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We present high-resolution spectroscopy of Rb$_\text{2}$ ultralong-range Rydberg molecules bound by mixed singlet-triplet electron-neutral atom scattering. The mixing of the scattering channels is a consequence of the hyperfine interaction…

We present an overview of our recent investigations of long-range interactions in an ultracold Cs Rydberg gas. These interactions are studied by high-resolution photoassociation spectroscopy, using excitation close to one-photon transitions…

原子物理 · 物理学 2016-07-15 Heiner Saßmannshausen , Johannes Deiglmayr , Frédéric Merkt

We calculate vibrational spectra of ultralong-range Cs(32p) Rydberg molecules which form in an ultracold gas of Cs atoms. We account for the partial-wave scattering of the Rydberg electrons from the ground Cs perturber atoms by including…

We observe long-range $^{85}$Rb and $^{87}$Rb (24$D$+5$S_{1/2}$) Rydberg molecules for eight different spin couplings, with binding energies up to 440~MHz and sub-percent relative uncertainty. Isotopic effects of the molecular binding…

原子物理 · 物理学 2020-01-15 Jamie L. MacLennan , Yun-Jhih Chen , Georg Raithel

We report the creation of ultralong-range Sr$_2$ molecules comprising one ground-state $5s^2$ $^1S_0$ atom and one atom in a $5sns$ $^3S_1$ Rydberg state for $n$ ranging from 29 to 36. Molecules are created in a trapped ultracold atomic gas…

We propose a novel scheme to efficiently tune the scattering length of two colliding ground-state atoms by off-resonantly coupling the scattering-state to an excited Rydberg-molecular state using laser light. For the s-wave scattering of…

量子气体 · 物理学 2017-10-04 Nóra Sándor , Rosario González-Férez , Paul S. Julienne , Guido Pupillo

We present experimental evidence for spin-orbit interaction of an electron as it scatters from a neutral atom. The scattering process takes place within a Rb$_2$ ultralong-range Rydberg molecule, consisting of a Rydberg atomic core, a…

We present a comprehensive study of the diverse properties of heteronuclear Rydberg molecules, placing a special emphasis on those composed of the light alkali atoms, Li, Na, and K. Electron-atom scattering phase shifts, which determine the…

原子物理 · 物理学 2019-02-13 Matthew T. Eiles

We unravel some peculiar properties of ultralong-range Rydberg molecules formed by an $s$-state $^{87}$Rb Rydberg atom and a corresponding ground-state atom whose electronic orbitals are spherically symmetric and therefore should not be…

原子物理 · 物理学 2019-02-06 Frederic Hummel , Christian Fey , Peter Schmelcher

We report the observation of spin-singlet ultra-long range Rydberg butterfly molecules consisting of a ground-state atom bound to a Rydberg atom by $P$-wave scattering of $^{87}$Rb Rydberg electrons from $^{87}$Rb(5s) atoms. A three-photon…

We present the formation of homonuclear Cs2, K2, and heteronuclear CsK long-range Rydberg molecules in a dual-species magneto-optical trap for 39K and 133Cs by one-photon UV photoassociation. The different ground-state-density dependence of…

原子物理 · 物理学 2021-01-08 Michael Peper , Johannes Deiglmayr

Rydberg-atom synthetic dimensions in the form of a lattice of n$^3S_1$ levels, $58\leq n \leq 63$, coupled through two-photon microwave excitation are used to examine dynamics within the single-particle Su-Schrieffer-Heeger (SSH)…

量子物理 · 物理学 2023-11-14 Y. Lu , C. Wang , S. K. Kanungo , S. Yoshida , F. B. Dunning , T. C. Killian

We consider ultralong-range polyatomic Rydberg molecules formed by combining a Rydberg cesium atom and a ground-state RbCs molecule. We explore the regime where the charge-dipole interaction due to the Rydberg electron with the diatomic…

We investigate the fine and spin structure of ultralong-range Rydberg molecules exposed to a homogeneous magnetic field. Each molecule consists of a $^{87}$Rb Rydberg atom whose outer electron interacts via spin-dependent $s$- and p-wave…

原子物理 · 物理学 2018-05-02 Frederic Hummel , Christian Fey , Peter Schmelcher

Rydberg molecule, formed by one or more Rydberg atoms, exhibits remarkable properties, including an exceptionally large spatial extent, rich rovibrational level structures, permanent electric dipole moments, and a pronounced sensitivity to…

原子物理 · 物理学 2026-03-11 Jingxu Bai , Yuechun Jiao , Xiao-Qiang Shao , Weibin Li , Jianming Zhao

Ultralong-range Rydberg molecules, composed of an excited Rydberg atom and a ground-state atom, are characterized by large bond lengths, dipole moments, sensitivity to external fields, and an unusual binding mechanism based on low-energy…

原子物理 · 物理学 2025-05-13 Agata Wojciechowska , Michał Tomza , Matthew T. Eiles

Long-range metastable molecules consisting of two cesium atoms in high Rydberg states have been observed in an ultracold gas. A sequential three-photon two-color photoassociation scheme was employed to form these molecules in states which…

原子物理 · 物理学 2016-11-17 Heiner Saßmannshausen , Johannes Deiglmayr

We introduce the Rydberg Composite, a new class of Rydberg matter where a single Rydberg atom is interfaced with a dense environment of neutral ground state atoms. The properties of the Composite depend on both the Rydberg excitation, which…

原子物理 · 物理学 2020-09-02 Andrew L. Hunter , Matthew T. Eiles , Alex Eisfeld , Jan M. Rost

Spectroscopic measurements of the rotational distribution of $^{84}$Sr and $^{86}$Sr 5sns $^1S_0$ ultralong-range Rydberg molecular dimers created via photoassociation in a cold gas are reported. The dimers are produced by two-photon…

原子物理 · 物理学 2024-06-14 C. Wang , Y. Lu , S. K. Kanungo , F. B. Dunning , T. C. Killian , S. Yoshida

The interaction between a Rydberg electron and a neutral atom situated inside its extended orbit is described via contact interactions for each atom-electron scattering channel. In ultracold environments, these interactions lead to…

原子物理 · 物理学 2017-05-10 Matthew T Eiles , Chris H Greene
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