相关论文: Impact of single-particle compressibility on the f…
The phase behavior of colloidal particles embedded in a binary fluid is influenced by wetting layers surrounding each particle. The free energy of the fluid film depends on its morphology, i.e., on size, shape and connectivity. Under rather…
We study the thermodynamics of binary mixtures with the volume fraction of the minority component less than the amount required to form a flat interface and show that the surface tension dominated equilibrium phase of the mixture forms a…
We report a theoretical study of ion size effect on various properties in a soft nanochannel with pH-dependent charge density. We develop a free energy based mean-field theory taking into account ion size as well as pH-dependence of charged…
In experimental systems, colloidal particles are virtually always at least somewhat polydisperse, which can have profound effects on their ability to crystallize. Unfortunately, accurately predicting the effects of polydispersity on phase…
The rheological properties of suspensions of bubbles in yield stress fluids are investigated through experiments on model systems made of monodisperse bubbles dispersed in concentrated emulsions. Thanks to this highly tunable system, the…
Microgels are complex macromolecules. These colloid-sized polymer networks possess internal degrees of freedom and, depending on the polymer(s) they are made of, can acquire a responsiveness to variations of the environment (temperature,…
Addition of particles to a viscoelastic suspension dramatically alters the properties of the mixture, particularly when it is sheared or otherwise processed. Shear-induced stretching of the polymers results in elastic stress that causes a…
It is theoretically shown that the excess liquid-liquid interfacial tension between two electrolyte solutions as a function of the ionic strength I behaves asymptotically as O(- I^0.5) for small I and as O(+- I) for large I. The former…
We develop a theory based on the method of collective variables to study the vapor-liquid equilibrium of asymmetric ionic fluids confined in a disordered porous matrix. The approach allows us to formulate the perturbation theory using an…
A new modified Poisson-Boltzmann equation accounting for the finite size of the ions valid for realistic salt-free concentrated suspensions has been derived, extending the formalism developed for pure salt-free suspensions [Roa et al.,…
We have studied experimentally particle suspension when injecting a gas at the bottom of an immersed granular layer confined in a Hele-Shaw cell. This work focuses on the dynamics of particles slightly denser than the surrounding fluid. The…
Slowly sheared particulate media like sand and suspensions flow heterogeneously as they yield via narrow shear bands where most of the strain is accumulated. Understanding shear band localization from microscopics is still a major…
Osmotic pressure is the driving force for the swelling of hydrogels. The hydrogel osmotic pressure can be decomposed into two parts: the mixing part due to polymer-solvent interaction and the elastic part due to polymer chain stretching.…
We explore the pressure dependence of a set of properties of simple monohydric alcohols, namely of methanol, ethanol and 1-propanol, by using isobaric-isothermal molecular dynamics computer simulations. A recently proposed united atom,…
The phase behavior of helical packings of thermoresponsive microspheres inside glass capillaries is studied as a function of volume fraction. Stable packings with long-range orientational order appear to evolve abruptly to disordered states…
We present experimental measurements of dynamical heterogeneities in a dense system of microgel spheres, sheared at different rates and at different packing fractions in a microfluidic channel, and visualized with high speed digital video…
Soft particles display highly versatile properties with respect to hard colloids, even more so at fluid-fluid interfaces. In particular, microgels, consisting of a cross-linked polymer network, are able to deform and flatten upon adsorption…
We study numerically how multiple deformable capsules squeeze into a constriction. This situation is largely encountered in microfluidic chips designed to manipulate living cells, which are soft entities. We use fully three-dimensional…
From a reanalysis of the published literature, the low-shear viscosity of suspensions of hard spheres is shown to have a dynamic crossover in its concentration dependence, from a stretched exponential at lower concentrations to a power law…
(Shortened) Thermal instability of partially ionized plasma is investigated by linear perturbation analysis. According to the previous studies under the one fluid approach, the thermal instability is suppressed due to the magnetic pressure.…