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Dynamic heterogeneity as one of the most important properties in supercooled liquids has been found for several decades. However, its structural origin remains open for many systems. Here, we propose a new structural parameter to…

无序系统与神经网络 · 物理学 2015-10-16 S. P. Pan , S. D. Feng , J. W. Qiao , W. M. Wang , J. Y. Qin

A few years ago it was showed that some systems that have very similar local structure, as quantified by the pair correlation function, exhibit vastly different slowing down upon supercooling [L. Berthier and G. Tarjus, Phys. Rev. Lett.…

软凝聚态物质 · 物理学 2015-06-17 Elijah Flenner , Hannah Staley , Grzegorz Szamel

We present the dynamic propensity distribution as an explicit measure of the degree to which the dynamics in a liquid over the time scale of structural relaxation is determined by the initial configuration. We then examine, for a binary…

统计力学 · 物理学 2009-01-27 Asaph Widmer-Cooper , Peter Harrowell

Glass-forming liquids grow dramatically sluggish upon cooling. This slowdown has long been thought to be accompanied by a growing correlation length. Characteristic dynamical and static length scales, however, have been observed to grow at…

无序系统与神经网络 · 物理学 2016-08-22 Patrick Charbonneau , Ethan Dyer , Jaehoon Lee , Sho Yaida

We use computer simulations to explore the manner in which the particle displacements on intermediate time scales in supercooled fluids correlate to their dynamic structural environment. The fluid we study, a binary mixture of hard spheres,…

软凝聚态物质 · 物理学 2010-05-11 William P. Krekelberg , Venkat Ganesan , Thomas M. Truskett

The dynamics of supercooled liquids slow down and become increasingly heterogeneous as they are cooled. Recently, local structural variables identified using machine learning, such as "softness", have emerged as predictors of local…

软凝聚态物质 · 物理学 2024-06-11 Sean A. Ridout , Andrea J. Liu

Using computer simulations, we show that the localized low frequency normal modes of a configuration in a supercooled liquid are strongly correlated with the irreversible structural reorganization of the particles within that configuration.…

软凝聚态物质 · 物理学 2011-09-08 Asaph Widmer-Cooper , Heidi Perry , Peter Harrowell , David R. Reichman

We discuss the spatiotemporal behavior of local density and its relation to dynamical heterogeneity in a highly supercooled liquid by using molecular dynamics simulations of a binary mixture with different particle sizes in two dimensions.…

软凝聚态物质 · 物理学 2015-03-20 Hayato Shiba , Takeshi Kawasaki

We numerically study the interplay between heterogeneous dynamics and properties of negatively curved regions of the potential energy surface in a model glassy system. We find that the unstable modes of saddles and quasi-saddles undergo a…

统计力学 · 物理学 2007-05-23 D. Coslovich , G. Pastore

One of the central problems of the liquid-glass transition is whether there is a structural signature that can qualitatively distinguish different dynamic behaviors at different degrees of supercooling. Here, we propose a novel structural…

软凝聚态物质 · 物理学 2015-09-24 Yan-Wei Li , You-Liang Zhu , Zhao-Yan Sun

Exploring structural order in disordered systems including liquids and glasses is an intriguing but challenging issue in condensed matter physics. Here we construct a new parameter based on the angular distribution function of particles and…

软凝聚态物质 · 物理学 2018-06-11 Xiunan Yang , Wei-Hua Wang , Ke Chen

The correlation between local structure and the propensity for structural rearrangements has been widely investigated in glass forming liquids and glasses. In this paper we use the excess two-body entropy $S_2$ and tetrahedrality $\n_{tet}$…

We find that the hierarchical organization of the potential energy landscape in a model supercooled liquid can be related to a change in the spatial distribution of soft normal modes. For groups of nearby minima, between which fast…

无序系统与神经网络 · 物理学 2014-03-17 Majid Mosayebi , Patrick Ilg , Asaph Widmer-Cooper , Emanuela Del Gado

We investigate experimentally the relationship between local structure and dynamical arrest in a quasi-2d colloidal model system which approximates hard discs. We introduce polydispersity to the system to suppress crystallisation. Upon…

软凝聚态物质 · 物理学 2017-12-27 Elisa Tamborini , C. Patrick Royall , Pietro Cicuta

Data-driven approaches to inferring the local structures responsible for plasticity in amorphous materials have made substantial contributions to our understanding of the failure, flow, and rearrangement dynamics of supercooled fluids. Some…

软凝聚态物质 · 物理学 2023-08-22 Tomilola M. Obadiya , Daniel M. Sussman

The use of probe molecules to extract the local dynamical and structural properties of complex dynamical systems is an age-old technique both in simulations and experiments. A lot of important information which is not immediately accessible…

软凝聚态物质 · 物理学 2021-03-30 Anoop Mutneja , Smarajit Karmakar

The relationship between the microscopic arrangement of molecules in a supercooled liquid and its slow dynamics at low temperature near glass transition is studied by Molecular Dynamics (MD) simulations. A Lennard-Jones liquid with…

软凝聚态物质 · 物理学 2009-11-13 Sneha Elizabeth Abraham , Biman Bagchi

As approaching the glass transition, particle motion in liquids becomes highly heterogeneous and regions with virtually no mobility coexist with liquid-like domains. This complex dynamics is believed to be responsible for different…

软凝聚态物质 · 物理学 2018-03-28 F. Puosi , N. Jakse , A. Pasturel

The relationship between structure and dynamics in glassy fluids remains an intriguing open question. Recent work has shown impressive advances in our ability to predict local dynamics using structural features, most notably due to the use…

软凝聚态物质 · 物理学 2023-04-19 Rinske M. Alkemade , Frank Smallenburg , Laura Filion

Supercooled liquids exhibit spatial heterogeneity in the dynamics of their fluctuating atomic arrangements. The length and time scales of the heterogeneous dynamics are central to the glass transition and influence nucleation and growth of…

材料科学 · 物理学 2018-05-09 Pei Zhang , Jason J. Maldonis , Ze Liu , Jan Schroers , Paul M. Voyles
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