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While it is well known that complete positivity guarantees the fulfilment of the second law of thermodynamics, its possible violations have never been proposed as a check of the complete positivity of a given open quantum dynamics. We…

量子物理 · 物理学 2015-10-28 G. Argentieri , F. Benatti , R. Floreanini , M. Pezzutto

Several models of quantum open systems are known at present to violate, according to principles of the standard quantum theory of open systems, the second law of thermodynamics. Here, a new and rather trivial model of another type is…

统计力学 · 物理学 2007-05-23 V. Capek

The validity of the Second Law of thermodynamics, indisputable in the macroscopic world, is challenged at the mesoscopic level: a mesoscopic isolated system, possessing spatial dimensions of the order of a few microns, is capable, as shown…

经典物理 · 物理学 2007-05-23 B. Crosignani , P. Di Porto , C. Conti

It is argued the the idea of a single temperature-like variable, introduced in [1], which enters a generalized second law for Markovian open system in non-equilibrium environment is not sufficient for a consistent and useful thermodynamic…

统计力学 · 物理学 2025-03-28 Robert Alicki

The second law of thermodynamics states that entropy production in macroscopic systems is non-negative, reaching zero only at thermodynamic equilibrium. As a corollary, this implies that the state trajectory of macroscopic systems is…

统计力学 · 物理学 2025-01-30 O. Politano , Alejandro L. Garcia , F. Baras , M. Malek Mansour

The second law of ordinary thermodynamics and the second law of steady state thermodynamics, as proposed by Oono and Paniconi, are investigated from the microscopic point of view for the open quantum system. Based on the H-theorem of…

统计力学 · 物理学 2007-05-23 Satoshi Yukawa

All physical theories should obey the second law of thermodynamics. However, existing proposals to describe the dynamics of hybrid classical-quantum systems either violate the second law or lack a proof of its existence. Here we rectify…

量子物理 · 物理学 2025-07-29 Isaac Layton , Harry J. D. Miller

Some works have appeared in recent accredited literature considering the possibility of macroscopic violations of the second law in simulated as well as really executed experiments. We argue the inexistence of such violations in experiments…

综合物理 · 物理学 2018-05-09 Leonardo Chiatti

We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open…

量子物理 · 物理学 2022-05-31 Alessandra Colla , Heinz-Peter Breuer

We present a short derivation and discussion of the master equation for an open quantum system weakly coupled to a heat bath and then its generalization to the case of with periodic external driving based on the Floquet theory. Further, a…

量子物理 · 物理学 2012-05-22 Robert Alicki , David Gelbwaser-Klimovsky , Gershon Kurizki

Fluctuations of thermodynamic observables, such as heat and work, contain relevant information on the underlying physical process. These fluctuations are however not taken into account in the traditional laws of thermodynamics. While the…

量子物理 · 物理学 2022-05-25 Timo Kerremans , Peter Samuelsson , Patrick P. Potts

We present a Gedankenexperiment that leads to a violation of detailed balance if quantum mechanical transition probabilities are treated in the usual way by applying Fermi's "golden rule". This Gedankenexperiment introduces a collection of…

量子物理 · 物理学 2020-09-21 Daniel Braak , Jochen Mannhart

We show that systems with negative specific heat can violate the zeroth law of thermodynamics. By both numerical simulations and by using exact expressions for free energy and microcanonical entropy it is shown that if two systems with the…

统计力学 · 物理学 2009-11-13 A. Ramirez-Hernandez , H. Larralde , F. Leyvraz

Uncertainty relations state that there exist certain incompatible measurements, to which the outcomes cannot be simultaneously predicted. While the exact incompatibility of quantum measurements dictated by such uncertainty relations can be…

量子物理 · 物理学 2015-06-05 Esther Hänggi , Stephanie Wehner

Thermodynamics entails a set of mathematical conditions on quantum Markovian dynamics. In particular, strict energy conservation between the system and environment implies that the dissipative dynamical map commutes with the unitary system…

量子物理 · 物理学 2021-04-07 Roie Dann , Ronnie Kosloff

The authors of Ref. [1] claim to have experimental verification of violations of the second law of thermodynamics based on the assertions: (i) "for large systems and over long times the entropy production rate is necessarily positive"; (ii)…

量子物理 · 物理学 2007-06-20 Elias P. Gyftopoulos

The second law of thermodynamics constitutes a fundamental principle of physics, precluding the existence of perpetual motion machines and providing a natural definition of the arrow of time. Its scope extends across virtually all areas of…

广义相对论与量子宇宙学 · 物理学 2025-10-21 Alejandro Corichi , Omar Gallegos

Quantum collision models allow for the dynamics of open quantum systems to be described by breaking the environment into small segments, typically consisting of non-interacting harmonic oscillators or two-level systems. This work introduces…

量子物理 · 物理学 2025-10-10 Anton Corr , Stefano Cusumano , Gabriele De Chiara

The requirement of complete positivity is very often regarded as a fundamental consistency condition for the description of open quantum dynamics. We critically examine this requirement and discuss both its physical motivations and its…

量子物理 · 物理学 2026-05-19 Fabio Benatti , Dariusz Chruściński , Saverio Pascazio

We take the perspective of open quantum systems and examine from their nonequilibrium dynamics the conditions when the physical quantities, their relations and the laws of thermodynamics become well defined and viable for quantum many body…

量子物理 · 物理学 2018-01-30 Jen-Tsung Hsiang , C. H. Chou , Y. Subaşi , B. L. Hu
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