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We test the Coulomb exchange and correlation energy density functionals of electron systems for atomic nuclei in the local density approximation (LDA) and the generalized gradient approximation (GGA). For the exchange Coulomb energies, it…

核理论 · 物理学 2018-04-25 Tomoya Naito , Ryosuke Akashi , Haozhao Liang

Guiding by the relativistic local density approximation, we explore a phenomenological formula for the coupling strength of Coulomb field to take into account the Coulomb exchange term effectively in the relativistic Hartree approximation.…

核理论 · 物理学 2013-05-27 Z. M. Niu , Q. Liu , Y. F. Niu , W. H. Long , J. Y. Guo

The energy density functional (EDF) method is very widely used in nuclear physics, and among the various existing functionals those based on the relativistic Hartree (RH) approximation are very popular because the exchange contributions…

核理论 · 物理学 2014-05-16 Nguyen Van Giai , Haozhao Liang , Huai-Qiang Gu , Wenhui Long , Jie Meng

The Coulomb exchange and correlation energy density functionals for electron systems are applied to nuclear systems. It is found that the exchange functionals in the generalized gradient approximation provide agreements with the exact-Fock…

核理论 · 物理学 2019-12-09 Tomoya Naito , Ryosuke Akashi , Gianluca Colò , Haozhao Liang , Xavier Roca-Maza

We develop relativistic short-range exchange energy functionals for four-component relativistic range-separated density-functional theory using a Dirac-Coulomb Hamiltonian in the no-pair approximation. We show how to improve the short-range…

化学物理 · 物理学 2020-06-24 Julien Paquier , Emmanuel Giner , Julien Toulouse

Effects of the relativistic correction of the Coulomb interaction on doubly-magic nuclei are discussed with Skyrme Hartree--Fock calculations. The relativistic correction is treated by using the local density approximation. It is found that…

核理论 · 物理学 2022-09-28 Tomoya Naito

We lay out the extension of range-separated density-functional theory to a four-component relativistic frame-work using a Dirac-Coulomb-Breit Hamiltonian in the no-pair approximation. This formalism combines a wave-function method for the…

化学物理 · 物理学 2018-12-12 Julien Paquier , Julien Toulouse

The non-relativistic large-$Z$ expansion of the exchange energy of neutral atoms provides an important input to modern non-empirical density functional approximations. Recent works report results of fitting the terms beyond the dominant…

化学物理 · 物理学 2023-10-09 Jeremy J. Redd , Antonio C. Cancio , Nathan Argaman , Kieron Burke

We study non-linear adiabatic connection paths in density-functional theory using modified electron-electron interactions that perform a long-range/short-range separation of the Coulomb interaction. These adiabatic connections allows to…

化学物理 · 物理学 2009-11-11 Julien Toulouse , Francois Colonna , Andreas Savin

By splitting the Coulomb interaction into long-range and short-range components, we decompose the energy of a quantum electronic system into long-range and short-range contributions. We show that the long-range part of the energy can be…

化学物理 · 物理学 2009-11-10 Julien Toulouse , Francois Colonna , Andreas Savin

We present a local density approximation (LDA) for one-dimensional (1D) systems interacting via the soft-Coulomb interaction based on quantum Monte-Carlo calculations. Results for the ground-state energies and ionization potentials of…

强关联电子 · 物理学 2015-05-27 N. Helbig , J. I. Fuks , M. Casula , M. J. Verstraete , M. A. L. Marques , I. V. Tokatly , A. Rubio

We construct and apply an exchange-correlation functional for the one-dimensional Hubbard model. This functional has built into it the Luttinger-liquid and Mott-insulator correlations, present in the Hubbard model, in the same way in which…

强关联电子 · 物理学 2007-05-23 K. Capelle , N. A. Lima , M. F. Silva , L. N. Oliveira

Attempts to go beyond the local density approximation (LDA) of Density Functional Theory (DFT) have been increasingly based on the incorporation of more realistic Coulomb interactions. In their earliest implementations, methods like…

强关联电子 · 物理学 2009-11-13 Jean-Pierre Julien , Jian-Xin Zhu , Robert C. Albers

For closed-shell systems, the local density approximation (LDA) and the LYP, BLYP, and B3LYP functionals are shown to be compatible with reference-state one-particle density-matrix theory, where this recently introduced formalism is based…

化学物理 · 物理学 2009-11-10 James P. Finley

We discuss a possible form for a theory akin to local density functional theory, but able to produce van der Waals energies in a natural fashion. The usual Local Density Approximation (LDA) for the exchange and correlation energy $E_{xc}$…

软凝聚态物质 · 物理学 2007-05-23 John F. Dobson

Time dependent quantum systems are the subject of intense inquiry, in mathematics, science, and engineering, particularly at the atomic and molecular levels. In 1984, Runge and Gross introduced time dependent density functional theory…

偏微分方程分析 · 数学 2021-02-24 Joseph W. Jerome

Local density approximation for the exchange energy is made for treatment of excited-states in density-functional theory. It is shown that taking care of the state-dependence of the LDA exchange energy functional leads to accurate…

其他凝聚态物理 · 物理学 2007-05-23 Manoj K. Harbola , Prasanjit Samal

Within density-functional theory, the local-density approximation (LDA) correlation functional is typically built by fitting the difference between the near-exact and Hartree-Fock (HF) energies of the uniform electron gas (UEG), together…

化学物理 · 物理学 2017-05-01 Fergus J. M. Rogers , Caleb J. Ball , Pierre-François Loos

Standard approximations for the exchange-correlation (XC) functional in Kohn-Sham density functional theory (KS-DFT) typically lead to unacceptably large errors when applied to strongly-correlated electronic systems. Partition-DFT (PDFT) is…

化学物理 · 物理学 2023-09-12 Yi Shi , Yuming Shi , Adam Wasserman

A widely used approximation to the exchange-correlation functional in density functional theory is the local density approximation (LDA), typically derived from the properties of the homogeneous electron gas (HEG). We previously introduced…

其他凝聚态物理 · 物理学 2018-06-27 Mike Entwistle , Michele Casula , Rex Godby
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