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Organic light-emitting diodes (OLEDs) must be engineered to circumvent the efficiency limit imposed by the 3:1 ratio of triplet to singlet exciton formation following electron-hole capture. Here we show the spin nature of luminescent…

Organic light-emitting diodes (OLEDs) have redefined lighting with their environment-friendliness and flexibility. However, only 25 % of the electronic states of organic molecules can emit light upon electrical excitation, limiting the…

材料科学 · 物理学 2025-02-17 Olli Siltanen , Kimmo Luoma , Andrew J. Musser , Konstantinos S. Daskalakis

At low temperatures and high magnetic fields, electron and hole spins in an organic light-emitting diode (OLED) become polarized so that recombination preferentially forms molecular triplet excited-state species. For low device currents,…

介观与纳米尺度物理 · 物理学 2021-04-28 Tobias Scharff , Wolfram Ratzke , Jonas Zipfel , Philippe Klemm , Sebastian Bange , John M. Lupton

We fabricate OLEDs using a stable neutral {\pi} radical, BDPA, as the emitter. There is only one electron in the singly occupied molecular orbital (SOMO) of this open-shell molecule. This feature makes the excited state of open-shell…

化学物理 · 物理学 2014-06-23 Qiming Peng , Hongwei Ma , Youchun Chen , Chuanyou He , Ablikim Obolda , Feng Li

Improving the efficiency and stability of organic light-emitting diodes (OLEDs) will further expand their present success in display applications. Triplet exciton-polaron quenching (TPQ) is an important cause of limited efficiency and…

原子与分子团簇 · 物理学 2025-06-13 Clint van Hoesel , Reinder Coehoorn , Peter A. Bobbert

Organic light emitting diodes (OLEDs) based on thermally activated delayed fluorescence (TADF) utilize molecular systems with a small energy splitting between singlet and triplet states. This can either be realized in intramolecular charge…

In photovoltaic diodes recombination of photogenerated electrons and holes is a major loss process. Biological light harvesting complexes (LHCs) prevent recombination via the use of cascade structures, which lead to spatial separation of…

Molecular triplet states can produce significant phosphorescence and act as a relay state for luminescence, such as in up-conversion processes. While this property makes triplet emitters interesting for organic light-emitting diodes…

介观与纳米尺度物理 · 物理学 2026-05-14 Li-Qing Zheng , Fábio J. R. Costa , Abhishek Grewal , Ruonan Wang , Fengmin Wang , Wei Li , Anna Rosławska , Klaus Kuhnke , Klaus Kern

We demonstrate experimentally an enhanced delayed fluorescence in tetracene single crystals strongly coupled to optical modes in open cavities formed by arrays of plasmonic nanoparticles. Hybridization of singlet excitons with collective…

介观与纳米尺度物理 · 物理学 2019-07-23 Matthijs Berghuis , Alexei Halpin , Quynh Le-Van , Mohammad Ramezani , Shaojun Wang , Shunsuke Murai , Jaime Gómez Rivas

In this study, we develop a steady state and time-dependent exciton diffusion model including singlet and triplet excitons coupled with a modified Poisson and drift-diffusion solver to explain the mechanism of hyper triplet-triplet fusion…

The photon upconversion based on sensitized triplet-triplet annihilation (sTTA-UC) is a spin-flip mechanism exploited to recover the energy of dark triplet states in conjugated systems. In this process a high-energy fluorescent singlet is…

In this study, we fabricated hybrid white organic light-emitting diodes (WOLEDs) based on triplet harvesting with simple structure. All the hole transporting material and host in emitting layer (EML) of devices were utilized with same…

仪器与探测器 · 物理学 2016-09-21 Kyo Min Hwang , Song Eun Lee , Sungkyu Lee , Han Kyu Yoo , Hyun Jung Baek , Jwajin Kim , Seung Soo Yoon , Young Kwan Kim

Two chromophores derived from heptazine, HAP-3MF and HAP-3TPA, were synthesized and tested as emitters in light-emitting diodes (OLEDs) by Adachi and coworkers. Both emitters were shown to exhibit quantum efficiencies which exceed the…

化学物理 · 物理学 2021-11-18 Andrzej L. Sobolewski , Wolfgang Domcke

The efficiency of an organic light-emitting diode (OLED) is fundamentally governed by the spin of recombining electron-hole pairs (singlet and triplet excitons), since triplets cannot usually emit light. The singlet-triplet energy gap, a…

The great progress in organic photovoltaics (OPV) over the past few years has been largely achieved by the development of non-fullerene acceptors (NFAs), with power conversion efficiencies now approaching 20%. To further improve device…

The quest for a spin-polarized organic light emitting diode (spin-OLED) is a common goal in the emerging fields of molecular electronics and spintronics. In this device two ferromagnetic electrodes are used to enhance the…

Organic light emitting diodes (OLEDs) based on thermally activated delayed fluorescence (TADF) show increased efficiencies due to efficient upconversion of non-emissive triplet states to emissive singlets states via reverse intersystem…

Spin-spin interactions in organic light-emitting diodes (OLEDs) based on thermally activated delayed fluorescence (TADF) are pivotal because radiative recombination is largely determined by triplet-to-singlet conversion, also called reverse…

Electroluminescence in organic light emitting diode (OLED) materials occurs via the recombination of excitonic electrons-hole pairs Only the singlet excitons of commonly used OLED materials, e.g., Aluminum trihydroxyquinoline (AlQ$_3$),…

材料科学 · 物理学 2009-11-07 M. W. C. Dharma-wardana , Marek Z. Zgierski

Spin triplet exciton formation sets limits on technologies using organic semiconductors that are confined to singlet-triplet photophysics. In contrast, excitations in the spin doublet manifold in organic radical semiconductors can show…

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