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We report a detailed study of the Te vapor annealing effect in Fe$_{1+y}$Te$_{0.6}$Se$_{0.4}$ single crystals. Bulk superconductivity can be gradually induced by annealing with increasing amount of Te, until the molar ratio of Te to the…

In this study, the effects of annealing under tellurium vapor have been investigated for Fe$_{1.03}$Te$_{0.8}$Se$_{0.2}$ single crystals. The as-grown crystal is not superconducting. After annealing it at 400 $^\circ$C for 250 h in…

Iron chalcogenide Fe(Te,Se) attracted much attention due to its simple structure, which is favorable for probing the superconducting mechanism. Its less toxic nature compared with iron arsenides is also advantageous for applications of…

Thermal conductivity measurements in magnetic fields have been carried out for FeSe$_{0.3}$Te$_{0.7}$ single crystals as-grown and annealed at 400 {\degree}C for 100 h in vacuum ($\sim$ 10$^{-4}$ Pa). It has been found that the thermal…

Fe$_{1+y}$Te$_{1-x}$Se$_x$ is unique in their structural simplicity, consisting of only FeTe/Se layers, which is favorable for probing the mechanism of superconductivity. Recently, a topological surface superconductivity as well as the…

超导电性 · 物理学 2019-08-27 Yue Sun , Zhixiang Shi , Tsuyoshi Tamegai

It has been clarified that bulk superconductivity in Fe$_{1+y}$Te$_{0.6}$Se$_{0.4}$ can be induced by annealing in an appropriate atmosphere to remove the harmful effects of excess iron. In order to clarify the details of the annealing…

超导电性 · 物理学 2016-02-03 Tatsuhiro Yamada , Yue Sun , Sunseng Pyon , Tsuyoshi Tamegai

We have systematically investigated the annealing effect on the superconductivity of iron chalcogenide Fe1+y(Te1-xSex). The atmospheres used for annealing include O2, N2, I2 vapor, air and vacuum. We observed that annealing in O2, I2 and…

超导电性 · 物理学 2012-11-07 J. Hu , G. C. Wang , B. Qian , Z. Q. Mao

Experimental evidences from transport, magnetic, and magneto-optical (MO) image measurements confirmed that arsenic (As) vapor annealing was another effective way to induce bulk superconductivity with isotropic, large, and homogenous…

We have systematically investigated and compared different methods to induce superconductivity in iron chalcogenide Fe1+yTe0.6Se0.4 including annealing in vacuum, N2, O2, I2 atmosphere, and immersing samples into acid and alcoholic…

超导电性 · 物理学 2013-04-08 Y. Sun , T. Taen , Y. Tsuchiya , Z. X. Shi , T. Tamegai

We reported that bulk superconductivity in Fe$_{1+y}$Te$_{1-x}$Se$_{x}$ can be induced by annealing in Se and S vapor. The well-annealed samples show a large critical current density, emph{J}$_c$ $\sim$ 2 - 4 $\times$ 10$^5$ A/cm$^2$.…

Recent investigations have shown that Fe$_{1+y}$Te$_{1-x}$Se$_{x}$ can be made superconducting by annealing it in Se and O vapors. The current lore is that these chalcogen vapors induce superconductivity by removing the magnetic excess Fe…

In as-grown bulk crystals of Fe$_{1+y}$Te$_{1-x}$Se$_{x}$ with $x\lesssim0.3$, excess Fe ($y>0$) is inevitable and correlates with a suppression of superconductivity. At the same time, there remains the question as to whether the character…

For the Fe-based superconductor Fe{1+y}Te{1-x}S{x}, superconductivity is induced by annealing treatment in oxygen atmosphere, whereas as-grown samples do not show superconductivity. We have investigated the sample-size dependence of…

超导电性 · 物理学 2016-11-23 Teruo Yamazaki , Tatsuya Sakurai , Hiroshi Yaguchi

We investigated the superconducting and transport properties in FeTe$_{1-x}$Se$_{x}$ (0.1 $\leq$ $x$ $\leq$ 0.4) single crystals prepared by O$_2$-annealing. Sharp superconducting transition width observed in magnetization measurement and…

超导电性 · 物理学 2015-02-17 Yue Sun , Toshihiro Taen , Tatsuhiro Yamada , Yuji Tsuchiya , Sunseng Pyon , Tsuyoshi Tamegai

Superconductivity in anti-PbO-type iron chalcogenides Fe1-xTe1-ySey (x = 0, 0.1, y = 0.1 0.4) depends on the amount (x) of interstitial iron atoms located between the FeTe1-ySey layers. Non-superconducting samples of nominal Fe1.1Te1-ySey…

超导电性 · 物理学 2015-05-25 Gina M. Friederichs , Matthias P. B. Wörsching , Dirk Johrendt

Superconductivity in FeSe was investigated under high pressure through the measurements of DC magnetization by using a diamond anvil cell. We successfully observed that the disappearance of the superconductivity as a results of the…

There are several strategies to discover new superconductors. Growing new materials and applying high pressures can be the classic ways since superconductivity was found. Also, chemical processing, such as annealing, is another way to…

Single crystalline FeTe$_{0.61}$Se$_{0.39}$ with a sharp superconducting transition at $T_{\textrm{c}} \sim$ 14 K is synthesized via slow furnace cooling followed by low-temperature annealing. The effect of annealing on the chemical and…

超导电性 · 物理学 2015-05-13 T. Taen , Y. Tsuchiya , Y. Nakajima , T. Tamegai

We investigated the S-doping-driven phase transition from antiferromagnetic to superconducting in FeTe1-xSx single crystals. The partial substitution of Te by S suppresses antiferromagnetism in Fe-square lattice. Superconductivity is…

We have synthesized polycrystalline samples and single crystals of Fe(Te1-xSx)y, and characterized their properties. Our results show that the solid solution of S in this system is limited, < 30%. We observed superconductivity at ~ 9 K in…

超导电性 · 物理学 2008-11-24 M. H. Fang , B. Qian , H. M. Pham , J. H. Yang , T. J. Liu , E. K. Vehstedt , L. Spinu , Z. Q. Mao
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