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We present a density functional study of graphene adhesion on a realistic SiO$_2$ surface taking into account van der Waals (vdW) interactions. The SiO$_2$ substrate is modeled at the local scale by using two main types of surface defects,…

介观与纳米尺度物理 · 物理学 2011-08-30 A. N. Rudenko , F. J. Keil , M. I. Katsnelson , A. I. Lichtenstein

The adsorption of fluorine, chlorine, bromine, and iodine diatomic molecules on graphene has been investigated using density functional theory with taking into account nonlocal correlation effects by means of vdW-DF approach. It is shown…

介观与纳米尺度物理 · 物理学 2010-09-15 A. N. Rudenko , F. J. Keil , M. I. Katsnelson , A. I. Lichtenstein

We investigate theoretically the adhesion and electronic properties of graphene on a muscovite mica surface using the density functional theory (DFT) with van der Waals (vdW) interactions taken into account (the vdW-DF approach). We found…

介观与纳米尺度物理 · 物理学 2011-01-25 A. N. Rudenko , F. J. Keil , M. I. Katsnelson , A. I. Lichtenstein

Both single layer Ga2O3 (SLGO) and graphene are attractive due to their respective electronic and mechanical properties such as wide bandgap and high electrical conductivity. Bringing them together by using van der Waals force to form a…

材料科学 · 物理学 2022-01-21 Lijie Li

The DFT/vdW-WF2s1 method, recently developed to include the van der Waals interactions in the Density Functional Theory and describe adsorption processes on metal surfaces by taking metal-screening effects into account, is applied to the…

材料科学 · 物理学 2015-06-11 Pier Luigi Silvestrelli , Alberto Ambrosetti

Recent atomic force microscopy (AFM) experiments~[ACS Nano {\bf 2014}, 8, 12410-12417] conducted on graphene-coated SiO$_2$ demonstrated that monolayer graphene (G) can effectively screen dispersion van der Waals (vdW) interactions deriving…

材料科学 · 物理学 2018-06-13 Alberto Ambrosetti , Pier Luigi Silvestrelli

Wetting behaviour of surfaces is believed to be affected by van der Waals (vdW) forces, however, there is no clear demonstration of this. With the isolation of two-dimensional vdW layered materials it is possible to test this hypothesis. In…

Intralayer deformation in van der Waals (vdW) heterostructures is generally assumed to be negligible due to the weak nature of the interactions between the layers, especially when the interfaces are found incoherent. In the present work,…

材料科学 · 物理学 2018-07-18 Benoit Van Troeye , Aurélien Lherbier , Jean-Christophe Charlier , Xavier Gonze

We use density functional theory (DFT) with a recently developed van der Waals density functional (vdW-DF) to study the adsorption of graphene on Al, Cu, Ag, Au, Pt, Pd, Co and Ni(111) surfaces. In constrast to the local density…

介观与纳米尺度物理 · 物理学 2015-05-14 M. Vanin , J. J. Mortensen , A. K. Kelkkanen , J. M. Garcia-Lastra , K. S. Thygesen , K. W. Jacobsen

We performed density functional theory (DFT) calculations for a bi-layered heterostructure combining a graphene layer with a MoS2 layer with and without intercalated Li atoms. Our calculations demonstrate the importance of the van der Waals…

材料科学 · 物理学 2015-02-27 Towfiq Ahmed , N. A. Modine , Jian-Xin Zhu

We investigate energetic and electronic properties of TiS2 , an archetypal van der Waals (vdW) material, from first principles, in the framework of the Density Functional Theory (DFT). In this system a recent experimental study showed a…

材料科学 · 物理学 2020-11-26 Ricci Matteo , Ambrosetti Alberto , Silvestrelli Pier Luigi

There is enormous recent interest in weak, van der Waals-type (vdW) interactions due to their fundamental relevance for two-dimensional materials and the so-called vdW heterostructures. Tackling this problem using computer simulation is…

材料科学 · 物理学 2019-08-20 Fabian Schulz , Peter Liljeroth , Ari Paavo Seitsonen

Adhesion is a key issue for researchers of various fields, it is therefore of uppermost importance to understand the parameters that are involved. Commonly, only surface parameters are employed to determine the adhesive forces between…

材料科学 · 物理学 2012-08-22 Peter Loskill , Hendrik Hähl , Thomas Faidt , Samuel Grandthyll , Frank Müller , Karin Jacobs

We have studied two interchange layer systems, (i) free standing partly hydrogenated graphene (graphone), and (ii) graphone on the Nickel (111) surface, to assess various density functional theory based computational schemes incorporating…

材料科学 · 物理学 2022-04-26 Magdalena Birowska , Maciej Marchwiany , Claudia Draxl , Jacek. A. Majewski

With first-principles DFT calculations, the interaction between graphene and SiO2 surface has been analyzed by constructing the different configurations based on {\alpha}-quartz and cristobalite structures. The single layer graphene can…

材料科学 · 物理学 2015-05-28 X. F. Fan , W. T. Zheng , Z. X. Shen , Jer-Lai Kuo

Understanding the interaction of organic molecules with TiO2 surfaces is important for a wide range of technological applications. While density functional theory (DFT) calculations can provide valuable insight about these interactions,…

材料科学 · 物理学 2015-06-23 Marcus Tillotson , Peter Brett , Roger A. Bennett , Ricardo Grau-Crespo

The theoretical description of sparse matter attracts much interest, in particular for those ground-state properties that can be described by density functional theory (DFT). One proposed approach, the van der Waals density functional…

It is shown that it is now possible to include van der Waals interactions via a nonempirical implementation of density functional theory to describe the correlation energy in electronic structure calculations on infinite systems of no…

This paper reviews the theoretical work undertaken using density functional theory (DFT) to explore graphene's interactions with its surroundings. We look at the impact of substrates, gate dielectrics and edge effects on the properties of…

介观与纳米尺度物理 · 物理学 2012-07-31 Priyamvada Jadaun , Bhagawan R. Sahu , Leonard F. Register , Sanjay K. Banerjee

A van der Waals (vdW) density functional was implemented in the mixed basis approach previously developed for studying two dimensional systems, in which the vdW interaction plays an important role. The basis functions here are taken to be…

计算物理 · 物理学 2017-12-27 Chung-Yuan Ren , Yia-Chung Chang , Chen-Shiung Hsue
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