相关论文: Methane, Carbon Monoxide, and Ammonia in Brown Dwa…
Cold brown dwarfs are excellent analogs of widely separated, gas giant exoplanets, and provide insight into the potential atmospheric chemistry and physics we may encounter in objects discovered by future direct imaging surveys. We present…
The atmospheric pressure-temperature profiles for transiting giant planets cross a range of chemical transitions. Here we show that the particular shape of these irradiated profiles for warm giant planets below 1300 K lead to striking…
We explore CO-CH4 quench kinetics in the atmospheres of substellar objects using updated time-scale arguments, as suggested by a thermochemical kinetics and diffusion model that transitions from the thermochemical-equilibrium regime in the…
Evidence of disequilibrium chemistry due to vertical mixing in the atmospheres of many T and Y-dwarfs has been inferred due to enhanced mixing ratios of CO and reduced NH$_3$. Atmospheric models of planets and brown dwarfs typically…
Almost all planetary atmospheres are affected by disequilibrium chemical processes. In this paper we introduce our recently developed Chemical Kinetic Model (\texttt{ChemKM}). We show that the results of our HD189733b model are in good…
Chemical equilibrium considerations suggest that, assuming solar elemental abundances, carbon on HD 209458b is sequestered primarily as carbon monoxide (CO) and methane (CH4). The relative mole fractions of CO(g) and CH4(g) in chemical…
High-resolution transmission spectroscopy of the warm gas-giant WASP-69b has revealed the presence of H2O, CO, CH4, NH3, and C2H2 in its atmosphere. This study investigates the impact of vertical diffusion and photochemistry on its…
The relative abundance of deuterium and hydrogen is a potent tracer of planet formation and evolution. Jupiter and Saturn have protosolar atmospheric D/H ratios, a relic of substantial gas accretion from the nebula, while the atmospheres of…
By generalizing the theory of convection to any type of thermal and compositional source terms (diabatic processes), we show that thermohaline convection in Earth oceans, fingering convection in stellar atmospheres, and moist convection in…
We study the abundances of complex carbon-bearing molecules in the oxygen-rich dust- forming atmospheres of Brown Dwarfs and giant gas planets. The inner atmospheric re- gions that form the inner boundary for thermochemical gas-phase models…
Carbon monoxide and ammonia have been detected in the spectrum of Gl 229B at abundances that differ substantially from those obtained from chemical equilibrium. Vertical mixing in the atmosphere is a mechanism that can drive slowly reacting…
Brown dwarf spectra are rich in information revealing of the chemical and physical processes operating in their atmospheres. We apply a recently developed atmospheric retrieval tool to an ensemble of late T-dwarf (600-800K) near infrared…
We present a comprehensive study of the abundance of carbon dioxide in exoplanetary atmospheres in hot, hydrogen-dominated atmospheres. We construct novel analytical models of systems in chemical equilibrium that include carbon monoxide,…
We present novel, analytical, equilibrium-chemistry formulae for the abundances of molecules in hot exoplanetary atmospheres that include the carbon, oxygen and nitrogen networks. Our hydrogen-dominated solutions involve acetylene…
Chemical disequilibrium has recently become a relevant topic in the study of the atmospheres of of transiting extrasolar planets, brown dwarfs, and directly imaged exoplanets. We present a new way of assessing whether or not a Jovian-like…
We calculated an atmospheric grid for hot mini-Neptune and giant exoplanets, that links astrophysical observable parameters- orbital distance and stellar type- with the chemical atmospheric species expected. The grid can be applied to…
Brown dwarfs that are short period ($<10\,$day) companions to actively flaring M dwarfs may provide a context to directly observe flare-driven photochemistry and structural changes in an extrasolar planet-like atmosphere. To assess the…
The atmospheres of brown dwarfs have been long observed to exhibit a multitude of non-equilibrium chemical signatures and spectral variability across the L, T and Y spectral types. We aim to investigate the link between the large-scale 3D…
We have developed 1-D photochemical and thermochemical kinetics and diffusion models for the transiting exoplanets HD 189733b and HD 209458b to study the effects of disequilibrium chemistry on the atmospheric composition of "hot Jupiters."…
Measurements of the C/O ratio in brown dwarfs are lacking, in part due to past models adopting solar C/O only. We have expanded the ATMO 2020 atmosphere model grid to include non-solar metallicities and C/O ratios in the T dwarf regime. We…