相关论文: High accuracy CO$_2$ line intensities determined f…
Atmospheric carbon dioxide concentrations are being closely monitored by remote sensing experiments which rely on knowing line intensities with an uncertainty of 0.5% or better. We report a theoretical study providing rotation-vibration…
Remote sensing experiments require high-accuracy, preferably sub-percent, line intensities and in response to this need we present computed room temperature line lists for six symmetric isotopologues of carbon dioxide: $^{13}$C$^{16}$O$_2$,…
The $\lambda$ = 2.06 $\mu$m absorption band of CO$_2$ is widely used for the remote sensing of atmospheric carbon dioxide, making it relevant to many important top-down measurements of carbon flux. The forward models used in the retrieval…
High-precision line intensities are of great value in various applications, such as greenhouse gas metrology, planetary atmospheric analysis, and trace gas detection. Here we report simultaneous measurements of cavity-enhanced absorption…
Accurate and comprehensive H2 pressure-induced broadening data for CO2 infrared lines over a wide temperature range are essential for modeling atmospheric opacity of exoplanets. However, available data are currently limited, some of which…
Astronomical observations of (sub)millimeter wavelength pure rotational emission lines of the second most abundant molecule in the Universe, CO, hold the promise of probing regions of high temperature and density in the innermost parts of…
Transmission spectra of H$_2$O+CO$_2$ mixtures have been recorded, at 296, 325 and 366 K, for various pressures and mixture compositions using two experimental setups. Their analysis enables to retrieve values of the 'continuum' absorption…
We introduce a spectroscopic approach to primary gas thermometry, harnessing precise optical cavity resonance frequencies and ab initio molecular line intensity calculations. By utilizing CO (3-0) vibrational band lines and cavity mode…
Experimental measurements and theoretical calculations of state-to-state rate coefficients for rotational energy transfer of CO in collision with H$_2$ are reported at the very low temperatures prevailing in dense interstellar clouds (5 -…
Coronal emission line intensities are commonly used to measure electron temperatures using emission measure and/or line ratio methods. In the presence of systematic errors in atomic excitation calculations and data noise, the information on…
Spectral line intensity mapping has been proposed as a promising tool to efficiently probe the cosmic reionization and the large-scale structure. Without detecting individual sources, line intensity mapping makes use of all available…
The study of environmental problems usually requires the description of variables with different nature and the assessment of relations between them. In this work, an algorithm for flexible estimation of the joint density for a…
A new hot line list for the main isotopologue of CO$_2$ is presented. The line list consists of almost 2.5 billion transitions between 3.5 million rotation-vibration states of CO$_2$ in its ground electronic state, covering the wavenumber…
The electronic, rotational, and vibrational components of the ultrafast optical nonlinearity in H$_2$ and D$_2$ are measured directly and absolutely at intensities up to the ionization threshold of $\sim$10$^{14}$ W/cm$^2$. As the most…
Using time-resolved infrared-vacuum-ultraviolet double-resonance spectroscopy, experimental room temperature measurements of state-to-state rate coefficients for rotational energy transfer within the X $^1\Sigma^+(v=2)$ vibrational state of…
We report on a comb-locked cavity ring-down spectrometer developed for high-precision, SI-traceable, molecular spectroscopy of air-broadened CO2 gas samples. The experimental setup relies on the use of a singly-resonant optical parametric…
Water is a key molecule in many astrophysical studies. Its high dipole moment makes this molecule to be subthermally populated under the typical conditions of most astrophysical objects. This motivated the calculation of various sets of…
We use an airborne pulsed integrated path differential absorption lidar to make spectroscopic measurements of the pressure-induced line broadening and line center shift of atmospheric CO2 at the 1572.335 nm absorption line. We measure the…
We present numerical simulations of molecular clouds (MCs) with self-consistent CO gas-phase and isotope chemistry in various environments. The simulations are post-processed with a line radiative transfer code to obtain $^{12}$CO and…
Context: It has been proposed that H$_2$ near-infrared lines may be excited by cosmic rays and allow for a determination of the cosmic-ray ionization rate in dense gas. One-dimensional models show that measuring both the H$_2$ gas column…