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This study focuses on the formation of two molecules of astrobiological importance - glycolaldehyde (HC(O)CH2OH) and ethylene glycol (H2C(OH)CH2OH) - by surface hydrogenation of CO molecules. Our experiments aim at simulating the CO…

星系天体物理 · 物理学 2017-05-26 Gleb Fedoseev , Herma M. Cuppen , Sergio Ioppolo , Thanja Lamberts , Harold Linnartz

Little is known about the chemistry of isocyanates (compounds with the functional group R-N=C=O) in the interstellar medium, as only four of them have been detected so far: isocyanate radical (NCO), isocyanic acid (HNCO), N-protonated…

With the goal of deriving the physical and chemical conditions of star forming regions in the Large Magellanic Cloud (LMC), a spectral line survey of the prominent star forming region N113 is presented. The observations cover parts of the…

天体物理学 · 物理学 2008-12-18 M. Wang , Y. -N. Chin , C. Henkel , J. B. Whiteoak , M. Cunningham

$Aims$: We revisit with new augmented accuracy the theoretical dynamics of basic isotope exchange reactions involved in the $^{12}$C/$^{13}$C, $^{16}$O/$^{18}$O, and $^{14}$N/$^{15}$N balance because these reactions have already been…

星系天体物理 · 物理学 2015-06-19 Mirjana Mladenović , Evelyne Roueff

Isomerism in complex organic molecules provides key insights into the formation mechanisms and physical conditions of the interstellar medium (ISM). Among the C$_2$H$_5$NO isomers, only acetamide and trans-N-methylformamide (trans-NMF) have…

Hydrogen cyanide (HCN) and formaldehyde (H2CO) are key precursors to biomolecules such as nucleobases and amino acids in planetary atmospheres; However, many reactions which produce and destroy these species in atmospheres containing CO2…

化学物理 · 物理学 2022-01-05 Ben K. D. Pearce , Paul W. Ayers , Ralph E. Pudritz

Methoxymethanol (CH3OCH2OH, MM) has been identified through gas-phase signatures in both high- and low-mass star-forming regions. This molecule is expected to form upon hydrogen addition and abstraction reactions in CO-rich ice through…

The HCN, HCO+, and HNC molecules are commonly used as tracers of dense star-forming gas in external galaxies, but such observations are spatially unresolved. Reliably inferring the properties of galactic nuclei and disks requires detailed…

星系天体物理 · 物理学 2015-05-20 Helen Roberts , Floris van der Tak , Gary Fuller , René Plume , Estelle Bayet

We report the first detection of SiC$_2$ in the interstellar medium. The molecule was identified through six rotational transitions toward G\,+0.693$-$0.027, a molecular cloud located in the Galactic center. The detection is based on a line…

HCN is becoming a popular choice of molecule for studying star formation in both low- and high-mass regions and for other astrophysical sources from comets to high-redshift galaxies. However, a major and often overlooked difficulty with HCN…

太阳与恒星天体物理 · 物理学 2013-05-08 R. M. Loughnane , M. P. Redman , M. A. Thompson , N. Lo , B. O'Dwyer , M. R Cunningham

Interstellar molecules with a peptide link -NH-C(=O)-, like formamide (NH$_2$CHO), acetamide (NH$_2$COCH$_3$) and isocyanic acid (HNCO) are particularly interesting for their potential role in pre-biotic chemistry. We have studied their…

太阳与恒星天体物理 · 物理学 2015-06-22 E. Mendoza , B Lefloch , A. López-Sepulcre , C. Ceccarelli , C. Codella , H. M. Boechat-Roberty , R. Bachiller

In recent astrochemical studies it has become crucial to study all the complete conformational panorama of the molecule, some of which are potentially detectable in the interstellar medium (ISM). In this context, the isomeric ratio can be…

星系天体物理 · 物理学 2025-06-04 Miguel Sanz-Novo , Germán Molpeceres , Víctor M. Rivilla , Izaskun Jiménez-Serra

Formaldehyde (H2CO) is one of the most abundant molecules observed in the icy mantle covering interstellar grains. Studying its evolution can contribute to our understanding of the formation of complex organic molecules in various…

星系天体物理 · 物理学 2020-09-14 Lei Song , Johannes Kästner

Ice chemistry in the dense, cold interstellar medium (ISM) is probably responsible for the formation of interstellar complex organic molecules (COMs). Recent laboratory experiments performed at T=4 K have shown that irradiation of CO:N2 ice…

星系天体物理 · 物理学 2024-01-09 Rafael Martín-Doménech , Alexander DelFranco , Karin I. Öberg , Mahesh Rajappan

We aim to reveal the chemistry of carbon-chain molecules in high-mass star-forming regions from molecular level to chemical evolution, applying the methods established in low-mass star-forming regions. In this proceeding, we summarize the…

星系天体物理 · 物理学 2017-01-10 Kotomi Taniguchi , Masao Saito

CO2 is one of the dominant components of the interstellar ice. Recent observations show CO2 exists more abundantly in polar (H2O-dominated) ice than in apolar (H2O-poor) ice. CO2 ice formation is primarily attributed to the reaction between…

星系天体物理 · 物理学 2023-09-06 Germán Molpeceres , Joan Enrique-Romero , Yuri Aikawa

We report observations of the ground state transitions of $^{12}$CO, $^{13}$CO C$^{18}$O, HCN, and HCO$^+$ at 88-115 GHz in the inner region of the nearby galaxy IC 342. These data were obtained with the 16-pixel spectroscopic focal plane…

We report the detection, for the first time in space, of cyano thioformaldehyde (HCSCN) and propynethial (HCSCCH) towards the starless core TMC-1. Cyano thioformaldehyde presents a series of prominent a- and b-type lines, which are the…

星系天体物理 · 物理学 2021-06-23 J. Cernicharo , C. Cabezas , Y. Endo , M. Agundez , B. Tercero , J. R. Pardo , N. Marcelino , P. de Vicente

In the interstellar medium, formic acid (HCOOH) plays a significant role in the synthesis of the simplest amino acid, glycine (NH$_{2}$CH$_{2}$COOH). The presence of HCOOH suggests that oxygen-bearing molecules may be directly involved in…

星系天体物理 · 物理学 2026-02-11 Arijit Manna , Sabyasachi Pal , Sekhar Sinha , Sushanta Kumar Mondal

Based on recent work, formamide might be a potentially very important molecule in the emergence of terrestrial life. Although detected in the interstellar medium for decades, its formation route is still debated, whether in the gas phase or…

太阳与恒星天体物理 · 物理学 2017-07-19 D. Skouteris , F. Vazart , C. Ceccarelli , N. Balucani , C. Puzzarini , V. Barone