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Structural investigations by means of transmission electron microscopy (TEM) on KFexSe2 with 1.5 \leq x \leq 1.8 have revealed a rich variety of microstructure phenomena, the KFe1.5Se2 crystal often shows a superstructure modulation along…

超导电性 · 物理学 2013-05-29 Z. Wang , Y. J. Song , H. L. Shi , Z. W. Wang , Z. Chen , H. F. Tian , G. F. Chen , J. G. Guo , H. X. Yang , J. Q. Li

The issue concerning the nature and the role of microstructural inhomogeneities in iron chalcogenide superconducting crystals of FeTe0.65Se0.35 and their correlation with transport properties of this system was addressed. Presented data…

The search for new superconducting materials has been spurred on by the discovery of iron-based superconductors whose structure and composition is qualitatively different from the cuprates. The study of one such material,…

The interplay between superconductivity, magnetism and crystal structure in iron-based superconductors is a topic of great interest amongst the condensed matter physics community as it is thought to be the key to understanding the…

The Fe-based superconducting KxFe2-ySe2 (0.6 {\leg} x {\leg} 1, 0.2{\leg} y {\leg} 0.4) compounds, unlike the well-known RFe2As2 (R = Ba, Sr, Ca) superconductors, contain complex structural features and notable physical properties, such as…

超导电性 · 物理学 2011-04-29 J. Q. Li , Y. J. Song , H. X. Yang , Z. Wang , H. L. Shi , G. F. Chen , Z. W. Wang , Z. Chen , H. F. Tian

The FeSe superconductor and its related systems have attracted much attention in the iron-based superconductors owing to their simple crystal structure and peculiar electronic and physical properties. The bulk FeSe superconductor has a…

超导电性 · 物理学 2015-06-24 Xu Liu , Lin Zhao , Shaolong He , Junfeng He , Defa Liu , Daixiang Mou , Bing Shen , Yong Hu , Jianwei Huang , X. J. Zhou

In this letter we show that superconducting Fe1.01Se undergoes a structural transition at 90 K from a tetragonal to an orthorhombic phase but that non-superconducting Fe1.03Se does not. Further, high resolution electron microscopy study at…

PbO-type Fe chalcogenide has been drawing much attention as the Fe-based superconductor with the most simple crystal structure. Whereas FeSe is an intrinsic superconductor, FeTe, while having a structure analogous to FeSe, exhibits…

超导电性 · 物理学 2011-05-27 Yoshikazu Mizuguchi , Yoshihiko Takano

In this paper, we address a number of outstanding issues concerning the nature and the role of magnetic inhomogenities in the iron chalcogenide system FeTe1-xSex and their correlation with superconductivity in this system. We report…

This article reviews recent experimental investigations on two binary Fe-chalcogenides: FeSe and Fe$_{1+y}$Te. The main focus is on synthesis, single crystal growth, chemical composition, as well as on the effect of excess iron on…

超导电性 · 物理学 2016-06-06 Sahana Rößler , Cevriye Koz , Steffen Wirth , Ulrich Schwarz

FeSe-derived superconductors show some unique behaviors relative to iron-pnictide superconductors, which are very helpful to understand the mechanism of superconductivity in high-Tc iron-based superconductors. The low-energy electronic…

超导电性 · 物理学 2014-12-17 X. F. Lu , N. Z. Wang , H. Wu , Y. P. Wu , D. Zhao , X. Z. Zeng , X. G. Luo , T. Wu , W. Bao , G. H. Zhang , F. Q. Huang , Q. Z. Huang , X. H. Chen

The crystal structure of the superconductor FeSe0.44Te0.56 was redetermined by high-resolution X-ray single crystal diffraction at 173 K (anti-PbO-type, P4/nmm, a=3.7996(2), c=5.9895(6) A, R1=0.022, wR2=0.041, 173 F^2). Significantly…

超导电性 · 物理学 2010-02-24 Marcus Tegel , Catrin Loehnert , Dirk Johrendt

We studied the correlation among structure and transport properties and superconductivity in the different $A_x$Fe$_2$Se$_2$ single crystals ($A$ = K, Rb, and Cs). Two sets of (00$l$) reflections are observed in the X-ray single crystal…

Potassium intercalated FeSe has been reported as a superconductor with superconducting transition temperatures ($T_{\rm c}$'s) of 30-48 K. However, there is no clear answer to identify the relationship between the surface morphology,…

超导电性 · 物理学 2017-01-06 Masashi Tanaka , Hiroyuki Takeya , Yoshihiko Takano

The latest discovery of a new iron-chalcogenide superconductor A$_x$Fe$_{2-y}$Se$_2$(A=K, Cs, Rb, Tl and etc.) has attracted much attention due to a number of its unique characteristics, such as the possible insulating state of the parent…

超导电性 · 物理学 2012-01-04 Daixiang Mou , Lin Zhao , Xingjiang Zhou

Single crystal neutron diffraction study has been performed on new superconductor A2Fe4Se5, where A = Cs, K, (Tl,Rb) and (Tl,K), and the same Fe vacancy ordered crystal structure and the same block checkerboard antiferromagne tic order…

超导电性 · 物理学 2011-09-21 F. Ye , S. Chi , Wei Bao , X. F. Wang , J. J. Ying , X. H. Chen , H. D. Wang , C. H. Dong , Minghu Fang

Iron-chalcogenide compounds with FeSe(Te, S) layers did not attract much attention until the discovery of high-Tc superconductivity (SC) in the iron-pnictide compounds at the begining of 2008. Compared with FeAs-based superconductors,…

超导电性 · 物理学 2015-06-16 ChiHeng Dong , Hangdong Wang , Minghu Fang

The superconducting and magnetic properties of phase-separated A$_x$Fe$_{2-y}$Se$_2$ compounds are known to depend on post-growth heat treatments and cooling profiles. This paper focusses on the evolution of microstructure on annealing, and…

The electronic structure of FeSe, the simplest iron based superconductor (Fe-SC), conceals a potential of dramatic increase of Tc that realizes under pressure or in a single layer film. This is also the system where nematicity, the…

超导电性 · 物理学 2017-02-14 Yu. V. Pustovit , A. A. Kordyuk

We have synthesized polycrystalline samples and single crystals of Fe(Te1-xSx)y, and characterized their properties. Our results show that the solid solution of S in this system is limited, < 30%. We observed superconductivity at ~ 9 K in…

超导电性 · 物理学 2008-11-24 M. H. Fang , B. Qian , H. M. Pham , J. H. Yang , T. J. Liu , E. K. Vehstedt , L. Spinu , Z. Q. Mao
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