K. Thirunavukkuarasu , Y. -L. Mathis , W. Kang , C. A. Kuntscher

We performed third-order electrical conductivity measurements on the organic conductor $\alpha$-(BEDT-TTF)$_2$I$_3$ using an ac bridge technique sensitive to nonlinear signals. Third-order conductance $G_3$ is clearly observed even at low…

强关联电子 · 物理学 2022-01-31 Mayu Ishii , Ryuji Okazaki , Masafumi Tamura

$\alpha$-(BEDT-TTF)$_2$I$_3$ is a prominent example of charge ordering among organic conductors. In this work we explore the details of transport within the charge-ordered as well as semimetallic phase at ambient pressure. In the…

We report a novel insulator-insulator transition arising from the internal charge degrees of freedom in the two-dimensional quarter-filled organic salt beta-(meso-DMBEDT-TTF)2PF6. The optical conductivity spectra above Tc = 70 K display a…

The quasi-two-dimensional organic superconductor beta-(BEDT-TTF)_2SF_5CH_2CF_2SO_3 (T_c approx 4.4 K)shows very strong Shubnikov-de Haas (SdH) oscillations which are superimposed on a highly anomalous steady background magnetoresistance,…

The fascinating electronic properties of the family of layered organic molecular crystals kappa-(BEDT-TTF)2X where X is an anion (e.g., X=I3, Cu[N(CN)2]Br, Cu(SCN)2) are reviewed. These materials are particularly interesting because of…

强关联电子 · 物理学 2007-05-23 Ross H. McKenzie
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