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Depending on the crystal growth conditions, an orthorhombic (O-type) or a tetragonal (T-type) structure can be found in the solid solution Cs2CuCl4-xBrx (0 < x < 4). Here we present measurements of the temperature-dependent magnetic…

X-ray and neutron powder diffraction data as a function of temperature are analyzed for the colossal dielectric constant material CaCu3Ti4O12. The local structure is studied using atomic pair distribution function analysis. No evidence is…

材料科学 · 物理学 2009-11-10 E. S. Bozin , V. Petkov , P. W. Barnes , P. M. Woodward , T. Vogt , S. D. Mahanti , S. J. L. Billinge

Pronounced anisotropy of magnetic properties and complex magnetic order of a new oxi-halide compound Co7(TeO3)4Br6 has been investigated by powder and single crystal neutron diffraction, magnetization and ac susceptibility techniques.…

材料科学 · 物理学 2013-05-29 M. Prester , I. Zivkovic , O. Zaharko , D. Pajic , P. Tregenna-Piggott , H. Berger

Crystal structure, electronic state of Ir$^{4+}$, and magnetic properties of the antifluorite compound K$_2$IrBr$_6$ are studied using high-resolution synchrotron x-ray diffraction, resonant inelastic x-ray scattering (RIXS), thermodynamic…

强关联电子 · 物理学 2021-04-02 Nazir Khan , Danil Prishchenko , Mary H. Upton , Vladimir G. Mazurenko , Alexander A. Tsirlin

Realisation of the tetragonal phase of $Cs_2CuCl_4$ is possible using specific crystal growth conditions at a temperature below $281K$. This work deals with the comparison of the magnetic susceptibility and the magnetization of this new…

We report on a systematic study of the magnetic properties on single crystals of the solid solution Cs$_2$CuCl$_{4-x}$Br$_x$ (0 $\leq$ x $\leq$ 4), which include the two known end-member compounds Cs$_2$CuCl$_4$ and Cs$_2$CuBr$_4$,…

We report X-ray diffraction and magnetic susceptibility studies of the structural phase transition in $\alpha$-RuCl$_{3}$. By utilizing a single crystal sample with predominantly single twin domain, we show that $\alpha$-RuCl$_{3}$ goes…

强关联电子 · 物理学 2023-11-08 Subin Kim , Ezekiel Horsley , Jacob P. C. Ruff , Beatriz D. Moreno , Young-June Kim

In this work we present a study of the low temperature magnetic phases of polycrystalline MnCr$_2$O$_4$ spinel through dc magnetization and ferromagnetic resonance spectroscopy (FMR). Through these experiments we determined the main…

材料科学 · 物理学 2014-12-03 Dina Tobia , Julián Milano , María Teresa Causa , Elin L. Winkler

We report the single-crystal X-ray analysis and magnetic properties of a new double-layered perovskite antiferromagnet, Cs$_3$Cu$_2$Cl$_4$Br$_3$. This structure is composed of Cu$_2$Cl$_4$Br$_3$ double layers with elongated CuCl$_4$Br$_2$…

强关联电子 · 物理学 2015-06-25 F. Yamada , T. Ono , H. Tanaka , J. Yamaura

We have grown a YCrO$_3$ single crystal by the floating-zone method and studied its temperature-dependent crystalline structure and magnetization by X-ray powder diffraction and PPMS DynaCool measurements. All diffraction patterns were well…

强关联电子 · 物理学 2024-03-08 Qian Zhao , Yinghao Zhu , Si Wu , Junchao Xia , Pengfei Zhou , Kaitong Sun , Hai-Feng Li

The magnetic properties of a new family of molecular-based quasi-two dimension $S=1/2$ Heisenberg antiferromagnets are reported. Three compounds, ($Cu(pz)_2(ClO_4)_2$, $Cu(pz)_2(BF_4)_2$, and $[Cu(pz)_2(NO_3)](PF_6)$) contain similar planes…

The crystal structure of the copper(II) tellurium(IV) oxochloride Cu$_{4}$Te$_{5}$O$_{12}$Cl$_{4}$ (Cu-45124) is composed of weakly coupled tetrahedral Cu clusters and shows crystallographic similarities with the intensively investigated…

The temperature evolution of the crystal and magnetic structures of ferroelectric sulfide AgCrS2 have been investigated by means of neutron scattering. AgCrS2 undergoes at TN = 41.6 K a first-order phase transition, from a paramagnetic…

We report on the crystal structure of the quantum magnet (CuCl)LaNb2O7 that was controversially described with respect to its structural organization and magnetic behavior. Using high-resolution synchrotron powder x-ray diffraction,…

材料科学 · 物理学 2015-03-17 Alexander A. Tsirlin , Artem M. Abakumov , Gustaaf Van Tendeloo , Helge Rosner

Transmission electron microscopy studies of [110] and [111] oriented FeCr_2S_4 single crystals at different temperatures reveal a structural transition at low temperatures indicating a cubic-to-triclinic symmetry reduction within…

材料科学 · 物理学 2009-11-10 M. Mertinat , V. Tsurkan , D. Samusi , R. Tidecks , F. Haider

A complex magnetic order of the multiferroic compound Co3TeO6 has been revealed by neutron powder diffraction studies on ceramics and crushed single crystals. The compound adopts a monoclinic structure (s.g. C2/c) in the studied temperature…

Double cation chalcohalide have recently been emerged as the interesting candidates for sustainable energy conversion applications, owing to their intrinsic chemical tunability, suitable band gap, and low thermal conductivity. With this…

A detailed study of the electronic transport and magnetic properties of Fe$_{1-x}$Cu$_x$Cr$_2$S$_4$ ($x \leq 0.5$) on single crystals is presented. The resistivity is investigated for $2 \leq T \leq 300$ K in magnetic fields up to 14 Tesla…

The crystal structures of the triangular lattice, layered anhydrous alums KCr(SO4)2, RbCr(SO4)2 and KAl(SO4)2 are characterized by X-ray and neutron powder diffraction at temperatures between 1.4 and 773 K. The compounds all crystallize in…

材料科学 · 物理学 2009-02-24 D. V. West , Q. Huang , H. W. Zandbergen , T. M. McQueen , R. J. Cava

We report the magnetization, ac susceptibility, and specific heat of optically float-zoned single crystals of CePdAl$_{3}$. In comparison to the properties of polycrystalline CePdAl$_{3}$ reported in the literature, which displays a…

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