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相关论文: $B\,^1\Sigma^{+}_{u}$ and $EF\,^{1}\Sigma^{+}_{g}$…

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An extensive survey of the D2 absorption spectrum has been performed with the high-resolution VUV Fourier-transform spectrometer of the DESIRS beamline at the SOLEIL synchrotron. The frequency range of 90 000-119 000 cm-1 covers the full…

An optimal set of 1050 rovibronic energy levels for 35 triplet electronic states of $D_2$ has been obtained by means of a statistical analysis of all available wavenumbers of triplet-triplet rovibronic transitions studied in emission,…

光学 · 物理学 2008-02-08 B. P. Lavrov , I. S. Umrikhin

Optimal set of 1050 rovibronic energy levels for 35 triplet electronic states of $D_2$ has been obtained by means of a statistical analysis of all available wavenumbers of triplet-triplet rovibronic transitions studied in emission,…

光学 · 物理学 2009-11-13 B. P. Lavrov , I. S. Umrikhin

Accurate $EF{}^1\Sigma^+_g-X{}^1\Sigma^+_g$ transition energies in molecular hydrogen were determined for transitions originating from levels with highly-excited vibrational quantum number, $v=11$, in the ground electronic state.…

原子物理 · 物理学 2016-09-23 T. Madhu Trivikram , M. L. Niu , P. Wcisło , W. Ubachs , E. J. Salumbides

Accurate experimental values for the vibrational ground tone or fundamental vibrational energy splitting of H$_2$, HD, and D$_2$ are presented. Absolute accuracies of $2\times10^{-4}$ cm$^{-1}$ are obtained from Doppler-free laser…

Recently a high precision spectroscopic investigation of the EF^1\Sigma_g^+ - X^1\Sigma_g^+ system of molecular hydrogen was reported yielding information on QED and relativistic effects in a sequence of rotational quantum states in the…

原子与分子团簇 · 物理学 2013-01-04 G. D. Dickenson , E. J. Salumbides , M. Niu , Ch. Jungen , S. C. Ross , W. Ubachs

The double minimum E$^1\Sigma^{+}_{\mathrm{u}}$ state in caesium dimer was investigated by analysing spectra of the E$^1\Sigma^{+}_{\mathrm{u}}$ $\leftarrow$ X$^1\Sigma^{+}_{\mathrm{g}}$ band system, simplified by polarisation labelling. A…

原子物理 · 物理学 2025-01-10 W. Jastrzebski , P. Kowalczyk , J. Szczepkowski , A. Pashov

We report a systematic study of the C(2)$^1\Pi_u$ electronic state in rubidium dimer, observed in polarization labelling spectroscopy experiment through the C $\leftarrow$ X$^{1}\Sigma^{+}_{g}$ transitions recorded under rotational…

化学物理 · 物理学 2022-07-27 Asen Pashov , Pawel Kowalczyk , Jacek Szczepkowski , Wlodzimierz Jastrzebski

An analytical representation for the potential energy curve for the ground state $X^1\Sigma^+$ of the hydrogen fluoride molecule (HF) is presented in the frame of the Born-Oppenheimer approximation. The analytical expression for the…

化学物理 · 物理学 2021-10-29 Laura E. Angeles Gantes , Horacio Olivares-Pilón

The 4503 rovibronic term values belonging to the mutually perturbed $A^1\Sigma^+_u$ and $b^3\Pi_u$ states of Cs$_2$ were extracted from laser induced fluorescence (LIF) $A\sim b\rightarrow X^1\Sigma^+_g$ Fourier transform spectra with the…

原子物理 · 物理学 2019-10-23 A. Znotins , A. Kruzins , M. Tamanis , R. Ferber , E. A. Pazyuk , A. V. Stolyarov , A. Zaitsevskii

Precision measurements are performed on highly excited vibrational quantum states of molecular hydrogen. The $v=12, J=0-3$ rovibrational levels of H$_2$ ($X^1\Sigma_g^+$), lying only $2000$ cm$^{-1}$ below the first dissociation limit, were…

原子物理 · 物理学 2015-09-30 M. L. Niu , E. J. Salumbides , W. Ubachs

We present high-precision non-relativistic variational calculations of bound vibrational-rotational state energies for the $H_2^+$ and $D_2^+$ molecular ions in each of the lowest electronic states of $\Sigma_g$, $\Sigma_u$, and $\Pi_u$…

原子物理 · 物理学 2007-05-23 J. M. Taylor , Zong-Chao Yan , A. Dalgarno , J. F. Babb

We report the potential energy curve, the diagonal Born-Oppenheimer, non-adiabatic mass, relativistic, and leading-order QED corrections for the ground electronic state of the helium dimer cation; the higher-order QED and finite-nuclear…

化学物理 · 物理学 2026-02-25 Edit Mátyus , Ádám Margócsy

Rotationally-resolved Fourier-transform spectra of laser-induced fluorescence (LIF) $A^1\Sigma^+_u\sim b^3\Pi_u \rightarrow X^1\Sigma^+_g$ of K$_2$ molecules were recorded and analyzed yielding 4053 term values of spin-orbit (SO) coupled $A…

原子物理 · 物理学 2023-12-29 I. Klincare , A. Lapins , M. Tamanis , R. Ferber , A. Zaitsevskii , E. A. Pazyuk , A. V. Stolyarov

The D^1\Pi_u - X^1\Sigma_g^+ absorption system of molecular deuterium has been re-investigated using the VUV Fourier -Transform (FT) spectrometer at the DESIRS beamline of the synchrotron SOLEIL and photon-induced fluorescence spectrometry…

The Ti:Saphire laser operated within 13800 - 11800 cm$^{-1}$ range was used to excite the $c^3\Sigma^+$ state of KCs molecule directly from the ground $X^1\Sigma^+$ state. The laser-induced fluorescence (LIF) spectra of the $c^3\Sigma^+…

State-of-the-art ab initio techniques have been applied to compute the potential energy curves for the electronic states in the A^1\Sigma_u^+, c^3\Pi_u, and a^3\Sigma_u^+ manifold of the strontium dimer, the spin-orbit and nonadiabatic…

化学物理 · 物理学 2012-05-30 Wojciech Skomorowski , Filip Pawlowski , Christiane P. Koch , Robert Moszynski

The $A^1\Sigma^+_u$ - $X^1\Sigma^+_g$ UV spectrum of Mg$_2$ has been investigated with high resolution employing Fourier-transform spectroscopy and laser excitation. Computer simulation and fit of line positions to the overlapping…

原子物理 · 物理学 2014-10-20 Horst Knöckel , Steffen Rühmann , Eberhard Tiemann

Energy levels of the four lowest bands in 160,162,164Dy and 168Er, B(E2) transition strengths between the levels, and the B(M1) strength distribution of the ground state, all calculated within the framework of pseudo-SU(3) model, are…

核理论 · 物理学 2007-05-23 J. P. Draayer , G. Popa , J. G. Hirsch

After the study of the three body molecular system H$_2^+$ ({\it J. Phys. B: At. Mol. Opt. Phys.} {\bf 45} 065101), its isotopomer, the deuterium molecular ion D$_2^+$ is studied. The three-body Schr\"odinger equation is solved using the…

原子物理 · 物理学 2015-06-15 Horacio Olivares Pilón
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