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Perovskite solar cells with record power conversion efficiency are fabricated by alloying both hybrid and fully inorganic compounds. While the basic electronic properties of the hybrid perovskites are now well understood, key electronic…

Interplays between charge and electric field, which play a critical role in determining the charge transport, recombination, storage and hysteresis in the perovskite solar cell, have been systematically investigated by both electrical…

材料科学 · 物理学 2017-10-31 Jiangjian Shi , Huiyin Zhang , Xin Xu , Dongmei Li , Yanhong Luo , Qingbo Meng

The basic processes of perovskite radiation resistance are discussed for photo- and high-energy electron irradiation. It is shown that ionization of iodine ions and a staged mechanism of elastic scattering (upon intermediate scattering on…

介观与纳米尺度物理 · 物理学 2018-12-17 Boris L. Oksengendler , Nigora N. Turaeva , Marlen I. Akhmedov

Perovskite Solar Cells (PSCs) have garnered global research interest owing to their superior photovoltaic (PV) performance. The future of photovoltaic technology lies in PSCs since they can produce power with performance on par with the…

材料科学 · 物理学 2025-09-18 Arghya Paul , Kanak Raj , Prince Raj Lawrence Raj , Pratim Kumar

If charge carriers accumulate in the charge transport layer of a solar cell, then the transient response of the electric field that originates from these accumulated charges results in hysteresis in the current-voltage ($J$-$V$)…

材料科学 · 物理学 2016-07-22 Kazuhiko Seki

Ionic migration in organo-halide perovskites plays an important role in operation of perovskite based solar cells and light emitting diodes. Despite the ionic migration being a reversible process, it often leads to worsening of perovskite…

Mixed halide perovskites undergo phase segregation, manifested as spectral red-shifting of photoluminescence spectra under illumination. In the iodine-bromide mixed perovskites, the origin of the low-energy luminescence is related to…

Perovskite-based solar cells are promising due to their rapidly improving efficiencies, but suffer from instability issues. Recently it has been claimed that one of the key contributors to the instability of perovskite solar cells is ion…

应用物理 · 物理学 2019-04-29 Boris Rivkin , Paul Fassl , Qing Sun , Alexander D. Taylor , Zhuoying Chen , Yana Vaynzof

Many recent advances in metal halide perovskite solar cell (PSC) performance are attributed to surface treatments which passivate interfacial trap states, minimise charge recombination and boost photovoltages. Surprisingly, these…

Mobile ions in hybrid perovskite semiconductors introduce a new degree of freedom to electronic devices suggesting applications beyond photovoltaics. An intuitive device model describing the interplay between ionic and electronic charge…

Organic-inorganic metal halide perovskite devices have generated significant interest for LED, photodetector, and solar cell applications due to their attractive optoelectronic properties and substrate-choice flexibility1-4. These devices…

Non-radiative recombination processes are the biggest hindrance to approaching the radiative limit of the open-circuit voltage for wide-band gap perovskite solar cells. In addition, to high bulk quality, good interfaces and good energy…

材料科学 · 物理学 2021-02-09 Zhifa Liu , Johanna Siekmann , Benjamin Klingebiel , Uwe Rau , Thomas Kirchartz

Perovskite solar cells (PSCs) based on methylammonium lead iodide (MAPbI3) exhibit remarkable photovoltaic performance, where interface engineering with hole transport layers (HTLs) is crucial for optimizing charge transfer and device…

材料科学 · 物理学 2025-12-30 Somayyeh Alidoust , V. Ongun Özçelik

With the rapid evolution of lead halide perovskite solar cells, there are considerable evidences that the mobile ions strongly impact their properties. However, except the activation energy, the other properties of ionic migration are…

材料科学 · 物理学 2018-06-21 Ningbo Yi , Gang Li , Yuhan Wang , Shuai Wang , Kaiyang Wang , Qinghai Song , Shumin Xiao

Perovskite solar cells (PSCs) are the fastest-growing photovoltaic (PV) technology in the solar cell community and have reached an efficiency close to that of commercial silicon (Si) solar cells. The organic-inorganic halide perovskite…

材料科学 · 物理学 2024-11-28 Kashimul Hossain

Organic-inorganic hybrid perovskites (OIHPs) have attracted extensive research interest as a promising candidate for efficient and inexpensive solar cells. Transmission electron microscopy characterizations that can benefit the fundamental…

In this article, the stability of p-i-n perovskite solar cells is studied under accelerated heat lifetime conditions (60 oC ,85oC and N2 atmosphere). By using a combination of buffer layer engineering, impedance spectroscopy and other…

Ion migration in halide perovskites is a key factor limiting the operational stability of solar cells due to formation of halogen ion enriched domains and accumulation layers. The present work demonstrates the manifestation of ion migration…

材料科学 · 物理学 2025-12-09 Vladimir Ivanov , Eduard Ageev , Denis Danilov , Eduard Danilovskiy , Dmitry Gets

We report that device architecture engineering has a substantial impact on the reverse bias instability that has been reported as a critical issue in commercializing perovskite solar cells. We demonstrate breakdown voltages exceeding -15 V…

Solar cells based on organic-inorganic metal halide perovskites show efficiencies close to highly-optimized silicon solar cells. However, ion migration in the perovskite films leads to device degradation and impedes large scale commercial…