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The observation of non-bulk superconductivity with an unexpectedly high onset transition temperature Tc up to ~ 49 K in non-superconducting single crystalline CaFe2As2 upon rare-earth doping has raised interesting questions concerning its…

超导电性 · 物理学 2013-08-15 B. Lv , F. Y. Wei , L. Z. Deng , Y. Y. Xue , C. W. Chu

In rare-earth doped single crystalline CaFe2As2, the mysterious small volume fraction which superconducts up to 49 K, much higher than the bulk Tc ~ 30s K, has prompted a long search for a hidden variable that could enhance the Tc by more…

超导电性 · 物理学 2016-02-16 F. Y. Wei , B. Lv , L. Z. Deng , J. K. Meen , Y. Y. Xue , C. W. Chu

We report the detection of unusual superconductivity up to 49 K in single crystalline CaFe2As2 via electron-doping by partial replacement of Ca by rare-earth. The superconducting transition observed suggests the possible existence of two…

超导电性 · 物理学 2011-10-28 B. Lv , L. Z. Deng , M. Gooch , F. Y. Wei , Y. Y. Sun , J. Meen , Y. Y. Xue , B. Lorenz , C. W. Chu

In this paper we report the superconductivity above 40 K in the electron doping single crystal Ca1-xRexFe2As2 (Re = La, Ce, Pr). The x-ray diffraction patterns indicate high crystalline quality and c-axis orientation. the resistivity…

Single crystalline CaFe2As2 and (Ca1-xNax)Fe2As2 polycrystals (0 < x < 0.66) are synthesized and characterized using structural, magnetic, electronic transport, and heat capacity measurements. These measurements show that the…

超导电性 · 物理学 2011-12-02 K. Zhao , Q. Q. Liu , X. C. Wang , Z. Deng , Y. X. Lv , J. L. Zhu , F. Y. Li , C. Q. Jin

Superconductivity of Ca1-xLaxFe2As2 single crystals with various doping level were investigated via electromagnetic measurements for out-plane (H//c) and in-plane (H//ab) directions. Obvious double superconducting transitions, which can…

超导电性 · 物理学 2013-08-28 W. Zhou , F. F. Yuan , J. C. Zhuang , Y. Sun , Y. Ding , L. J. Cui , J. Bai , Z. X. Shi

In order to clarify the origin of anomalous superconductivity in (Ca,RE)Fe2As2 system, Pr doped and Pr,Co co-doped CaFe2As2 single crystals were grown by the FeAs flux method. These samples showed two-step superconducting transition with…

High-pressure superconductivity in a rare-earth doped Ca0.86Pr0.14Fe2As2 single crystalline sample has been studied up to 12 GPa and temperatures down to 11 K using designer diamond anvil cell under a quasi-hydrostatic pressure medium. The…

We have successfully synthesized the fluoride-arsenide compounds Ca$_{1-x}$RE$_x$FeAsF (RE=Nd, Pr; x=0, 0.6). The x-ray powder diffraction confirmed that the main phases of our samples are Ca$_{1-x}$RE$_x$FeAsF with the ZrCuSiAs structure.…

超导电性 · 物理学 2009-04-23 Peng Cheng , Bing Shen , Gang Mu , Xiyu Zhu , Fei Han , Bin Zeng , Hai-Hu Wen

Aliovalent rare earth substitution into the alkaline earth site of CaFe2As2 single-crystals is used to fine-tune structural, magnetic and electronic properties of this iron-based superconducting system. Neutron and single crystal x-ray…

超导电性 · 物理学 2015-03-19 S. R. Saha , N. P. Butch , T. Drye , J. Magill , S. Ziemak , K. Kirshenbaum , P. Y. Zavalij , J. W. Lynn , J. Paglione

Single crystals of Ca1-xLaxFe2As2 for x ranging from 0 to 0.25 have been grown and characterized by structural, transport and magnetic measurements. Coexistence of two superconducting phases is observed, in which the low superconducting…

超导电性 · 物理学 2013-10-21 Y. Sun , W. Zhou , L. J. Cui , J. C. Zhuang , Y. Ding , F. F. Yuan , J. Bai , Z. X. Shi

The effects of isovalent doping on the superconducting transition temperature Tc in novel 112-type iron arsenide Ca1-xLaxFeAs2 were studied by conducting measurements of electrical resistivity rho and magnetization M. P or Sb doping…

Significant manifestation of interplay of superconductivity and charge density wave, spin density wave or magnetism is dome-like variation in superconducting critical temperature (Tc) for cuprate, iron-based and heavy Fermion…

Co-doped BaFe2As2 has been previously shown to have an unusually significant improvement of Tc (up to 2 K, or almost 10%) with annealing 1-2 weeks at 700 or 800 C, where such annealing conditions are insufficient to allow significant atomic…

超导电性 · 物理学 2015-06-19 J. S. Kim , G. N. Tam , G. R. Stewart

Superconductivity has been explored in single crystals of the Ni-doped FeAs-compound SrFe2-xNixAs2 grown by self-flux solution method. The antiferromagnetic order associated with the magnetostructural transition of the parent compound…

超导电性 · 物理学 2011-01-27 Shanta R. Saha , Nicholas P. Butch , Kevin Kirshenbaum , Johnpierre Paglione

The recently discovered FeAs-based superconductors are a new, promising set of materials for both technological as well as basic research. They offer transition temperatures as high as 55 K as well as essentially isotropic and extremely…

超导电性 · 物理学 2015-05-18 Paul C. Canfield , Sergey L. Bud'ko

Two single crystalline samples with the same nominal composition of Rb0.8Fe2Se2 prepared via slightly different precursor routes under the same thermal processing conditions were investigated at ambient and high pressures. One sample was…

超导电性 · 物理学 2012-07-18 M. Gooch , B. Lv , L. Z. Deng , T. Muramatsu , J. Meen , Y. Y. Xue , B. Lorenz , C. W. Chu

In this paper we report the synthesis of iron-based superconductors CaFe2-xRhxAs2 using one-step solid state reaction method, which crystallizes in the ThCr2Si2-type structure with a space group I4/mmm. The systematic evolution of the…

超导电性 · 物理学 2015-05-19 Yanpeng Qi , Lei Wang , Zhaoshun Gao , Dongliang Wang , Xianping Zhang , Chunlei Wang , Chao Yao , Yanwei Ma

A new hight Tc Fe-based compound system, AFe2As2 with A = K, Cs, K/Sr and Cs/Sr has been found. Through electron-doping, Tc of the A = K and Cs compounds rises to ~37 K, and finally enter a spin-density-wave state (SDW) through further…

超导电性 · 物理学 2008-09-09 K. Sasmal , B. Lv , B. Lorenz , A. Guloy , F. Chen , Y. Xue , C. W. Chu

Dome-shape superconductivity phase diagram can commonly be observed in cuprate and iron-based systems via tuning parameters such as charge carrier doping, pressure, bond angle, and etc. We report doping electrons from transition-metal…

超导电性 · 物理学 2016-04-12 W. Zhou , X. Z. Xing , H. J. Zhao , Z. X. Shi , K. Yamaura
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