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Photoassociation of two ultracold rubidium atoms and the subsequent formation of stable molecules in the singlet ground and lowest triplet states is investigated theoretically. The method employs laser pulses inducing transitions via…

原子物理 · 物理学 2007-05-23 Christiane P. Koch , Ronnie Kosloff , Françoise Masnou-Seeuws

Photoassociation of ultracold atoms is shown to lead to alignment of the product molecules along the excitation laser polarization axis. We theoretically investigate pulsed photoassociation of $^{87}Rb$ atoms into a specific weakly-bound…

量子物理 · 物理学 2017-11-15 S. Kallush , J. L. Carini , P. L. Gould , R. Kosloff

We propose an improved photoassociation scheme to produce ultracold molecules in their vibronic ground state for the generic case where non-adiabatic effects facilitating transfer to deeply bound levels are absent. Formation of molecules is…

原子物理 · 物理学 2008-10-28 Christiane P. Koch , Robert Moszynski

In recent experiments on ultracold matter, molecules have been produced from ultracold atoms by photoassociation, Feshbach resonances, and three-body recombination. The created molecules are translationally cold, but vibrationally highly…

量子物理 · 物理学 2007-05-23 Christiane P. Koch , José P. Palao , Ronnie Kosloff , Françoise Masnou-Seeuws

We investigate computationally a method for ultrafast preparation of alkali metal atoms in their Rydberg states using a three-dimensional model potential in the single active electron approximation. By optimizing laser pulse shapes that can…

原子物理 · 物理学 2018-11-21 Janne Solanpää ja Esa Räsänen

This theoretical paper investigates the formation of ground state molecules from ultracold cesium atoms in a two-color scheme. Following previous work on photoassociation with chirped picosecond pulses [Luc-Koenig et al., Phys. Rev. A {\bf…

原子物理 · 物理学 2007-05-23 Christiane P. Koch , Eliane Luc-Koenig , Françoise Masnou-Seeuws

We have studied the formation of ultracold RbSr molecules with laser pulses. After discussing the advantages of the Mott insulator phase for the control with pulses, we present two classes of strategies. The first class involves two…

Using resonance-enhanced two-photon ionization, we detect ultracold, ground-state RbCs molecules formed via photoassociation in a laser-cooled mixture of 85Rb and 133Cs atoms. We obtain extensive bound-bound excitation spectra of these…

原子物理 · 物理学 2009-11-10 Andrew J. Kerman , Jeremy M. Sage , Sunil Sainis , Thomas Bergeman , David DeMille

We consider the formation of cold ground-state polar molecules in a low vibrational level by laser fields. Starting from a pair of cold colliding atoms of dissimilar species, we propose a strategy consisting of three steps. In the first…

原子物理 · 物理学 2026-01-14 Emanuel F. de Lima

The transfer of weakly bound KRb molecules from levels just below the dissociation threshold into the vibrational ground state with shaped laser pulses is studied. Optimal control theory is employed to calculate the pulses. The complexity…

原子物理 · 物理学 2011-04-15 Mamadou Ndong , Christiane P. Koch

We report an ultrafast and efficient way to create the maximum coherence between the two lower states in a -like atomic systems, driven by two nonlinearly chirped few-cycle pulses. The phenomenon of coherent population trapping and…

量子物理 · 物理学 2011-11-18 Amarendra K. Sarma , Parvendra Kumar

We demonstrate the production of ultracold polar RbCs molecules in their vibronic ground state, via photoassociation of laser-cooled atoms followed by a laser-stimulated state transfer process. The resulting sample of $X ^1\Sigma^+ (v=0)$…

原子物理 · 物理学 2009-11-11 J. M. Sage , S. Sainis , T. Bergeman , D. DeMille

We report on the creation of ultracold 84Sr2 molecules in the electronic ground state. The molecules are formed from atom pairs on sites of an optical lattice using stimulated Raman adiabatic passage (STIRAP). We achieve a transfer…

量子气体 · 物理学 2012-09-18 Simon Stellmer , Benjamin Pasquiou , Rudolf Grimm , Florian Schreck

Chemical reactions can be surprisingly efficient at ultracold temperatures ( < 1mK) due to the wave nature of atoms and molecules. The study of reactions in the ultracold regime is a new research frontier enabled by cooling and trapping…

原子物理 · 物理学 2017-01-16 Lee R. Liu , Jessie T. Zhang , Yichao Yu , Nicholas R. Hutzler , Yu Liu , Till Rosenband , Kang-Kuen Ni

We analyze the formation of Rb_2 molecules with short photoassociation pulses applied to a cold Rb-85 sample. A pump laser pulse couples a continuum level of the ground electronic state X ^1\Sigma_{g}^+ with bound levels in the 0_{u}^+…

原子物理 · 物理学 2007-06-22 Jordi Mur-Petit , Eliane Luc-Koenig , Françoise Masnou-Seeuws

Photoassociation of ultracold atoms induced by chirped picosecond pulses is analyzed in a non-perturbative treatment by following the wavepackets dynamics on the ground and excited surfaces. The initial state is described by a Boltzmann…

原子与分子团簇 · 物理学 2009-06-10 Eliane Luc-Koenig , Mihaela Vatasescu , Francoise Masnou-Seeuws

This theoretical paper presents numerical calculations for photoassociation of ultracold cesium atoms with a chirped laser pulse and detailed analysis of the results. In contrast with earlier work, the initial state is represented by a…

原子与分子团簇 · 物理学 2009-11-10 E. Luc-Koenig , R. Kosloff , F. Masnou-Seeuws , M. Vatasescu

We have studied the effect of resonant electronic state coupling on the formation of ultracold ground-state $^{85}$Rb$_2$. Ultracold Rb$_2$ molecules are formed by photoassociation (PA) to a coupled pair of $0_u^+$ states, $0_u^+(P_{1/2})$…

原子物理 · 物理学 2008-10-31 H. K. Pechkis , D. Wang , Y. Huang , E. E. Eyler , P. L. Gould , W. C. Stwalley , C. P. Koch

Ultracold ground-state molecules can be formed from ultracold atoms via photoassociation followed by a spontaneous emission process. Typically, the molecular products are distributed over a range of final states. Here, we propose to use an…

量子物理 · 物理学 2018-12-20 Tobias Kampschulte , Johannes Hecker Denschlag

We have produced ultracold, polar RbCs* molecules via photoassociation in a laser-cooled mixture of Rb and Cs atoms. Using a model of the RbCs* molecular interaction which reproduces the observed rovibrational structure, we infer decay…

原子物理 · 物理学 2009-11-10 Andrew J. Kerman , Jeremy M. Sage , Sunil Sainis , David DeMille , Thomas Bergeman
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