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We have used first-principles methods to investigate the phase diagram of multiferroic bismuth ferrite (BiFeO3 or BFO), revealing the energetic and vibrational features that control the occurrence of various relevant structures. More…

材料科学 · 物理学 2015-06-17 Claudio Cazorla , Jorge Íñiguez

BiFeO3 is the most famous multiferroic material, but its G-type antiferromagnetism is highly desirable to be replaced by strong macroscopic magnetism beyond room temperature. Here we obtain double perovskite Bi2FeMoO6 with R3 (#146) space…

材料科学 · 物理学 2014-10-20 Peng Chen , Bang-Gui Liu

We calculate the effect of epitaxial strain on the structure and properties of multiferroic bismuth ferrite, BiFeO3, using first-principles density functional theory. We find that, while small strains cause only quantitative changes in…

材料科学 · 物理学 2021-04-06 A. J. Hatt , N. A. Spaldin , C. Ederer

Structural, electrical and magnetic properties of Bi0.9-xLa0.1ErxFeO3 (BLEFOx) (x = 0.05, 0.07, 0.1) polycrystalline ceramics prepared by solid solution route were studied. A phase transition from rhombohedral phase to monoclinic phase was…

材料科学 · 物理学 2008-05-29 Pragya Pandit , S. Satapathy , Poorva Sharma , P. K. Gupta , S. M. Yusuf

Using Landau-Ginzburg-Devonshire (LGD) theory for BiFeO3 dense fine grained ceramics with quasi spherical grains and nanosized inter grain spaces enriched by elastic defects, we calculated a surprisingly strong size-induced increase of the…

Microwave (MW) transmission, absorption, and reflection loss spectra of the ferrimagnetic U-type hexaferrite Sr$_4$CoZnFe$_{36}$O$_{60}$ ceramics were studied from 100 MHz to 35 GHz at temperatures between 10 and 390 K. 9 MW magnetic…

材料科学 · 物理学 2024-08-08 M. Kempa , V. Bovtun , D. Repček , J. Buršík , C. Kadlec , S. Kamba

Bismuth ferrite is one of the most widely studied multiferroic materials because of its large ferroelectric polarisation coexisting with magnetic order at room temperature. Using density functional theory (DFT), we identify several…

材料科学 · 物理学 2021-05-12 Bastien F. Grosso , Nicola A. Spaldin

Pressure-induced phase transitions of multiferroic BiFeO3 have been investigated using synchrotron radiation X-ray diffraction with diamond anvil cell technique at room temperature. Present experimental data clearly show that rhombohedral…

材料科学 · 物理学 2013-08-30 Zhang XiaoLi , Wu Ye , Zhang Qian , Dong JunCai , Wu Xiang , Liu Jing , Wu ZiYu , Chen DongLiang

We have investigated the complex dielectric and impedance properties of magnetoelectric compound Fe2TiO5 (FTO) as a function of temperature (T) and frequency (f) to understand the grain (G) and grain boundary (Gb) contributions to its…

材料科学 · 物理学 2015-12-15 Shivani Sharma , Tathamay Basu , Aga Shahee , K. Singh , N. P. Lalla , E. V. Sampathkumaran

Infrared reflectance spectra of an epitaxial Bi2FeCrO6 thin film prepared by pulsed laser deposition on LaAlO3 substrate were recorded between 10 and 900 K. No evidence for a phase transition to the paraelectric phase was observed, but some…

材料科学 · 物理学 2009-01-06 S. Kamba , D. Nuzhnyy , R. Nechache , K. Zaveta , D. Niznansky , E. Santava , C. Harnagea , A. Pignolet

Magnetic dc susceptibility between 1.5 and 800 K, ac susceptibility and magnetization, thermodynamic properties, temperature dependence of radio and audio-wave dielectric constants and conductivity, contact-free dielectric constants at…

The substitution of bismuth by samarium in BiFeO3 is known to induce a structural phase transition from the polar phase to a non-polar phase, with a possible antiferroelectric intermediate structure. In this paper, we investigate the impact…

Multiferroic materials have driven significant research interest due to their promising technological potential. Developing new room-temperature multiferroics and understanding their fundamental properties are important to reveal…

The magnetic and transport properties of BiFeO3/La2NiMnO6 (BFO/LNMO) composite have been investigated both experimentally and theoretically. Unlike the normal rhombohedral (R3c) phase, BFO in the composites is crystallized in the triclinic…

The structural, dielectric and ferroelectric properties of lead-free (Na0.5-xKxBi0.5-xLax)TiO3 powders synthesized by sol-gel self-combustion method were investigated. Rietveld refinement of Synchrotron x-ray diffraction data confirms pure…

We report on the frequency and stress dependence of the direct piezoelectric d33 coefficient in BiFeO3 ceramics. The measurements reveal considerable piezoelectric nonlinearity, i.e., dependence of d33 on the amplitude of the dynamic…

材料科学 · 物理学 2015-06-11 Tadej Rojac , Andreja Bencan , Goran Drazic , Marija Kosec , Dragan Damjanovic

The compression behavior of delafossite compound CuCrO2 has been investigated by in-situ x-ray diffraction and Raman spectroscopic measurements upto 23.2 and 34 GPa respectively. X-ray diffraction data shows the stability of ambient…

材料科学 · 物理学 2015-06-22 Alka B. Garg , A. K. Mishra , K. K. Pandey , Surinder M. Sharma

Crystalline Bi5NbO10 nanoparticles have been achieved through a modified sol-gel process using a mixture of ethylenediamine and ethanolamine as a solvent. The Bi5NbO10 nanoparticles were characterized by X-ray diffraction (XRD),…

材料科学 · 物理学 2009-10-26 Jungang Hou , Rahul Vaish , Yuanfang Qu , Dalibor Krsmanovica , K. B. R. Varmac , R. V. Kumara

The possibility of obtaining relatively high dielectric constant polymer-ceramic composite by incorporating the giant dielectric constant material, CaCu3Ti4O12 (CCTO) in a Poly(vinylidene fluoride) (PVDF) polymer matrix by melt mixing and…

材料科学 · 物理学 2013-01-18 P. Thomasa , K. T. Varughese , K. Dwarakanath , K. B. R. Varma

Piezoelectric and ferroelectric ceramics with a high Curie temperature (Tc) have attracted a growing attention owning to their applications under severe environments. In this work, phase structure, dielectric, ferroelectric and…