相关论文: Chemical evolution in the early phases of massive …
From observations, column density ratios or integrated intensity ratios between some species exhibit monotonic increase or decrease along with the evolution of high-mass star-forming regions (HMSFRs). Such ratios are defined as chemical…
We report on the first measurements of the isotopic ratio 14N/15N in N2H+ toward a statistically significant sample of high-mass star forming cores. The sources belong to the three main evolutionary categories of the high-mass star…
We use the deuteration of $c$-$\mathrm{C_{3}H_{2}}$ to probe the physical parameters of starless and protostellar cores, related to their evolutionary states, and compare it to the $\mathrm{N_{2}H^{+}}$-deuteration in order to study…
The surface formation of NH3 and its deuterated isotopologues - NH2D, NHD2, and ND3 - is investigated at low temperatures through the simultaneous addition of hydrogen and deuterium atoms to nitrogen atoms in CO-rich interstellar ice…
We present the results of models of the chemistry, including deuterium, in the inner regions of protostellar disks. We find good agreement with recent gas phase observations of several (non--deuterated) species. We also compare our results…
The destiny of complex organic molecules (COMs) in star-forming regions is interlinked with various evolutionary phases. Therefore, identifying these species in diversified environments of identical star-forming regions would help to…
Massive stars play an important role in the Universe. Unlike low-mass stars, the formation of these objects located at great distances is still unclear. It is expected to be governed by some combination of self-gravity, turbulence, and…
Context: In the last years, the H2D+ and D2H+ molecules have gained great attention as probes of cold and depleted dense molecular cloud cores. These ions are at the basis of molecular deuterium fractionation, a common characteristic…
[abridged] The enhanced degrees of deuterium fractionation observed in envelopes around protostars demonstrate the importance of chemistry at low temperatures, relevant in pre- and protostellar cores. formaldehyde is an important species in…
The chemical changes of high-mass star-forming regions provide a potential method for classifying their evolutionary stages and, ultimately, ages. In this study, we search for correlations between molecular abundances and the evolutionary…
Chemical composition of the massive cores forming high-mass stars can put some constrains on the time scale of the massive star formation: sulphur chemistry is of specific interest due to its rapid evolution in warm gas and because the…
Based on recent work, formamide might be a potentially very important molecule in the emergence of terrestrial life. Although detected in the interstellar medium for decades, its formation route is still debated, whether in the gas phase or…
Observations of deuterium fractionation in the solar system, and in interstellar and circumstellar material, are commonly used to constrain the formation environment of volatiles. Toward protoplanetary disks, this approach has been limited…
Deuterium fractionation can constrain the physical and chemical conditions at the early stage of brown dwarf formation. We present IRAM 30m observations over a wide frequency range of 213-279 GHz of singly and doubly deuterated species of…
We investigate the deuteration of methanol towards the high-mass star forming region NGC 7538-IRS1. We have carried out a multi-transition study of CH$_3$OH, $^{13}$CH$_3$OH and of the deuterated fllavors, CH$_2$DOH and CH$_3$OD, between…
This paper reviews the chemistry of star-forming regions, with an emphasis on the formation of high-mass stars. We first outline the basic molecular processes in dense clouds, their implementation in chemical models, and techniques to…
We aim to investigate the chemistry of internal photon-dominated regions surrounding deeply embedded hypercompact and ultracompact HII regions. We search for specific tracers of this evolutionary stage of massive star formation that can be…
Star-forming regions host a large and evolving suite of molecular species. Molecular transition lines, particularly of complex molecules, can reveal the physical and dynamical environment of star formation. We aim to study the large-scale…
Hot cores and their precursors contain an integrated record of the physics of the collapse process in the chemistry of the ices deposited during that collapse. In this paper, we present results from a new model of the chemistry near high…
Aims. We aim to improve a previous model for the prediction of column densities and deuterium fractions of non- and singly deuterated methanol. Thereby, we try to identify crucial chemical and physical parameters, for which the study of…