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The influence of multiple vibrational modes on current fluctuations in electron transport through single-molecule junctions is investigated. Our analysis is based on a generic model of a molecular junction, which comprises a single…

介观与纳米尺度物理 · 物理学 2014-09-26 C. Schinabeck , R. Härtle , H. B. Weber , M. Thoss

It is often intriguing experimentally to take stock of how conformational changes in the device configuration may impact the overall charge transport behavior of single-molecule junctions. Based on the allied approach of density functional…

介观与纳米尺度物理 · 物理学 2020-02-06 Talem Rebeda Roy , Arijit Sen

We carry out experiments on single-molecule junctions at low temperatures, using the mechanically controlled break junction technique. Analyzing the results received with more than ten different molecules the nature of the first peak in the…

介观与纳米尺度物理 · 物理学 2012-03-21 Daniel Secker , Stefan Wagner , Stefan Ballmann , Rainer Härtle , Michael Thoss , Heiko B. Weber

This thesis investigates the mechanically controlled break junctions, with a particular emphasis on elucidating the behaviour of molecular currents at room temperature. The core of this experimental investigation involves a detailed…

介观与纳米尺度物理 · 物理学 2024-09-17 Giovanna Angelis Schmidt

We report on inelastic electron tunneling spectroscopy measurements carried out on single molecules incorporated into a mechanically controllable break-junction of Au and Pt electrodes at low temperature. Here we establish a correlation…

介观与纳米尺度物理 · 物理学 2010-11-16 Youngsang Kim , Hyunwook Song , Florian Strigl , Hans-Fridtjof Pernau , Takhee Lee , Elke Scheer

Non-equilibrium Green's functions (NEGF) formalism combined with extended Huckel (EHT) and charging model are used to study electrical conduction through single-molecule junctions. Analyzed molecular complex is composed of asymmetric…

介观与纳米尺度物理 · 物理学 2009-11-11 Kamil Walczak , Sergey Edward Lyshevski

Single molecule junctions exhibit dynamic structural configurations that strongly influence their electronic and thermoelectric properties. Here, we combine conductance (G) and Seebeck coefficient (S) measurements using the novel AC based…

The effect of vibrational motion on resonant charge transport through single molecule junctions is investigated. The study is based on a combination of first-principles electronic structure calculations to characterize the system and…

其他凝聚态物理 · 物理学 2007-12-24 Claudia Benesch , Martin Cizek , Jiri Klimes , Michael Thoss , Wolfgang Domcke

We have studied the $1/f$ voltage noise of gold nano-contacts in electromigrated and mechanically controlled break-junctions having resistance values $R$ that can be tuned from 10 $\Omega$ (many channels) to 10 k$\Omega$ (single atom…

介观与纳米尺度物理 · 物理学 2014-01-03 ZhengMing Wu , SongMei Wu , S. Oberholzer , M. Steinacher , M. Calame , C. Schönenberger

This mini review focuses on conductance measurements through molecular junctions containing few tens of molecules, which are fabricated along two approaches: (i) conducting atomic force microscope contacting a self-assembled monolayers on…

应用物理 · 物理学 2019-11-12 Dominique Vuillaume

We measure the low bias conductance of a series of substituted benzene diamine molecules while breaking a gold point contact in a solution of the molecules. Transport through these substituted benzenes is by means of nonresonant tunneling…

We present an original method to estimate the conductivity of a single molecule anchored to nanometric-sized metallic electrodes, using a Mechanically Controlled Break Junction (MCBJ) operated at room temperature in liquid. We record the…

介观与纳米尺度物理 · 物理学 2018-03-16 M. Gil , T. Malinowski , M. Iazykov , H. Klein

It is shown, with citing tunnel junction as an example, that mutual interplay of electron quantum transfers in a conducting system can be the fast mechanism for generation fundamental low-frequency flicker conductance fluctuations (1/f…

统计力学 · 物理学 2007-05-23 Yu. E. Kuzovlev , Yu. V. Medvedev , A. M. Grishin

Quantum transport through single molecules is very sensitive to the strength of the molecule-electrode contact. Here, we investigate the behavior of a model molecular junction weakly coupled to external electrodes in the case where charging…

介观与纳米尺度物理 · 物理学 2009-11-11 Bo Song , Dmitry A. Ryndyk , Gianaurelio Cuniberti

Using first-principles calculations based on density functional theory combined with the non-equilibrium Green's function approach, the transport behaviors of a single-molecule junction formed by benzenedithiol connected to gold electrodes…

材料科学 · 物理学 2022-09-20 Rigao Wang , Feng Shuang , Xiaowen Shi , Mingyan Chen

Vibronic effects in resonant electron transport through single-molecule junctions are analyzed. The study is based on generic models for molecular junctions, which include electronic states on the molecular bridge that are vibrationally…

介观与纳米尺度物理 · 物理学 2011-03-15 R. Härtle , M. Thoss

We consider charge transport through a nanoscopic object, e.g. single molecules, short nanotubes, or quantum dots, that is weakly coupled to metallic electrodes. We account for several levels of the molecule/quantum dot with level-dependent…

介观与纳米尺度物理 · 物理学 2007-05-23 A. Thielmann , M. H. Hettler , J. König , G. Schön

In this contribution we demonstrate structural control over a transport resonance in HS(CH$_{2}$)$_{n}$[1,4 - C$_{6}$H$_{4}$](CH$_{2}$)$_{n}$SH (n = 1, 3, 4, 6) metal - molecule - metal junctions, fabricated and tested using the scanning…

介观与纳米尺度物理 · 物理学 2015-06-04 Carly Brooke , Andrea Vezzoli , Simon J. Higgins , Linda A. Zotti , J. J. Palacios , Richard J. Nichols

We have investigated the transport and noise properties of submicron YBCO bicrystal grain-boundary junctions prepared using electron beam lithography. The junctions show an increased conductance for low voltages reminiscent of Josephson…

超导电性 · 物理学 2009-10-31 F. Herbstritt , T. Kemen , L. Alff , A. Marx , R. Gross

The characteristics of molecular electronic devices are critically determined by metal-organic interfaces, which influence the arrangement of the orbital levels that participate in charge transport. Studies on self-assembled monolayers…

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