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The Shockley-Queisser limit describes the maximum solar energy conversion efficiency achievable for a particular material and is the standard by which new photovoltaic technologies are compared. This limit is based on the principle of…

光学 · 物理学 2014-12-04 Yunlu Xu , Tao Gong , Jeremy N. Munday

The Shockley-Queisser (SQ) limit, introduced by W. Shockley and H. J. Queisser in 1961, is the most well-established fundamental efficiency limit for single-junction photovoltaic solar cells. For widely-studied semiconductors such as Si,…

应用物理 · 物理学 2021-06-09 Qian Zhou , Arfa Karani , Yaxiao Lian , Baodan Zhao , Richard H. Friend , Dawei Di

The Shockley-Queisser limit is one of the most fundamental results in the field of photovoltaics. Based on the principle of detailed balance, it defines an upper limit for a single junction solar cell that uses an absorber material with a…

材料科学 · 物理学 2017-06-29 Marnik Bercx , Rolando Saniz , Bart Partoens , Dirk Lamoen

The photovoltaic solar cell is a mature technology, with silicon-based technologies deployed at scale, yet current technologies are limited by the Shockley-Queisser thermodynamic limit, known since the early 1960s. The single-junction…

材料科学 · 物理学 2026-01-26 Gabriel J. Man

Maximum efficiency of ideal single-junction photovoltaic (PV) cells is limited to 33% (for one sun illumination) by intrinsic losses such as band edge thermalization, radiative recombination, and inability to absorb below-bandgap photons.…

光学 · 物理学 2015-06-17 Svetlana V. Boriskina , Gang Chen

The efficiency of GaAs nanowire solar cells can be significantly improved without any new processing steps or material requirements. We report coupled optoelectronic simulations of a GaAs nanowire (NW) solar cell with vertical p-i-n…

Photovoltaic materials are recognized for their potential as sustainable energy sources that enable the conversion between light and electrical energy. However, solar cells have been unable to surpass the theoretical limit of 32%, known as…

应用物理 · 物理学 2024-06-18 Jeonggyu Hwang

Improving the conversion efficiency of solar energy to electricity is most important to mankind. For single-junction photovoltaic solar-cells, the Shockley-Queisser thermodynamic efficiency limit is extensively due to the heat dissipation,…

光学 · 物理学 2015-06-11 Assaf Manor , Leopoldo L. Martin , Carmel Rotschild

The Shockley-Queisser (SQ) limit provides a convenient metric for predicting light-to-electricity conversion efficiency of a solar cell based on the band gap of the light-absorbing layer. In reality, few materials approach this radiative…

计算物理 · 物理学 2020-05-22 Sunghyun Kim , José A. Márquez , Thomas Unold , Aron Walsh

We employ a detailed balance approach to model a single-junction solar cell with a realistic narrow-band, non-unity-quantum-yield upconverter. As upconverter bandwidths are increased from 0 to 0.5 eV, maximum cell efficiencies increase from…

光学 · 物理学 2013-09-23 Justin A. Briggs , Ashwin C. Atre , Jennifer A. Dionne

The ideal solar cell conversion efficiency limit known as the Shockley-Queisser (SQ) limit, which is based on a detailed balance between absorption and radiation, has long been a target for solar cell researchers. While the theory for this…

应用物理 · 物理学 2018-11-07 Kenji Kamide , Toshimitsu Mochizuki , Hidefumi Akiyama , Hidetaka Takato

Compared to traditional pn-junction photovoltaics, hot carrier solar cells offer potentially higher efficiency by extracting work from the kinetic energy of photogenerated "hot carriers" before they cool to the lattice temperature. Hot…

Nanowire devices have long been proposed as an efficient alternative to their planar counterparts for different optoelectronic applications. Unfortunately, challenges related to the growth and characterization of doping and p-n junction…

材料科学 · 物理学 2023-01-23 Vidur Raj , Yi Zhu , Kaushal Vora , Lan Fu , Hark Hoe Tan , Chennupati Jagadish

The purpose of this work is to look for a practical structure for application of quantum dots (QD) in solar cells in order to enhance sub-band gap photon absorption. We focuse on a stack of strain-compensated GaSb/GaAs type-II QDs. We…

介观与纳米尺度物理 · 物理学 2014-10-17 A. Kechiantz , A. Afanasev , J. -L. Lazzari

Absorbed sunlight in a solar cell produces electrons and holes. But, at the open circuit condition, the carriers have no place to go. They build up in density and, ideally, they emit external fluorescence that exactly balances the incoming…

光学 · 物理学 2013-08-02 Owen D. Miller , Eli Yablonovitch , Sarah R. Kurtz

Light trapping in sub-wavelength semiconductor nanowires (NWs) offers a promising approach to simultaneously reducing material consumption and enhancing photovoltaic performance. Nevertheless, the absorption efficiency of a NW, defined by…

介观与纳米尺度物理 · 物理学 2023-07-19 Yiming Yang , Xingyue Peng , Steven Hyatt , Dong Yu

In a recent paper, Guillemoles et al [J.F. Guillemoles, T. Kirchartz, D. Cahen and U Rau, Guide for the perplexed to the Shockley-Queisser model for solar cells, Nat. Photonics, 13, 501 (2019)] attempt to clarify and explain the often cited…

应用物理 · 物理学 2019-11-22 Tom Markvart

With the consideration of photon recycling effect, the efficiency limit of methylammonium lead iodide (CH3NH3PbI3) perovskite solar cells is predicted by a detailed balance model. To obtain convincing predictions, both AM 1.5 spectrum of…

材料科学 · 物理学 2015-07-01 Wei E. I. Sha , Xingang Ren , Luzhou Chen , Wallace C. H. Choy

The Shockley and Queisser limit, a well-known efficiency limit for a solar cell, is based on unrealistic physical assumptions and its maximum limit is seriously overestimated. To understand the power loss mechanisms of record-efficiency…

应用物理 · 物理学 2019-08-28 Yoshitsune Kato , Shohei Fujimoto , Masayuki Kozawa , Hiroyuki Fujiwara

A high theoretical efficiency of 47.2% was achieved by a novel combination of In0.51Ga0.49P, GaAs, In0.24Ga0.76As and In0.19Ga0.81Sb subcell layers in a simulated quadruple junction solar cell under 1 sun concentration. The electronic…

应用物理 · 物理学 2019-05-21 Mohammad Jobayer Hossain , Bibek Tiwari , Indranil Bhattacharya
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