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SrTiO$_3$ is a highly efficient photocatalyst for the overall water splitting reaction under UV irradiation. However, an atomic-level understanding of the active surface sites responsible for the oxidation and reduction reactions is still…

Perovskite photoelectrodes are being extensively studied in search for photocatalytic materials that can produce hydrogen through water splitting. The solar-to-hydrogen efficiency of these materials is critically dependent on the…

应用物理 · 物理学 2019-06-26 Yihuang Xiong , Ismaila Dabo

Photocatalytic water splitting represents a pivotal pathway for converting solar energy into chemical energy, with the core challenge lying in the design and optimization of photocatalysts [1] . TiO2, as a quintessential photocatalytic…

材料科学 · 物理学 2025-02-20 Zhihao Shen

TiO$_2$ and SrTiO$_3$ are well known materials in the field of photocatalysis due to their exceptional electronic structure, high chemical stability, non-toxicity and low cost. However, owing to the wide band gap, these can be utilized only…

材料科学 · 物理学 2020-09-25 Manish Kumar , Pooja Basera , Shikha Saini , Saswata Bhattacharya

The interaction of water with TiO2 is crucial to many of its practical applications, including photocatalytic water splitting. Following the first demonstration of this phenomenon 40 years ago there have been numerous studies of the rutile…

Photocatalytic water splitting reaction on TiO2 surface is one of the fundamental issues that bears significant implication in hydrogen energy technology and has been extensively studied. However, the existence of the very first reaction…

化学物理 · 物理学 2011-11-15 Shijing Tan , Yongfei Ji , Yang Wang , Jin Zhao , Aidi Zhao , Bing Wang , Yi Luo , Jinlong Yang , J. G. Hou

Band engineering is employed thoroughly and targets technologically scalable photoanodes for solar water splitting applications. Complex and costly recipes are necessary, often for average performances. Here we report simple photoanode…

材料科学 · 物理学 2023-04-18 Stefan Stanescu , Théo Alun , Yannick J. Dappe , Dris Ihiawakrim , Ovidiu Ersen , Dana Stanescu

We adapt the computational hydrogen electrode approach to explicitly account for photo-generated charges and use it to computationally screen for viable catalyst/co-catalyst combinations for photo-catalytic water splitting. The hole energy…

材料科学 · 物理学 2013-07-31 Harald Oberhofer , Karsten Reuter

Owing to the versatility in their chemical and physical properties, transition metal perovskite oxides have emerged as a new category of highly efficient photocatalysts for photoelectrochemical water splitting. Here, to understand the…

Titanium dioxide (TiO$_2$) plays a central role in the study of artificial photosynthesis, owing to its ability to perform photocatalytic water splitting. Despite over four decades of intense research efforts in this area, there is still…

材料科学 · 物理学 2016-07-28 Christopher E. Patrick , Feliciano Giustino

Rearrangement of atoms due to broken translational symmetries at the surface of SrTiO$_3$ is scarcely debatable in the present day scenario. Actual concern demands to unveil the true structure and precise mechanism responsible for atomic…

材料科学 · 物理学 2018-11-08 Adeel Y Abid , Ning Li , Ayaz Arif , Peng Gao

Solar water splitting has attracted much attention as a clean and renewable route to produce hydrogen fuel. Since the oxygen evolution half-reaction (OER) requires high overpotentials, much research has focused on finding catalyst materials…

材料科学 · 物理学 2019-06-03 Maria Bouri , Ulrich Aschauer

Photocatalytic water splitting represents a very promising but at the same time very challenging contribution to a clean and renewable route to produce hydrogen fuel. Developing efficient and cost-effective photocatalysts for water…

材料科学 · 物理学 2023-01-12 Manjari Jain , Deepika Gill , Sanchi Monga , Saswata Bhattacharya

Photoelectrochemical solar water splitting is a promising approach to convert solar energy into sustainable hydrogen fuel using semiconductor electrodes. Due to their visible light absorption properties, oxynitrides have shown to be…

Water splitting is unanimously recognized as environment friendly, potentially low cost and renewable energy solution based on the future hydrogen economy. Especially appealing is photo-catalytic water splitting whereby a suitably chosen…

光学 · 物理学 2023-07-19 V. G. Kravets , A. N. Grigorenko

Recent rapid progress in efficiencies for solar water splitting by photoelectrochemical devices has enhanced its prospects to enable storable renewable energy. Efficient solar fuel generators all use tandem photoelectrode structures, and…

Perovskite SrTiO3 (STO) is an attractive photocatalyst for solar water splitting, but suffers from a limited photoresponse in the ultraviolet spectral range due to its wide band gap. By means of hybrid density functional theory…

材料科学 · 物理学 2021-06-16 Y. S. Hou , S. Ardo , R. Q. Wu

Surface electronic structures of the photoelectrodes determine the activity and efficiency of the photoelectrochemical water splitting, but the controls of their surface structures and interfacial chemical reactions remain challenging.…

Photocatalytic water splitting has attracted considerable attention for renewable energy production. Since the first reported photocatalytic water splitting by titanium dioxide, this material remains one of the most promising…

材料科学 · 物理学 2026-03-24 Marija Stojkovic , Edward Linscott , Nicola Marzari

The compositional and structural flexibility of functionalised two-dimensional metal carbonitrides or MXenes has been exploited through a combinatorial search for new materials that can act as catalysts for photo-assisted water splitting by…

材料科学 · 物理学 2024-04-05 Swati Shaw , Subhradip Ghosh
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