相关论文: Ubiquitous argonium (ArH$^+$) in the diffuse inter…
We present a general parameter study, in which the abundance of interstellar argonium (ArH$^+$) is predicted using a model for the physics and chemistry of diffuse interstellar gas clouds. Results have been obtained as a function of UV…
Argonium has recently been detected as a ubiquitous molecule in our Galaxy. Model calculations indicate that its abundance peaks at molecular fractions in the range of 1E-4 to 1E-3 and that the observed column densities require high values…
Along several sight lines within the Milky Way ArH+ has been ubiquitously detected with only one detection in extragalactic environments, namely along two sight lines in the red shift z=0.89 absorber towards the lensed blazar PKS 1830-211.…
There is a robust polyatomic chemistry in diffuse, partially-molecular interstellar gas that is readily accessible in absorption at radio/mm/sub-mm wavelengths. Accurate column densities are derived owing to the weak internal excitation, so…
Surprisingly large column densities of H3+ have been detected using infrared absorption spectroscopy in seven diffuse cloud sightlines (Cygnus OB2 12, Cygnus OB2 5, HD 183143, HD 20041, WR 104, WR 118, and WR 121), demonstrating that H3+ is…
Observations of CO+ suggest column densities on the order 10^12 cm^-2 that can not be reproduced by many chemical models. CO+ is more likely to be destroyed than excited in collisions with hydrogen. An anomalous excitation mechanism may…
One of the surprises of the Herschel mission was the detection of ArH+ towards the Crab Nebula in emission and in absorption towards strong Galactic background sources. Although these detections were limited to the first quadrant of the…
The transition between atomic and molecular hydrogen is associated with important changes in the structure of interstellar clouds, and marks the beginning of interstellar chemistry. Because of the relatively simple networks controlling…
Recent advances in identifying giant molecular filaments in galactic surveys allow us to study the interstellar material and its dense, potentially star forming phase on scales comparable to resolved extragalactic clouds. Two large…
We report the first detection of chloronium, H$_2$Cl$^+$, in the interstellar medium, using the HIFI instrument aboard the \emph{Herschel} Space Observatory. The $2_{12}-1_{01}$ lines of ortho-H$_2^{35}$Cl$^+$ and ortho-H$_2^{37}$Cl$^+$ are…
We present high S/N measurements of the H I Ly alpha absorption line toward 16 Galactic targets which are at distances between approximately 190 and 2200 pc, all beyond the wall of the Local Bubble. We describe the models used to remove…
Star formation activity in molecular clouds is often found to be correlated with the amount of material above a column density threshold of $\sim 10^{22} \, {\rm cm^{-2}}$. Attempts to connect this column density threshold to a ${\it…
Context. Radio frequency molecular absorption lines appear along sight lines with AV well below 1 mag, revealing the presence of H2 in diffuse gas even when 2.6mm CO emission is absent. Aims. We discuss absorption lines of HCO+, C2H, HCN,…
Molecular hydrogen being unobservable in cold molecular clouds, the column density measurements of molecular gas currently rely either on dust emission observation in the far-IR or on star counting. (Sub-)millimeter observations of numerous…
We have constructed three-dimensional models for the equilibrium abundance of molecular hydrogen within diffuse interstellar clouds of arbitrary geometry that are illuminated by ultraviolet radiation. The position-dependent photo-…
Recent submillimeter and far-infrared wavelength observations of absorption in the rotational ground-state lines of various simple molecules against distant Galactic continuum sources have opened the possibility of studying the chemistry of…
This is the first in a series of three papers describing a project with the Cosmic Origins Spectrograph on the Hubble Space Telescope to measure abundances of the neutral interstellar medium (ISM) in a sample of 9 nearby star-forming…
The sheer interstellar abundance of helium makes any bound molecules or complexes containing it of potential interest for astrophysical observation. This work utilizes high-level and trusted quantum chemical techniques to predict the…
The Atacama Pathfinder Experiment (APEX) 12m telescope was used to observe the N=1-0, J=0-1 ground state transitions of OH+ at 909.1588 GHz with the CHAMP+ heterodyne array receiver. Two blended hyperfine structure transitions were detected…
We present a theoretical investigation of the chemistry of fluorine-bearing molecules in diffuse and dense interstellar gas clouds. The chemistry of interstellar fluorine is qualitatively different from that of any other element, because -…