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Void induced coronene C23H12++ was suggested to be a possible carrier of the astronomically observed polycyclic aromatic hydrocarbon (PAH), which shows unique molecular structure with carbon two pentagons connected with five hexagons. Well…

化学物理 · 物理学 2015-02-14 Norio Ota

In order to find out a selected number of molecules to reproduce the infrared spectrum of interstellar gas and dust, model coronene molecules with void and charge have been computed using density functional theory. Among them, a single void…

星系天体物理 · 物理学 2014-12-02 Norio Ota

Interstellar dust shows ubiquitous interstellar infrared spectrum (IR) due to polycyclic aromatic hydrocarbon (PAH). By our previous quantum chemistry calculation, it was suggested that a molecule group having hydrocarbon pentagon-hexagon…

星系天体物理 · 物理学 2017-07-24 Norio Ota

In order to find out capable molecular source of astronomically well observed infrared (IR) spectrum, asymmetric molecular configuration polycyclic aromatic hydrocarbon (PAH) was analyzed by the density functional theory (DFT) analysis.…

星系天体物理 · 物理学 2015-10-27 Norio Ota

This study theoretically predicts the specific Polycyclic Aromatic Hydrocarbon (PAH) molecules to reproduce both astronomically observed Infrared Bands (IR) and Diffuse Interstellar Bands (DIB). In our recent paper, we could reproduce IR by…

星系天体物理 · 物理学 2023-11-23 Norio Ota

Reflection Nebula NGC2023 shows specific interstellar infrared spectrum due to polycyclic aromatic hydrocarbon (PAH) in a wide wavelength range from 5 to 20 micrometer. By our previous quantum chemistry calculation, it was suggested that a…

原子物理 · 物理学 2017-04-21 Norio Ota

It is very important to identify carrier molecules of astronomical interstellar infrared spectrum (IR) to understand chemical evolution step of polycyclic aromatic hydrocarbon (PAH) in the universe. In our previous study, it was suggested…

星系天体物理 · 物理学 2018-01-22 Norio Ota

By applying quantum chemical calculation, interstellar infrared spectrum was categorized to three classes. Type-A show unusual feature of strong peaks at 11.3,12.9, and 14.0 micrometer. Usually observed 6.2, 7.7, and 8.6 micrometer bands…

星系天体物理 · 物理学 2017-08-29 Norio Ota

Interstellar infrared observation shows featured spectrum due to polycyclic aromatic hydrocarbon (PAH)at wavelength 3.3,6.2,7.6,7.8,8.6,and 11.3 micrometer,which are ubiquitously observed in many astronomical dust clouds and galaxies. Our…

星系天体物理 · 物理学 2018-08-06 Norio Ota

Polycyclic aromatic hydrocarbon (PAH) ions are crucial intermediates in interstellar chemistry and may play a key role in the infrared emission features observed in space. Here, we investigate the infrared spectra of the indenyl…

The observed variations in profiles of the interstellar aromatic infrared bands correlate with the object type and are indicative of PAH populations existing i n different sources. Spectroscopic studies on PAHs can provide tools for the int…

天体物理学 · 物理学 2009-11-13 Amit Pathak , Shantanu Rastogi

Void induced di-cation coronene C23H12++ is a possible carrier of the astronomically observed polycyclic aromatic hydrocarbon (PAH). Based on density functional theory, multiple spin state analysis was done for neutral void coronene C23H12.…

化学物理 · 物理学 2015-01-09 Norio Ota

In order to find out capable chemical evolution step from astronomically created organic in interstellar space to biological organic on the earth, infrared spectrum of nitrogen substituted carbon pentagon-hexagon coupled polycyclic aromatic…

化学物理 · 物理学 2016-03-11 Norio Ota

The detection of fullerene molecules in a variety of astrophysical environments suggests that smaller dehydrogenated carbon molecules may also be present in these sources. One of these is planar C24 which has been shown to be more stable…

星系天体物理 · 物理学 2011-03-16 S. Kuzmin , W. W. Duley

This work presents theoretical calculations of infrared spectra of nitrogen (N)-containing polycyclic aromatic hydrocarbon (PAH) molecules with incorporation of N, NH and NH$_2$ using density functional theory (DFT). The properties of their…

星系天体物理 · 物理学 2021-12-30 Akant Vats , Amit Pathak , Takashi Onaka , Mridusmita Buragohain , Itsuki Sakon , Izumi Endo

Interstellar ubiquitous infrared spectrum (IR) due to polycyclic aromatic hydrocarbon (PAH) was observed in many astronomical dust clouds. A capable astronomical chemical evolution path from graphene to PAH was studied based on the first…

介观与纳米尺度物理 · 物理学 2017-03-20 Norio Ota

Interstellar Polycyclic Aromatic Hydrocarbon (PAH) molecules exist in diverse forms depending on the local physical environment. Formation of ionized PAHs (anions and cations) is favourable in the extreme conditions of the ISM. Besides in…

星系天体物理 · 物理学 2017-12-27 Mridusmita Buragohain , Amit Pathak , Peter Sarre , Nand Kishor Gour

The unidentified infrared emission (UIE) features at 3.3, 6.2, 7.7, 8.6, 11.3 and 12.7 micron are ubiquitously seen in a wide variety of astrophysical regions and commonly attributed to polycyclic aromatic hydrocarbon (PAH) molecules.…

星系天体物理 · 物理学 2024-03-11 Kaijun Li , Aigen Li , Xuejuan Yang , Taotao Fang

The detection of benzonitrile (C6H5CN), 1- and 2-cyano-naphthalene (C10H7CN) in the cold, dark molecular cloud TMC-1 at centimetre (cm) wavelengths has opened up prospects for the detection of other N- and CN-containing polycyclic aromatic…

星系天体物理 · 物理学 2022-11-04 Akant Vats , Amit Pathak

This work proposes deuteronated PAH (DPAH+ ) molecules as a potential carrier of the 4.4 and 4.65 {\mu}m mid infrared emission bands that have been observationally detected towards the Orion and M17 regions. Density Functional Theory…

星系天体物理 · 物理学 2017-11-28 Mridusmita Buragohain , Amit Pathak , Peter Sarre , Takashi Onaka , Itsuki Sakon
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