相关论文: Rubidium Rydberg linear macrotrimers

We detail the rich electronic and vibrational structure of triatomic "butterfly" molecules, ultra-long-range Rydberg molecules bound by resonant $p$-wave scattering. We divide these molecules into two sub-classes depending on their parity…

We report on the observation of highly excited ($\nu \sim 100)$ vibrational states of a trilobite ultralong-range Rydberg molecule in $^{87}$Rb. These states manifest spectroscopically in a regularly spaced series of peaks red-detuned from…

Controlling molecular binding at the level of single atoms is one of the holy grails of quantum chemistry. Rydberg macrodimers -- bound states between highly excited Rydberg atoms -- provide a novel perspective in this direction. Resulting…

Rydberg atoms and beams of ultracold polar molecules have become highly useful experimental tools in recent years. There is therefore a need for accessible calculations of interaction potentials between such particles and nearby surfaces…

The ability to generate and control strong long-range interactions via highly excited electronic states has been the foundation for recent breakthroughs in a host of areas, from atomic and molecular physics [1, 2] to quantum optics [3, 4]…

We show that the recently observed class of long-range ion-Rydberg molecules can be divided into two families of states, which are characterised by their unique electronic structures resulting from the ion-induced admixture of quantum…

We investigate the dynamics of Rydberg electrons excited from the ground state of ultracold atoms trapped in an optical lattice. We first consider a lattice comprising an array of double-well potentials, where each double well is occupied…

Helium atoms in Rydberg states have been manipulated coherently with microwave radiation pulses near a gold surface and near a superconducting NbTiN surface at a temperature of $3 \text{K}$. The experiments were carried out with a skimmed…

The Rydberg excitation blockade has been at the heart of an impressive array of recent achievements; however, state-mixing interactions can compromise its efficiency. When ultracold atoms are excited to Rydberg states near F\"orster…

Long-range Rydberg molecules (LRMs) form when a highly excited Rydberg electron scatters from ground-state atoms inside its orbit, creating oscillatory, long-range potentials. We present a combined theoretical and experimental study of…

Recent theoretical studies with alkali atoms A$^{\ast}$ excited to high Rydberg states predicted the existence of ultra long-range molecular bound states. Such excited dimers have large electric dipole moments which, in combination with…

A Rydberg and a ground-state atom can form ultralong range diatomic molecules provided the interaction between the ground-state atom and the Rydberg electron is attractive [C. H. Greene, et al., Phys. Rev. Lett. 85, 2458 (2000)]. A…

We investigate polyatomic ultralong-range Rydberg molecules consisting of three ground state atoms bound to a Rydberg atom via $s$- and $p$-wave interactions. By employing the finite basis set representation of the unperturbed Rydberg…

We investigate the collective aspects of Rydberg excitation in ultracold mesoscopic systems. Strong interactions between Rydberg atoms influence the excitation process and impose correlations between excited atoms. The manifestations of the…

Experiments involving ultracold molecules require sufficiently long lifetimes, which can be very short for excited rovibrational states in the molecular potentials. For alkali atoms such as rubidium, a lowest rovibrational molecular state…

We consider a multichannel generalization of the Fermi pseudopotential to model low-energy atom-atom interactions near a magnetically tunable Feshbach resonance, and calculate the adiabatic hyperspherical potential curves for a system of…

A potential energy surface for the lowest quartet electronic state of lithium trimer is developed and used to study spin-polarized Li + Li_2 collisions at ultralow kinetic energies. The potential energy surface allows barrierless atom…

We use the sensitive response to electric fields of Rydberg atoms to characterize all three vector components of the local electric field close to an atom-chip surface. We measured Stark-Zeeman maps of $S$ and $D$ Rydberg states using an…

We investigate the electronic structure of a triatomic Rydberg molecule formed by a Rydberg atom and two neutral ground-state atoms. Taking into account the $s$-wave and $p$-wave interactions we perform electronic structure calculations and…

We review experimental and theoretical tools to excite, study and understand strongly interacting Rydberg gases. The focus lies on the excitation of dense ultracold atomic samples close to, or within quantum degeneracy, to high lying…