相关论文: A complete model of CH+ rotational excitation incl…

The abundances of interstellar CH+ and SH+ are not well understood as their most likely formation channels are highly endothermic. Using data from Herschel, we study the formation of CH+ and SH+ in a typical high UV-illumination…

Small carbon hydride cations, such as the methylidyne ion (CH$^+$), play an important role in the chemistry of the interstellar medium (ISM). They participate in gas-phase reaction networks leading to the formation of hydrocarbon species…

We present a detailed theoretical study of the rotational excitation of CH$^+$ due to reactive and nonreactive collisions involving C$^+(^2P)$, H$_2$, CH$^+$, H and free electrons. Specifically, the formation of CH$^+$ proceeds through the…

The methylidyne cation (CH$^+$) and the methyl cation (CH$_3^+$) are building blocks of organic molecules, yet their coupled formation and excitation mechanisms remain mainly unprobed. The James Webb Space Telescope (JWST), with its high…

The abundance of CH+ and OH and excitation are predicted to be enhanced by the presence of vibrationally excited H2 or hot gas (~500-1000 K) in PDRs with high incident FUV radiation field. The excitation may also originate in dense gas…

We discuss the detection of 14 rovibrational lines of CH$^+$, obtained with the iSHELL spectrograph on NASA's Infrared Telescope Facility (IRTF) on Maunakea. Our observations in the 3.49 - 4.13 $\mu$m spectral region, obtained with a 0.375"…

The internal energy available in vibrationally excited H2 molecules can be used to overcome or diminish the activation barrier of various chemical reactions of interest for molecular astrophysics. In this article we investigate in detail…

The formation of CH+ in the interstellar medium has long been an outstanding problem in chemical models. In order to probe the physical conditions of the ISM in which CH+ forms, we propose the use of CH3+ observations. The pathway to…

HeH$^+$ belongs to the class of "reactive" ions that can be destroyed so quickly that chemical formation and destruction rates may compete with inelastic rates and should be considered when solving the statistical equilibrium equations.…

Aims: The large abundances of CH$^+$ in the diffuse interstellar medium (ISM) are a long standing issue of our understanding of the thermodynamical and chemical states of the gas. We investigate, here, the formation of CH+ in turbulent and…

Ever since they were first detected in the interstellar medium, the radio wavelength (3.3 GHz) hyperfine-structure splitting transitions in the rotational ground state of CH have been observed to show anomalous excitation. Astonishingly,…

Observations of CO+ suggest column densities on the order 10^12 cm^-2 that can not be reproduced by many chemical models. CO+ is more likely to be destroyed than excited in collisions with hydrogen. An anomalous excitation mechanism may…

The CH$^+$ ion is a key species in the initial steps of interstellar carbon chemistry. Its formation in diverse environments where it is observed is not well understood, however, because the main production pathway is so endothermic (4280…

{\bf R}-matrix calculations combined with the adiabatic nuclei approximation are used to compute electron-impact rotiational excitation rates for three closed-shell diatomic cations, HeH$^+$, CH$^+$, ArH$^+$. Comparisons with previous…

We have developed an excitation model for small molecules including radiative pumping by dust photons from near infrared to submillimeter wavelengths. This model applies to molecules within bright photodissociation regions in galactic…

Aims. To follow the species chemistry arising in diverse sources of the Galaxy with Herschel. Methods. SPIRE FTS sparse sampled maps of the Orion bar & compact HII regions G29.96-0.02 and G32.80+0.19 have been analyzed. Results. Beyond the…

High quality archival spectra of interstellar absorption from C I toward 9 stars, taken with the Goddard High Resolution Spectrograph on the Hubble Space Telescope, were analyzed. Our sample was supplemented by two sight lines, 23 Ori and…

We report high angular resolution (4.9" x 3.0") images of reactive ions SH+, HOC+, and SO+ toward the Orion Bar photodissociation region (PDR). We used ALMA-ACA to map several rotational lines at 0.8 mm, complemented with multi-line…

SH$^+$ is a surprisingly widespread molecular ion in diffuse interstellar clouds. There, it plays an important role triggering the sulfur chemistry. In addition, SH$^+$ emission lines have been detected at the UV-illuminated edges of dense…

We aim to obtain accurate rate coefficients for the collisional excitation of CH+ by He for high gas temperatures. The ab initio coupled-cluster [CCSD(T)] approximation was used to compute the interaction potential energy. Cross sections…