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The influence of the pressure of a chemically inert carrier-gas on the nucleation rate is one of the biggest puzzles in the research of gas-liquid nucleation. Different experiments can show a positive effect, a negative effect, or no effect…

统计力学 · 物理学 2008-10-13 Jan Wedekind , Antti-Pekka Hyvärinen , David Brus , David Reguera

An analytical description of nucleation stage in a supersaturated vapor with instantly created supersaturation is given with taking into account the vapor concentration inhomogeneities arising as a result of depletion due to non-stationary…

化学物理 · 物理学 2014-04-25 Anatoly Kuchma , Maxim Markov , Alexander Shchekin

Vapour-liquid equilibria (VLE) and the influence of an inert carrier gas on homogeneous vapour to liquid nucleation are investigated by molecular simulation for quaternary mixtures of carbon dioxide, nitrogen, oxygen, and argon. Canonical…

大气与海洋物理 · 物理学 2015-05-14 Martin Horsch , Zengyong Lin , Thorsten Windmann , Hans Hasse , Jadran Vrabec

Recent work has shown that the stress tensor components, such as energy density or pressure, of a quantum field can be subject to large vacuum fluctuations. The energy density or pressure must be averaged in time before the fluctuations can…

量子物理 · 物理学 2021-07-21 L. H. Ford

This paper is a continuation of a study of the properties and applications of quantum stress tensor fluctuations. Here we treat the vacuum fluctuations of the electromagnetic energy-momentum flux operator which as been averaged in space and…

高能物理 - 理论 · 物理学 2024-12-05 L. H. Ford

It is shown for an electron-nucleus mixture that the electron and nuclear pressures are defined clearly and simply by the virial theorem; the total pressure of this system is a sum of these two pressures. The electron pressure is different…

统计力学 · 物理学 2009-11-10 Junzo Chihara , Mitsuru Yamagiwa

At first, pressure formulas for the electrons under the external potential produced by fixed nuclei are derived both in the surface integral and volume integral forms concerning an arbitrary volume chosen in the system; the surface integral…

材料科学 · 物理学 2009-11-07 Junzo Chihara , Ichirou Fukumoto , Mitsuru Yamagiwa , Hiroo Totsuji

We study the effects of the electromagnetic subvacuum fluctuations on the dynamics of a nonrelativistic charged particle in a wavepacket. The influence from the quantum field is expected to give an additional effect to the velocity…

量子物理 · 物理学 2015-05-13 Tai-Hung Wu , Jen-Tsung Hsiang , Da-Shin Lee

Classical nucleation theory offers a good framework for understanding the common features of new phase formation processes in metastable homogeneous media at rest. However, nucleation processes in liquids are ubiquitously affected by…

软凝聚态物质 · 物理学 2016-04-18 F. Mura , A. Zaccone

The classical nucleation theory (CNT) concept of a nucleus as a fragment of the bulk new phase fails for nanosized nuclei. An extension of CNT taking into account the properties of the transition region between coexisting bulk phases is…

化学物理 · 物理学 2017-06-09 Nikolay V. Alekseechkin

We present a systematic and unifying treatment of the problem of spontaneous nucleation of particle-antiparticle pairs in a (2+1)-dimensional system due to a static and uniform electromagnetic-like field, in the presence of quantum…

高能物理 - 理论 · 物理学 2017-08-23 Roberto Iengo , Giancarlo Jug

Pressure is the mechanical force per unit area that a confined system exerts on its container. In thermal equilibrium, it depends only on bulk properties (density, temperature, etc.) through an equation of state. Here we show that in a wide…

统计力学 · 物理学 2015-12-17 A. P. Solon , Y. Fily , A. Baskaran , M. E. Cates , Y. Kafri , M. Kardar , J. Tailleur

We explore the concept of negative pressure and its relevance in a variety of physical contexts: the expansion of the universe, mixture theory, cavitation, and the capillary effect in plants. Using thermodynamic arguments, we discuss the…

The pressure exerted on a wall by a gas at equilibrium does not depend on the shape of the confining potential defining the wall. In contrast, it has been shown recently [A.P. Solon et al., Nat. Phys. 11, 673 (2015)] that a gas of…

软凝聚态物质 · 物理学 2016-03-11 Marc Joyeux , Eric Bertin

The task of a first principles theoretical calculation of the rate of gas to liquid nucleation has remained largely incomplete despite the existence of reliable results from unbiased simulation studies at large supersaturation. Although the…

软凝聚态物质 · 物理学 2024-02-26 Subhajit Acharya , Biman Bagchi

The multivariable theory of nucleation [N. V. Alekseechkin, J. Chem. Phys. 124, 124512 (2006)] is applied to the droplet nucleation in a supersaturated single-component vapor; the droplet volume V, temperature T, and volume change rate…

化学物理 · 物理学 2015-06-18 Nikolay V. Alekseechkin

The work of formation of a critical nucleus is sometimes written as W=n{\Delta}{\mu}+{\gamma}A. The first term W_{vol}=n{\Delta}{\mu} is called the volume term and the second term {\gamma}A the surface term with {\gamma} being the…

化学物理 · 物理学 2013-05-09 Atsushi Mori

The build up of the stress whose relaxation is presumed to account for pulsar frequency glitches can be attributed to various mechanisms, of which the most efficient involve differential rotation of the neutron superfluid in the inner…

天体物理学 · 物理学 2009-11-10 Nicolas Chamel , Brandon Carter

In interiors of celestial objects matter is subdued to extremely high values of pressure.Theoretical analysis of the behaviour of atoms and molecules under high pressure is a complex quantum mechanical and statistical problem. The aim of…

量子物理 · 物理学 2013-12-24 V. Celebonovic Belgrade

We theoretically investigate the nucleation of liquid droplets from vapor in the presence of a charged spherical particle. Due to field gradients, sufficiently close to the critical point of the vapor--gas system, the charge destabilizes…

化学物理 · 物理学 2021-11-04 Roni Kroll , Yoav Tsori
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