相关论文: Upper limits for PH3 and H2S in Titan's Atmosphere…

In this paper we describe a first quantitative search for several molecules in Titan's stratosphere in Cassini CIRS infrared spectra. These are: ammonia (NH3), methanol (CH3OH), formaldehyde (H2CO), and acetonitrile (CH3CN), all of which…

In this chapter we describe the remote sensing measurement of nitrogen-bearing species in Titan's atmosphere by the Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft. This instrument, which detects the thermal infrared…

Following the announcement of the detection of phosphine (PH$_3$) in the cloud deck of Venus at millimeter wavelengths, we have searched for other possible signatures of this molecule in the infrared range. Since 2012, we have been…

The complex organic chemistry harbored by the atmosphere of Titan has been investigated in depth by Cassini observations. Among them, a series of solar occultations performed by the VIMS instrument throughout the 13 years of Cassini…

The Voyager 1 flyby of Titan in 1980 gave a first glimpse of the chemical complexity of Titan's atmosphere, detecting many new molecules with the infrared spectrometer (IRIS). These included propane (C3H8) and propyne (CH3C2H), while the…

Thermochemical equilibrium and kinetic calculations for the trace gases CO, PH3, and SiH4 give three independent constraints on the water and total oxygen abundances of Saturn's deep atmosphere. A lower limit to the water abundance of…

Of the C$_{3}$H$_{x}$ hydrocarbons, propane (C${_3}$H$_{8}$) and propyne (methylacetylene, CH$_{3}$C$_{2}$H) were first detected in Titan's atmosphere during the Voyager 1 flyby in 1980. Propene (propylene, C$_{3}$H$_{6}$) was first…

The presence of phosphine (PH$_3$) in the atmosphere of Venus was reported by Greaves et al. (2021a), based on observations of the J=1-0 transition at 267 GHz using ground-based, millimeter-wave spectroscopy. This unexpected discovery…

In Titan's atmosphere, the chemistry of small hydrocarbons and nitriles represent an important link from molecular species to the ubiquitous organic haze that gives Titan its characteristic yellow color. Here we present a new search for two…

The Cassini/Composite InfraRed Spectrometer (CIRS) instrument has been observing the middle atmosphere of Titan over almost half a Saturnian year. We used the CIRS dataset processed through the up-to-date calibration pipeline to…

The Cassini/Huygens mission provided new insights on the chemistry of the upper atmosphere of Titan. The presence of large molecules and ions (>100 s of amu) detected by Cassini at high altitude was not expected, and questions the original…

The Cassini Composite Infrared Spectrometer (CIRS) observed thermal emission in the far- and mid-infrared (from 10 cm$^{-1}$ to 1500 cm$^{-1}$), enabling spatiotemporal studies of ethane on Titan across the span of the Cassini mission from…

Thermochemical equilibrium and kinetic calculations are used to model sulfur and phosphorus chemistry in giant planets, brown dwarfs, and extrasolar giant planets (EGPs). The chemical behavior of individual S- and P-bearing gases and…

The role of polycyclic aromatic hydrocarbons (PAH) and Nitrogen containing PAH (PANH) as intermediates of aerosol production in the atmosphere of Titan has been a subject of controversy for a long time. An analysis of the atmospheric…

The organic haze produced from complex CH4/N2 chemistry in the atmosphere of Titan plays an important role in processes that occur in the atmosphere and on its surface. The haze particles act as condensation nuclei and are therefore…

Measurements of trace-gases in planetary atmospheres help us explore chemical conditions different to those on Earth. Our nearest neighbor, Venus, has cloud decks that are temperate but hyper-acidic. We report the apparent presence of…

Cassini-Huygens data are used to re-examine the potential sources of the D/H enhancement over solar, measured in methane, in Titan's atmosphere. Assuming that the system is closed with respect to carbon, the use of constraints from the…

Aims: We investigate the composition of Titan's stratosphere from new medium-resolution far-infrared observations performed with the full range of Herschel's Photodetector Array Camera and Spectrometer (PACS) (51-220 $\mu$m at a resolution…

Titan's ionosphere contains a plethora of hydrocarbons and nitrile cations and anions as measured by the Ion Neutral Mass Spectrometer and Cassini Plasma Spectrometer (CAPS) onboard the Cassini spacecraft. Data from the CAPS Ion Beam…

In this article I summarize the current state of knowledge about the composition of Titan's atmosphere, and our current understanding of the suggested chemistry that leads to that observed composition. I begin with our present knowledge of…