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A series of sigma-phase Fe_{100-x}V_x samples with 34.4 < x < 59.0 were investigated by neutron and X-ray diffraction and Mossbauer spectroscopy (MS) techniques. The first two methods were used for verification of the transformation from…

Sigma-phase Fe65.9V34.1 alloy was investigated with the M\"ossbauer spectroscopy. M\"ossbauer spectra were recorded in the temperature interval of 80-300 K. Their analysis in terms of the hyperfine distribution protocol yielded the average…

强关联电子 · 物理学 2016-01-05 J. Żukrowski , S. M. Dubiel

Debye temperature, $\Theta_D$, of Fe-rich Fe$_{100-x}$Cr$_x$ disordered alloys with $0\le x \le 22.3$ was determined from the temperature dependence of the central shift of M\"ossbauer spectra recorded in the temperature range of 60 -- 300…

材料科学 · 物理学 2010-02-17 B. F. O. Costa , J. Cieslak , S. M. Dubiel

Debye temperature, TD, of Fe100-xCrx disordered alloys with 0<x<99.9 was determined from the temperature dependence of the centre shift of 57Fe Mossbauer spectra recorded in the temperature range of 80-300K. Its compositional dependence…

材料科学 · 物理学 2010-01-19 S. M. Dubiel , J. Cieslak , B. F. O. Costa

A very simple method for determining the center (isomer) shift, CS, of a M\"ossbauer spectrum is outlined. Its applicability is demonstrated on two examples viz. pyrite and a ternary sigma-phase Fe-Cr-Ni compound. Sets of the spectra…

强关联电子 · 物理学 2022-07-05 Stanisław M. Dubiel , Jan Żukrowski

A very simple method for determining the center (isomer) shift, CS, and the spectral area, A, of a M\"ossbauer spectrum is outlined. Its applicability is demonstrated in two examples viz. pyrite and a ternary sigma-phase Fe-Cr-Ni compound.…

其他凝聚态物理 · 物理学 2022-09-05 Stanisław M. Dubiel , Jan Żukrowski

Single-crystals of Cr and Cr3%Mn doped with ca. 0.2 at.% 119Sn were studied by means of 119Sn-site M\"ossbauer spectroscopy. M\"ossbauer spectra recorded in the temperature range of 78-300 K were analyzed using a hyperfine field…

强关联电子 · 物理学 2019-08-30 Stanisław M. Dubiel , Jan Żukrowski

A series on nanocrystalline Fe100-xCrx alloys prepared by mechanical alloying was investigated with X-ray diffraction (XRD), scanning electron microscopy (SEM) and M\"ossbauer spectroscopy (MS) techniques. XRD and SEM were used to…

强关联电子 · 物理学 2015-08-10 S. M. Dubiel , B. F. O. Costa , J. Cieslak , A. C. Batista

Fe-gluconate was studied by means of the M\"ossbauer spectroscopy in the temperature interval of 80-305K. The measured spectra were analyzed in terms of two subspectra and, alternatively, two distributions of the quadrupole splitting. The…

材料科学 · 物理学 2016-03-01 S. M. Dubiel , J. Cieslak

Binding of 57Fe atoms in a metallic chromium was investigated in a Cr-Fe alloy, containing less than 0.1 at% Fe enriched to ~95 % in 57Fe isotope, using 57Fe-site Mossbauer spectroscopy. The binding force was derived from the Debye…

材料科学 · 物理学 2011-02-17 S. M. Dubiel , J. Zukrowski , J. Cieslak

Magnetic properties of four sigma-phase Fe_(100-x)V_x samples with 34.4<x<55.1 were investigated by Mossbauer spectroscopy and magnetic measurements in the temperature interval 5-300 K. Four magnetic quantities viz. hyperfine field, Curie…

Sigma-phase Fe0.525Cr0.455Ni0.020 alloy was studied by means of M\"ossbauer spectrometry in the temperature range of 5-293 K. The average center shift, <CS>, determined from the recorded M\"ossbauer spectra was shown to significantly…

强关联电子 · 物理学 2022-03-04 Stanisław M. Dubiel , Jan Żukrowski

C14 Laves phase Nb0.975Fe2.025 compound was investigated by means of the M\"ossbauer spectroscopy. Spectra were recorded in the temperature range of 5-300K. Their analysis in terms of three sub spectra yielded information on magnetic and…

强关联电子 · 物理学 2018-07-03 Jan Żukrowski , Stanislaw M. Dubiel

We report measurements of 57Fe Mossbauer spectra for RFe2Zn20 ( R = Lu, Yb, Gd) from ~ 4.5 K to room temperature. The obtained isomer shift values are very similar for all three compounds, their temperature dependence was analyzed within…

材料科学 · 物理学 2015-09-02 Sergey L. Bud'ko , Tai Kong , Xiaoming Ma , Paul C Canfield

With the advent of Fe-As based superconductivity it has become important to study how superconductivity manifests itself in details of 57Fe Mossbauer spectroscopy of conventional, Fe - bearing superconductors. To this end, the iron-based…

材料科学 · 物理学 2015-08-07 Xiaoming Ma , Sheng Ran , Hua Pang , Fashen Li , Paul C. Canfield , Sergey L. Bud'ko

The Debye temperature, T${_\theta}$=(h/2${\pi}$)/k${_B}$$\omega$$_\theta$, where the Debye frequency $\omega$$_\theta$ is integrated characteristic frequency of full phonon spectrum, $\alpha$$^2$($\omega$)F($\omega$). In the BCS theory,…

超导电性 · 物理学 2020-08-04 E. F. Talantsev

Two intermetallic FeAl compounds with Al content of 70.68 and 72.17 at.pct were studied using M\"ossbauer spectroscopy (5 to 296 K) and X-ray diffraction (15 to 300 K). The compounds were found to crystallize in the orthorhombic Cmcm space…

材料科学 · 物理学 2021-05-19 Stanisław M. Dubiel , Łukasz Gondek , Tilo Zienert , Jan Żukrowski

A review is presented on physical properties of the sigma-phase in Fe-Cr and Fe-V alloy systems as revealed both with experimental -- mostly with the Mossbauer spectroscopy -- and theoretical methods. In particular, the following questions…

材料科学 · 物理学 2012-01-06 Stanislaw M Dubiel , Jakub Cieslak

We report mainly the heat capacity and Mossbauer study of self flux grown FeTe single crystal, which is ground state compound of the Fe chalcogenides superconducting series, i.e., FeTe1-x(Se/S)x. The as grown FeTe single crystal is large…

超导电性 · 物理学 2018-05-31 P. K Maheshwari , V. Raghavendra Reddy , V. P. S. Awana

Measurements of the specific heat of Mg ^{11}B_2 (MgB2), from 1 to 50 K, in magnetic fields to 9 T, give the Debye temperature, $\Theta$ = 1050 K, the coefficient of the normal-state electron contribution, $\gamma_n$ = 2.6 mJ mol^{-1}…

超导电性 · 物理学 2009-11-07 F. Bouquet , R. A. Fisher , N. E. Phillips , D. G. Hinks , J. D. Jorgensen
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