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Giant magnetostriction in insulating magnetic materials is highly required for applications but is rarely observed. Here we show that giant magnetostriction (> 1500 ppm) can be achieved in an insulating transition metal oxide CaBaCo4O7…

强关联电子 · 物理学 2021-09-29 Yi-Sheng Chai , Jun-Zhuang Cong , Jin-Cheng He , Dan Su , Xia-Xin Ding , John Singleton , Vivien Zapf , Young Sun

Magneto-electric coupling in pyroelectric CaBaCo$_4$O$_7$ is investigated using ab-intio calculations and Landau theory. The former shows that exchange-striction is strong enough to produce a giant change in electric polarization upon…

强关联电子 · 物理学 2015-06-19 R. D. Johnson , K. Cao , P. G. Radaelli

In rhombohedral CaMn7O12, an improper ferroelectric polarization of magnitude 2870 {\mu}C m-2 is induced by an incommensurate helical magnetic structure that evolves below TN1 = 90 K. The electric polarization was found to be constrained to…

强关联电子 · 物理学 2015-05-30 R. D. Johnson , L. C. Chapon , D. D. Khalyavin , P. Manuel , P. G. Radaelli , C. Martin

Ferroelectricity in the incommensurate helical magnetic phase (below TN, 43K) of alpha CaCr2O4 has been confirmed by pyroelectric measurements. Magnetoelectric and magnetodielectric coupling exist below TN and are proportional to the square…

材料科学 · 物理学 2012-08-03 Kiran Singh , Charles Simon , Pierre Toledano

The polar magnet CaBaCo$_{4}$O$_{7}$ is known to exhibit the largest magnetic-field-driven electric polarization change ($\Delta P$) associated with an antiferromagnetic (AFM)-ferrimagnetic (FIM) transition in a narrow temperature range…

材料科学 · 物理学 2022-08-10 M. Gen , A. Miyake , H. Yagiuchi , Y. Watanabe , A. Ikeda , Y. H. Matsuda , M. Tokunaga , T. Arima , Y. Tokunaga

Transport and magnetic studies of Ca3Ru2O7 for temperatures ranging from 0.4 K to 56 K and magnetic fields, B, up to 45 T leads to strikingly different behavior when the field is applied along the different crystal axes. A ferromagnetic…

强关联电子 · 物理学 2009-11-11 X. N. Lin , Z. X. Zhou , V. Durairaj , P. Schlottmann , G. Cao

We have investigated the magnetic and dielectric properties of Ca$_2$CoSi$_2$O$_7$ crystal. The dielectricity and magnetism of Ca$_2$CoSi$_2$O$_7$ are strongly coupled below a canted antiferromagnetic transition temperature ($T_{\rm N}$):…

强关联电子 · 物理学 2009-05-29 M. Akaki , J. Tozawa , D. Akahoshi , H. Kuwahara

Magnetic and dielectric properties of \aa kermanite Ca$_2$CoSi$_2$O$_7$ single crystals were investigated in pulsed high magnetic fields. In magnetic fields along the $c$ axis, this material shows a magnetization plateau in a wide range of…

强关联电子 · 物理学 2015-06-22 Mitsuru Akaki , Hideki Kuwahara , Akira Matsuo , Koichi Kindo , Masashi Tokunaga

We report ferroelectric ordering in Ni substituted CaBaCo4O7. Magnetization showed ferrimagnetic transition at 60 K and an additional transition is found ~ 82 K, further, enhanced antiferromagnetic interactions and decrease in saturation…

材料科学 · 物理学 2017-10-18 C. Dhanasekhar , A. K Das , Ripandeep Singh , A. Das , G. Giovannetti , D. Khomskii , A. Venimadhav

CaBaCo4O7 represents a new class of ferrimagnets whose structure is built up of CoO4 tetrahedra only, similarly to other members LnBaCo4O7 of the 114 series, forming an alternate stacking of kagome and triangular layers. Neutron powder…

材料科学 · 物理学 2015-05-18 V. Caignaert , V. Pralong , V. Hardy , C. Ritter , B. Raveau

Spin excitations were studied by absorption spectroscopy in CaBaCo4O7 which is a type-I multiferroic compound with the largest magnetic-order induced ferroelectric polarization ({\Delta}P=17mC/m2) reported, so far. We observed two optical…

强关联电子 · 物理学 2016-01-05 S. Bordács , V. Kocsis , Y. Tokunaga , U. Nagel , T. Rõõm , Y. Takahashi , Y. Taguchi , Y. Tokura

The magnetic properties of the ferrimagnetic cobaltite CaBaCo$_4$O$_7$ are systematically investigated. We find that the susceptibility exhibits a downward deviation below $\sim$ 360 K, suggesting the occurrence of short range magnetic…

强关联电子 · 物理学 2015-03-19 Zhe Qu , Langsheng Ling , Lei Zhang , Li Pi , Yuheng Zhang

We investigate the spin-induced polarization in the multiferroic compound Ba2CuGe2O7 using variarional and finite temperature mean field approaches. The compound is described by a spin-3/2 Heisenberg model extended with easy plane…

强关联电子 · 物理学 2012-02-21 Judit Romhanyi , Miklos Lajko , Karlo Penc

A detailed investigation of Ba$_2$MnGe$_2$O$_7$ was performed in its low-temperature magnetoelectric state combining neutron diffraction with magnetization measurements on single crystals. In the paramagnetic state at 10 K, polarized…

强关联电子 · 物理学 2023-03-07 A. Sazonov , H. Thoma , R. Dutta , M. Meven , A. Gukasov , R. Fittipaldi , V. Granata , T. Masuda , B. Náfrádi , V. Hutanu

In RBaCo4O7 (R = Ca, Y and Rare earth) cobaltite family, only CaBaCo4O7 shows 3D long range ferrimagnetic and spin driven electric polarization properties. In the present study, we have investigated the structural, magnetic and electric…

强关联电子 · 物理学 2020-01-08 C. Dhanasekhar , A. K Das , A. Das , S. K. Mishra , R. Rawat , A. Venimadhav

We study the magnetocapacitance (MC) effect and magnetoelectric (ME) coupling in spin-flop driven antiferromagnet Co4Ta2O9. The magnetocapacitance data at high magnetic fields are analyzed by phenomenological Ginzburg-landau theory of…

材料科学 · 物理学 2017-07-12 S. Chaudhary , P. Srivastava , S. Patnaik

We performed susceptibility, magnetization, specific heat, and single crystal neutron diffraction measurements on single crystalline BaMn$_2$Si$_2$O$_7$. Based on the results, we revisited its spin structure with a more accurate solution…

强关联电子 · 物理学 2019-07-31 G. H. Wang , C. Y. Xu , H. B. Cao , T. Hong , Q. Huang , Q. Y. Ren , J. Q. Xu , H. D. Zhou , W. D. Luo , D. Qian , J. Ma

Co4Nb2O9 (CNO) having {\alpha}-Al2O3 crystal structure with Co chains along c-direction shows gigantic magnetoelelctric coupling below antiferromagnetic ordering temperature of 27 K but above a spin flop field of 1.6 T. We have investigated…

材料科学 · 物理学 2016-06-16 C. Dhanasekhar , S. K. Mishra , R. Rawat , A. K. Das , A. Venimadhav

A joint theoretical approach, combining macroscopic symmetry analysis with microscopic methods (density functional theory and model cluster Hamiltonian), is employed to shed light on magnetoelectricity in Ba2CoGe2O7. We show that the…

强关联电子 · 物理学 2015-05-27 Kunihiko Yamauchi , Paolo Barone , Silvia Picozzi

BaMF4 (M=Fe, Co, Ni and Mn) family are typical multiferroic materials, having antiferromagnetism at around liquid nitrogen temperature. In this work, polycrystalline BaFeF4 has been prepared by solid state reaction. The slight deficiency of…

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