相关论文: Ultracold chemistry with alkali-metal-rare-earth m…
Ultracold chemical reactions of weakly bound triplet-state alkali-metal dimer molecules have recently attracted much experimental interest. We perform rigorous quantum scattering calculations with a new $ab\, initio$ potential energy…
A fundamental question in the study of chemical reactions is how reactions proceed at a collision energy close to absolute zero. This question is no longer hypothetical: quantum degenerate gases of atoms and molecules can now be created at…
We theoretically characterize interactions, energetics, and chemical reaction paths in ionic two-body and three-body systems of alkali-metal and alkaline-earth-metal atoms in the context of modern experiments with cold hybrid ion-atom…
The quantum mechanical few-body problem at ultracold energies poses severe challenges to theoretical techniques, particularly when long-range interactions are present that decay only as a power-law potential. In this paper we review the…
Universal low-energy properties are studied for three identical bosons confined in two dimensions. The short-range pair-wise interaction in the low-energy limit is described by means of the boundary condition model. The wave function is…
Chemical reactions can be surprisingly efficient at ultracold temperatures ( < 1mK) due to the wave nature of atoms and molecules. The study of reactions in the ultracold regime is a new research frontier enabled by cooling and trapping…
We have carried out the first quantum dynamics calculations on ultracold atom-diatom collisions in isotopic mixtures. The systems studied are spin-polarized 7Li + 6Li7Li, 7Li + 6Li2, 6Li + 6Li7Li and 6Li + 7Li2. Reactive scattering can…
We present a unified formalism for describing chemical reaction rates of trapped, ultracold molecules. This formalism reduces the scattering to its essential features, namely, a propagation of the reactant molecules through a gauntlet of…
The K + KRb $\longrightarrow$ Rb + K$_{2}$ chemical reaction is the first ultracold atom-diatom chemical reaction for which experimental results have been reported for temperatures below 1 $\mu$K more than a decade ago. The reaction occurs…
Chemical reaction rates often depend strongly on stereodynamics, namely the orientation and movement of molecules in three-dimensional space. An ultracold molecular gas, with a temperature below 1 uK, provides a highly unusual regime for…
Chemical reactions at ultracold temperature provide an ideal platform to study chemical reactivity at the fundamental level, and to understand how chemical reactions are governed by quantum mechanics. Recent years have witnessed the…
Ab initio quantum chemistry calculations are performed for the mixed alkali triatomic system. Global minima of the ground and first excited doublet states of the trimer are found and Born-Oppenheimer potential energy surfaces of the Li atom…
How does a chemical reaction proceed at ultralow temperatures? Can simple quantum mechanical rules such as quantum statistics, single scattering partial waves, and quantum threshold laws provide a clear understanding for the molecular…
We present a theoretical investigation of cold reactive and non-reactive collisions of Li and Rb atoms with C$_{2}^{-}$. The potential energy surfaces for the singlet and triplet states of the Li--C$_{2}^{-}$ and Rb--C$_{2}^{-}$ systems…
We study theoretically interaction potentials and low energy collisions between different alkali atoms and alkali ions. Specifically, we consider systems like X + Y$^{+}$, where X(Y$^{+})$ is either Li(Cs$^+$) or Cs(Li$^+$), Na(Cs$^+$) or…
The realization of ultracold polar molecules in laboratories has pushed both physics and chemistry to new realms. In particular, these polar molecules offer scientists unprecedented opportunities to explore chemical reactions in the…
Ultracold collisions between spin-polarized Na atoms and vibrationally excited Na_2 molecules are investigated theoretically, using both an inelastic formalism (neglecting atom exchange channels) and a reactive formalism (including atom…
The universal three-body dynamics in ultra-cold binary Fermi and Fermi-Bose mixtures is studied. Two identical fermions of the mass $m$ and a particle of the mass $m_1$ with the zero-range two-body interaction in the states of the total…
Three-body recombination is a chemical reaction where the collision of three atoms leads to the formation of a diatomic molecule. In the ultracold regime it is expected that the production rate of a molecule generally decreases with its…
Ultracold collisions of LiO molecules in the $^{2}\Pi_{3/2}$ ground state are considered, under the influence of either an external magnetic or electric field. Inelastic collisions are shown to be suppressed in the presence of modest…