相关论文: Cyanide photochemistry and fractionation in the MW…
UV photochemistry in the surface layers of protoplanetary disks dramatically alters their composition relative to previous stages of star formation. The abundance ratio CN/HCN has long been proposed to trace the UV field in various…
The distributions and abundances of molecules in protoplanetary disks are powerful tracers of the physical and chemical disk structures. The abundance ratios of HCN and its isomer HNC are known to be sensitive to gas temperature. Their line…
The chemistry of proto-planetary disks is thought to be dominated by two major processes: photodissociation near the disk surface, and depletion on dust grains in the disk mid-plane, resulting in a layered structure with molecules located…
Molecular line emission from protoplanetary disks is a powerful tool to constrain their physical and chemical structure. Nevertheless, only a few molecules have been detected in disks so far. We take advantage of the enhanced capabilities…
Aims: The two stable isotopes of nitrogen, 14N and 15N, exhibit a range of abundance ratios both inside and outside the solar system. The elemental ratio in the solar neighborhood is 440. Recent ALMA observations showed HCN/HC15N ratios…
Nitrogen fractionation is commonly used to assess the thermal history of Solar System volatiles. With ALMA it is for the first time possible to directly measure 14N/15N ratios in common molecules during the assembly of planetary systems. We…
The distributions and abundances of small organics in protoplanetary disks are potentially powerful probes of disk physics and chemistry. HNC is a common probe of dense interstellar regions and the target of this study. We use the…
The organic content of protoplanetary disks sets the initial compositions of planets and comets, thereby influencing subsequent chemistry that is possible in nascent planetary systems. We present observations of the complex nitrile-bearing…
The deuterium enrichment of molecules is sensitive to their formation environment. Constraining patterns of deuterium chemistry in protoplanetary disks is therefore useful for probing how material is inherited or reprocessed throughout the…
We present a spatially resolved map of integrated-intensity and abundance of Neptune's stratospheric hydrogen cyanide (HCN). The analyzed data were obtained from the archived 2016 observation of the Atacama Large Millimeter/submillimeter…
HCN is among the most commonly detected molecules in star- and planet-forming regions. It is of broad interest as a tracer of star-formation physics, a probe of nitrogen astrochemistry, and an ingredient in prebiotic chemical schemes.…
We studied several representative circumstellar disks surrounding the Herbig Ae star MWC 480 and the T Tauri stars LkCa 15 and DM Tau at (sub-)millimeter wavelengths in lines of CCH. Our aim is to characterize photochemistry in the heavily…
The UV radiation field is a critical regulator of gas-phase chemistry in surface layers of disks around young stars. In an effort to understand the relationship between photocatalyzing UV radiation fields and gas emission observed at…
The isotopic ratio of nitrogen in nearby protoplanetary disks, recently measured in CN and HCN, indicates that a fractionated reservoir of nitrogen is available at the stage of comet formation. This reservoir presents a 3:1 enrichment in…
Observations conducted using the Atacama Large Millimeter/submillimeter Array on the protoplanetary disk around TW Hya show the nitrogen fractionation of HCN molecules in HC$^{14}$N/HC$^{15}$N $\sim$120 at a radius of $\sim$20 AU. In this…
Bright ring-like structure emission of the CN molecule has been observed in protoplanetary disks. We investigate whether such structures are due to the morphology of the disk itself or if they are instead an intrinsic feature of CN…
Vinyl cyanide (C$_2$H$_3$CN) is theorized to form in Titan's atmosphere via high-altitude photochemistry and is of interest regarding the astrobiology of cold planetary surfaces due to its predicted ability to form cell membrane-like…
In the interstellar medium, the amide-type molecules play an important role in the formation of the prebiotic molecules in the hot molecular cores or high-mass star formation regions. The complex amide-related molecule cyanamide…
The cyanide radical CN is abundant in protoplanetary disks, with line fluxes often comparable to those of $^{13}$CO. It is known to be sensitive to UV irradiation of the upper disk atmosphere, with models predicting ring-shaped emission. We…
Molecular lines observed towards protoplanetary disks carry information about physical and chemical processes associated with planet formation. We present ALMA Band 6 observations of C2H, HCN, and C18O in a sample of 14 disks spanning a…