相关论文: The Effect of an Inert Solid Reservoir on Molecula…
In this work we investigate the effects of ion accretion and size-dependent dust temperatures on the abundances of both gas-phase and grain-surface species. While past work has assumed a constant areal density for icy species, we show that…
We survey the current situation regarding chemical modelling of the synthesis of molecules in the interstellar medium. The present state of knowledge concerning the rate coefficients and their uncertainties for the major gas-phase processes…
Context. Interstellar surface chemistry is a complex process that occurs in icy layers accumulated onto grains of different sizes. Efficiency of surface processes often depends on the immediate environment of adsorbed molecules. Aims. We…
We present a new gas-grain chemical model to constrain the effect of grain size distribution on molecular abundances in starless and pre-stellar cores. We introduce grain-size dependence simultaneously for cosmic-ray (CR)-induced desorption…
Theoretical studies have revealed that dust grains are usually moving fast through the turbulent interstellar gas, which could have significant effects upon interstellar chemistry by modifying grain accretion. This effect is investigated in…
We present a study of the elemental depletion in the interstellar medium. We combined the results of a Galatic model describing the gas physical conditions during the formation of dense cores with a full-gas-grain chemical model. During the…
Atoms and molecules, and in particular CO, are important coolants during the evolution of interstellar star-forming gas clouds. The presence of dust grains, which allow many chemical reactions to occur on their surfaces, strongly impacts…
The Galaxy is in continuous elemental evolution. Since new elements produced by dying stars are delivered to the interstellar medium, the formation of new enerations of stars and planetary systems is influenced by this metal enrichment. We…
Observations of gaseous complex organic molecules (COMs) in cold starless and prestellar cloud cores require efficient desorption of the COMs and their parent species from icy mantles on interstellar grains. With a simple astrochemical…
Major components of ices on interstellar grains in molecular clouds - water and carbon oxides - occur at various optical depths. This implies that selective desorption mechanisms are at work. An astrochemical model of a contracting low-mass…
Aims. We study the effect of large scale dynamics on the molecular composition of the dense interstellar medium during the transition between diffuse to dense clouds. Methods. We followed the formation of dense clouds (on sub-parsec scales)…
We investigate the uncertainties affecting the temperature profiles of dense cores of interstellar clouds. In regions shielded from external ultraviolet radiation, the problem is reduced to the balance between cosmic ray heating, line…
The observed gas-phase molecular inventory of hot cores is believed to be significantly impacted by the products of chemistry in interstellar ices. In this study, we report the construction of a full macroscopic Monte Carlo model of both…
The physical conditions in a collapsing cloud can be traced by observations of molecular lines. To correctly interpret these observations the abundance distributions of the observed species need to be derived. The chemistry in a collapsing…
Context. Cosmic ray particles that hit interstellar grains in dark molecular cores may induce whole-grain heating. The high temperature of a CR-heated grain allows energy barriers for bulk diffusion and reactions to be overcome.…
Computational models of interstellar gas-grain chemistry have historically adopted a single dust-grain size of 0.1 micron, assumed to be representative of the size distribution present in the interstellar medium. Here, we investigate the…
The elemental depletion of interstellar sulfur from the gas phase has been a recurring challenge for astrochemical models. Observations show that sulfur remains relatively non-depleted with respect to its cosmic value throughout the diffuse…
Aims: The gas-phase abundance of methanol in dark quiescent cores in the interstellar medium cannot be explained by gas-phase chemistry. In fact, the only possible synthesis of this species appears to be production on the surfaces of dust…
In this work, we reexamine sulfur chemistry occurring on and in the ice mantles of interstellar dust grains, and report the effects of two new modifications to standard astrochemical models; namely, (a) the incorporation of cosmic…
We present models for the evolution of the elemental abundances in the gas and dust phases of the interstellar medium (ISM) of our Galaxy by generalizing standard models for its dynamical and chemical evolution. In these models, the stellar…