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In order to tune the magnetic properties of the cleavable high-Curie temperature ferromagnet Fe$_{5-x}$GeTe$_2$, the effect of increasing the electron count through arsenic substitution has been investigated. Small additions of arsenic (2.5…

材料科学 · 物理学 2021-11-15 Andrew F. May , Jiaqiang Yan , Raphael Hermann , Mao-Hua Du , Michael A. McGuire

The intermetallic $\tau_{11}$ Al$_4$Fe$_{1.7}$Si phase is of interest for high-temperature structural application due to its combination of low density and high strength. We determine the crystal structure of the $\tau_{11}$ phase through a…

The electronic, magnetic, and thermodynamic properties of ordered and chemically disordered FeRh alloy is studied using ab-initio methods. The equiatomic Fe$_{50}$Rh$_{50}$ composition is reported for both ordered and disordered phases.…

材料科学 · 物理学 2022-08-01 Greeshma R , Rudra Banerjee

The non-stoichiometric Fe$_2$P-type (FeMnP$_{0.5}$Si$_{0.5}$)$_{1-x}$(FeV)$_{x}$ alloys ( $x=0, 0.01$, $0.02$, and $0.03$) have been investigated as potential candidates for magnetic refrigeration near room temperature. The magnetic…

X-ray diffraction experiments were performed on polycrystalline and single-crystal specimens of Ce$_{2}$Fe$_{17}$ at temperatures between 10 K and 300 K. Below $T_{\mathrm{t}}$ = 118$\pm$2 K, additional weak superstructure reflections were…

The Ce$_2$Fe$_{17}$ intermetallic compound has been studied intensely for several decades; its low-temperature state is reported experimentally either as ferromagnetic or antiferromagnetic by different authors, with a measured ordering…

材料科学 · 物理学 2022-02-17 Alena Vishina , Olle Eriksson , Olga Yu. Vekilova , Anders Bergman , Heike C. Herper

Here, we provide a detailed study of the crystal structure and physical properties of the recently discovered vdW ferromagnet FePd$_2$Te$_2$. We find this compound has a relatively wide width of formation, and grow single crystals with…

Connections between crystal chemistry and critical temperature $T_c$ have been in the focus of superconductivity, one of the most widely studied phenomena in physics, chemistry and materials science alike. In most Fe-based superconductors,…

A simple two-band model is used to describe the magnitude and temperature dependence of the magnetic susceptibility, Hall coefficient and Seebeck data from undoped and Co doped BaFe2As2. Overlapping rigid parabolic electron and hole bands…

超导电性 · 物理学 2010-02-26 B. C. Sales , M. A. McGuire , A. S. Sefat , D. Mandrus

We report the crystal growth and structural, magnetic, conductivity, and specific heat investigations of Rb(1-x)Fe(2-y)Se2 single crystals with varying stoichiometry prepared by self-flux and Bridgman methods. The system exhibits a strongly…

超导电性 · 物理学 2011-11-01 V. Tsurkan , J. Deisenhofer , A. Günther , H. -A. Krug von Nidda , S. Widmann , A. Loidl

Motivated by the recent observations of incommensurate magnetic order and electric polarization in YBaCuFeO5 up to temperatures TN2 as high as 230K [1,2] we report here for the first time a model for the incommensurate magnetic structure of…

We have successfully synthesized a new layered iron oxychalcogenide BaFe2OSe2 single crystal. This compound is built up of Ba and Fe-Se(O) layers alternatively stacked along the c-axis. The Fe-Se(O) layers contain double chains of…

超导电性 · 物理学 2015-06-05 Hechang Lei , Hyejin Ryu , John Warren , A. I. Frenkel , V. Ivanovski , B. Cekic , C. Petrovic

Three novel precipitation strengthened bcc alloys which exhibit a smooth microstructural gradient with composition have been fabricated in bulk form by induction casting. All three alloys are comprised of a mixture of disordered A2-(Fe, Cr)…

材料科学 · 物理学 2021-03-23 Silas Wolff-Goodrich , Sebastian Haas , Uwe Glatzel , Christian Liebscher

The crystal and magnetic structures of the orthorhombic e-Fe2O3 have been studied by simultaneous Rietveld refinement of X-ray and neutron powder diffraction data in combination with Mossbauer spectroscopy, as well as magnetisation and heat…

Dark blue single crystals of Al$_{1.75}^{3+}$ Ti$_{1.0}^{4+}$ Ti$_{0.25}^{3+}$O$_5$ were grown with a novel synthesis method based on the reaction of a Ti3+/Ti4+ containing langbeinite melt and Al$_2$O$_3$. The obtained needles crystallize…

材料科学 · 物理学 2022-12-02 Davor Tolj , WenHua Bi , Yong Liu , Ivica Zivkovic , Henrik M. Ronnow , Arnaud Magrez

The compound BaFe2Se3 (Pnma) has been synthesized in the form of single crystals with the average composition Ba0.992Fe1.998Se3. The Moessbauer spectroscopy used for investigation of the valence states of Fe in this compound at temperature…

The Fe-based superconducting KxFe2-ySe2 (0.6 {\leg} x {\leg} 1, 0.2{\leg} y {\leg} 0.4) compounds, unlike the well-known RFe2As2 (R = Ba, Sr, Ca) superconductors, contain complex structural features and notable physical properties, such as…

超导电性 · 物理学 2011-04-29 J. Q. Li , Y. J. Song , H. X. Yang , Z. Wang , H. L. Shi , G. F. Chen , Z. W. Wang , Z. Chen , H. F. Tian

The intersection between nonsymmorphic symmetry and electronic correlations has emerged as a platform for topological Kondo semimetallic states and unconventional spin textures. Here we report the synthesis of nonsymmorphic…

Structural, magnetic, electrical transport, and heat capacity data are reported for single crystals of TlFe1.6Se2. This compound crystallizes in a tetragonal structure similar to the ThCr2Si2 structure, but with vacancies in the Fe layer.…

The crystal and magnetic structures of AlFe2B2 have been studied with a combination of X-ray and neutron diffraction and electronic structure calculations. The magnetic and magnetocaloric properties have been investigated by magnetisation…