相关论文: CH2D+, the Search for the Holy Grail

Most stars in the Galaxy, including the Sun, were born in high-mass star-forming regions. It is hence important to study the chemical processes in these regions to better understand the chemical heritage of both the Solar System and most…

Our observations of TMC-1 with the Yebes 40 m radio telescope in the 31.0-50.3 GHz range allowed us to detect a group of unidentified lines, showing a complex line pattern indicative of an open-shell species. {}The observed frequencies of…

We have investigated the two-dimensional (R,Z) distribution of deuterated molecular species in circumstellar disks around young stellar objects. The abundance ratios between singly deuterated and normal molecules (``D/H ratios'') in disks…

H$_3^+$ emission is the dominant cooling mechanism in Jupiter's thermosphere and a useful probe of temperature and ion densities. The H$_3^+$ ion is predicted to form in the thermospheres of close-in `hot Jupiters' where its emission would…

The successive addition of H atoms to CO in the solid phase has been hitherto regarded as the primary route to form methanol in dark molecular clouds. However, recent Monte Carlo simulations of interstellar ices alternatively suggested the…

Aims. We aim to improve a previous model for the prediction of column densities and deuterium fractions of non- and singly deuterated methanol. Thereby, we try to identify crucial chemical and physical parameters, for which the study of…

We report the first detection in the ${\it J}_{{\it K}}$ = 1$_{0}$ - 0$_{0}$ rotational transition line of CH$_{3}$D towards three Class 0/I proto-brown dwarfs (proto-BDs) from IRAM 30 m observations. Assuming a rotational temperature of 25…

The deuteration mechanism of molecules in the interstellar medium (ISM) is still being debated. Observations of deuterium-bearing species in several astronomical sources represent a powerful tool to improve our understanding of the…

Deuterium fractionation is a well-established evolutionary tracer in low-mass star formation, but its applicability to the high-mass regime remains an open question. The abundances and ratios of deuterated species have often been proposed…

Using the Yebes 40m and IRAM 30m radiotelescopes, we detected two series of harmonically related lines in space that can be fitted to a symmetric rotor. The lines have been seen towards the cold dense cores TMC-1, L483, L1527, and L1544.…

Most protoplanetary disks experience a phase in which they are subjected to strong ultraviolet radiation from nearby massive stars. This UV radiation can substantially alter their chemistry by producing numerous radicals and molecular ions.…

The abundance of deuterated molecules in a star-forming region is sensitive to the environment in which they are formed. Deuteration fractions therefore provide a powerful tool for studying the physical and chemical evolution of a…

Aims. To follow the species chemistry arising in diverse sources of the Galaxy with Herschel. Methods. SPIRE FTS sparse sampled maps of the Orion bar & compact HII regions G29.96-0.02 and G32.80+0.19 have been analyzed. Results. Beyond the…

We aim to reproduce the DCO$^+$ emission in the disk around HD163296 using a simple 2D chemical model for the formation of DCO$^+$ through the cold deuteration channel and a parametric treatment of the warm deuteration channel. We use data…

We have investigated the chemistry of ${\rm C + H_3^+}$ forming CH$^+$, CH$_2^+$, and CH$_3^+$. These reactions are believed to be some of the key gas-phase astrochemical processes initiating the formation of organic molecules in molecular…

Context : Despite the low cosmic abundance of deuterium (D/H ~ 1e-5), large degrees of deuterium fractionation in molecules are observed in star forming regions with enhancements that can reach 13 orders of magnitude, which current models…

We investigate deuterium chemistry coupled with the nuclear spin-state chemistry of H$_2$ and H$_3^+$ in protoplanetary disks. Multiple paths of deuterium fractionation are found; exchange reactions with D atoms, such as HCO$^+$ + D, are…

We use spectra and maps of NH2D, ND2H, and ND3, obtained with the CSO, IRAM 30m and Arecibo telescopes, to study deuteration processes in dense cores. The data include the first detection of the hyperfine structure of ND2H. The emission of…

Probing the gas and dust in proto-planetary disks is central for understanding the process of planet formation. In disks surrounding solar type protostars, the bulk of the disk mass resides in the outer midplane, which is cold ($\leq$20 K),…

CH$_3^+$, a cornerstone intermediate in interstellar chemistry, has recently been detected for the first time by the James Webb Space Telescope. The photodissociation of this ion is studied here. Accurate explicitly correlated…