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We have systematically investigated the annealing effect on the superconductivity of iron chalcogenide Fe1+y(Te1-xSex). The atmospheres used for annealing include O2, N2, I2 vapor, air and vacuum. We observed that annealing in O2, I2 and…

超导电性 · 物理学 2012-11-07 J. Hu , G. C. Wang , B. Qian , Z. Q. Mao

Experimental evidences from transport, magnetic, and magneto-optical (MO) image measurements confirmed that arsenic (As) vapor annealing was another effective way to induce bulk superconductivity with isotropic, large, and homogenous…

To elucidate the mechanism as to why alcoholic beverages can induce superconductivity in Fe_{1+d}Te_{1-x}S_x samples, we performed component analysis and found that weak acid such as organic acid has the ability to induce superconductivity.…

Iron chalcogenide Fe(Te,Se) attracted much attention due to its simple structure, which is favorable for probing the superconducting mechanism. Its less toxic nature compared with iron arsenides is also advantageous for applications of…

The effect of vacuum annealing on superconductivity is investigated in Fe(Se,Te) single crystals. It is found that superconductivity is not enhanced by annealing under high vacuum (~ 10^(-3) Pa) or by annealing in a sealed evacuated quartz…

超导电性 · 物理学 2013-05-14 Seiki Komiya , Masafumi Hanawa , Ichiro Tsukada , Atsutaka Maeda

Superconductivity in anti-PbO-type iron chalcogenides Fe1-xTe1-ySey (x = 0, 0.1, y = 0.1 0.4) depends on the amount (x) of interstitial iron atoms located between the FeTe1-ySey layers. Non-superconducting samples of nominal Fe1.1Te1-ySey…

超导电性 · 物理学 2015-05-25 Gina M. Friederichs , Matthias P. B. Wörsching , Dirk Johrendt

Superconductivity in polycrystalline Fe1+dTe0.9Se0.1 was enhanced by heating in alcoholic beverages. We found that part of the excess Fe was deintercalated from the interlayer sites by the treatment and the shielding volume fractions were…

Effects of iodine annealing to induce bulk superconductivity in Fe1+yTe0.6Se0.4 have been systematically studied by changing the molar ratio of iodine to the sample and annealing temperature. The optimal condition to induce bulk…

超导电性 · 物理学 2016-09-30 Jingting Chen , Yue Sun , Tatsuhiro Yamada , Sunseng Pyon , Tsuyoshi Tamegai

For the Fe-based superconductor Fe{1+y}Te{1-x}S{x}, superconductivity is induced by annealing treatment in oxygen atmosphere, whereas as-grown samples do not show superconductivity. We have investigated the sample-size dependence of…

超导电性 · 物理学 2016-11-23 Teruo Yamazaki , Tatsuya Sakurai , Hiroshi Yaguchi

We reported that bulk superconductivity in Fe$_{1+y}$Te$_{1-x}$Se$_{x}$ can be induced by annealing in Se and S vapor. The well-annealed samples show a large critical current density, emph{J}$_c$ $\sim$ 2 - 4 $\times$ 10$^5$ A/cm$^2$.…

We reported a controllable way of removing excess Fe in Fe1+yTe0.6Se0.4 by annealing in a fixed amount of O2. Compared with the weak superconductivity induced by dilute acids, O2 annealing can successfully induce bulk superconductivity.…

It has been clarified that bulk superconductivity in Fe$_{1+y}$Te$_{0.6}$Se$_{0.4}$ can be induced by annealing in an appropriate atmosphere to remove the harmful effects of excess iron. In order to clarify the details of the annealing…

超导电性 · 物理学 2016-02-03 Tatsuhiro Yamada , Yue Sun , Sunseng Pyon , Tsuyoshi Tamegai

We found that hot alcoholic beverages were effective in inducing superconductivity in FeTe$_{0.8}$S0$_{.2}$. Heating FeTe$_{0.8}$S0$_{.2}$ compound in various alcoholic beverages enhances the superconducting properties compared to pure…

超导电性 · 物理学 2015-05-19 K Deguchi , Y Mizuguchi , Y Kawasaki , T Ozaki , S Tsuda , T Yamaguchi , Y Takano

There are several strategies to discover new superconductors. Growing new materials and applying high pressures can be the classic ways since superconductivity was found. Also, chemical processing, such as annealing, is another way to…

Recent investigations have shown that Fe$_{1+y}$Te$_{1-x}$Se$_{x}$ can be made superconducting by annealing it in Se and O vapors. The current lore is that these chalcogen vapors induce superconductivity by removing the magnetic excess Fe…

We report a detailed study of the Te vapor annealing effect in Fe$_{1+y}$Te$_{0.6}$Se$_{0.4}$ single crystals. Bulk superconductivity can be gradually induced by annealing with increasing amount of Te, until the molar ratio of Te to the…

Superconductivity in FeTe0.8S0.2 is successfully induced by an electrochemical reaction using an ionic liquid solution. A clear correlation between the Fe concentration in the solution and the manifestation of superconductivity was…

We report superconductivity induced in films of the non-superconducting, antiferromagnetic parent material FeTe by low temperature oxygen incorporation in a reversible manner. X-ray absorption shows that oxygen doping changes the nominal Fe…

超导电性 · 物理学 2010-07-26 Yuefeng Nie , Donald Telesca , Joseph I. Budnick , Boris Sinkovic , Barrett O. Wells

In order to clarify the origin of anomalous superconductivity in (Ca,RE)Fe2As2 system, Pr doped and Pr,Co co-doped CaFe2As2 single crystals were grown by the FeAs flux method. These samples showed two-step superconducting transition with…

Since the discovery of superconductivity at 26 K in oxy-pnictide LaFeAsO1-xFx, enormous interests have been stimulated in the field of condensed matter physics and material sciences. Among the many kind of structures in the iron pnictide…

超导电性 · 物理学 2012-07-06 Fei Han , Bing Shen , Zhen-Yu Wang , Hai-Hu Wen
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