相关论文: First detections of the key prebiotic molecule PO …
Phosphorus is a crucial element in prebiotic chemistry, especially the P$-$O bond, which is key for the formation of the backbone of the deoxyribonucleic acid. So far, PO had only been detected towards the envelope of evolved stars, and…
Phosphorus is a key element that plays an essential role in biological processes important for living organisms on Earth. The origin and connection of phosphorus-bearing molecules to early Solar system objects and star-forming molecular…
In recent years, phosphorus monoxide (PO) -- an important molecule for prebiotic chemistry -- has been detected in star-forming regions and in the comet 67P/Churyumov-Gerasimenko. These studies have revealed that, in the interstellar…
Phosphorus is a key ingredient in terrestrial biochemistry, but is rarely observed in the molecular ISM and therefore little is known about how it is inherited during the star and planet formation sequence. We present observations of the…
As part of the Large Program ASAI (Astrochemical Surveys At IRAM), we have used the IRAM 30m telescope to lead a systematic search for the emission of rotational transitions of P-bearing species between 80 and 350 GHz towards L1157-B1, a…
Phosphorus (P) is one of the essential elements for life due to its central role in biochemical processes. Recent searches have shown that P-bearing molecules (in particular PN and PO) are present in star-forming regions, although their…
For decades, the detection of phosphorus-bearing molecules in the interstellar medium was restricted to high-mass star-forming regions (as e.g. SgrB2 and Orion KL) and the circumstellar envelopes of evolved stars. However, recent…
The chemistry of phosphorus in star- and planet-forming regions is poorly understood, despite the central role of phosphorus in terrestrial biochemistry. We present ALMA Band 3 and 4 observations of PO and PN towards the Class I protostar…
Phosphorus is a crucial element for the development of life, but so far P-bearing molecules have been detected only in a few astrophysical objects, hence its interstellar chemistry is almost totally unknown. Here we show new detections of…
The chemistry of phosphorus (31P) in space is particularly significant due to the key role it plays in biochemistry on Earth. Utilising radio and infrared spectroscopic observations, several key phosphorus-containing molecules have been…
To understand how Phosphorus-bearing molecules are formed in star-forming regions, we have analysed ALMA observations of PN and PO towards the massive star-forming region AFGL 5142, combined with a new analysis of the data of the comet…
Phosphorus-bearing species are an essential key to form life on Earth, however they have barely been detected in the interstellar medium. Since only PN and PO have been identified so far towards star-forming regions, the chemical formation…
Phosphorus is a necessary element for life on Earth, but at present we have limited constraints on its chemistry in star- and planet-forming regions: to date, phosphorus carriers have only been detected towards a few low-mass protostars.…
We report the first detection of the phosphorus monoxide ion (PO$^{+}$) in the interstellar medium. Our unbiased and very sensitive spectral survey towards the G+0.693$-$0.027 molecular cloud covers four different rotational transitions of…
We present multi-transition observations of PN towards a sample of nine massive dense cores in different evolutionary stages. Using transitions with different excitation conditions, we have found for the first time that the excitation…
The reactions of the low-lying metastable states of atomic phosphorus, P($^2$D) and P($^2$P), with H$_{2}$O and H$_{2}$ were studied by the pulsed laser photolysis at 248 nm of PCl$_{3}$ , combined with laser induced fluorescence detection…
Phosphorus (P) is one of the important elements for the formation of life and plays a crucial role in several biochemical processes. Recent spectral line surveys have confirmed the existence of P-bearing molecules, especially PN and PO, in…
The study of phosphorus chemistry in the interstellar medium has become a topic of growing interest in astrobiology, because it is plausible that a wide range of P-bearing molecules were introduced in the early Earth by the impact of…
The detection of organic molecules with increasing complexity and potential biological relevance is opening the possibility to understand the formation of the building blocks of life in the interstellar medium. One of the families of…
How complex organic - and potentially prebiotic - molecules are formed in regions of low- and high-mass star-formation remains a central question in astrochemistry. In particular, with just a few sources studied in detail, it is unclear…