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The single-crystal growth, stoichiometry, and structure of Rb1-xFe2-ySe2-zSz crystals with substitution of Se by S are reported. The variation of the magnetic and thermodynamic parameters of samples was studied by differential-scanning…

Here, we report the synthesis and characterization of sulphur-substituted iron telluride i.e. FeTe1-xSx; (x = 0-30 %) system and study the impact of low temperature oxygen (O2) annealing as well. Rietveld analysis of room temperature x-ray…

超导电性 · 物理学 2015-05-19 V. P. S. Awana , Anand Pal , Arpita Vajpayee , Bhasker Gahtori , H. Kishan

We have carried out a systematic study of the PbO-type compound FeSe_{1-x}Te_x (x = 0~1), where Te substitution effect on superconductivity is investigated. It is found that superconducting transition temperature reaches a maximum of…

We have synthesized polycrystalline samples and single crystals of Fe(Te1-xSx)y, and characterized their properties. Our results show that the solid solution of S in this system is limited, < 30%. We observed superconductivity at ~ 9 K in…

超导电性 · 物理学 2008-11-24 M. H. Fang , B. Qian , H. M. Pham , J. H. Yang , T. J. Liu , E. K. Vehstedt , L. Spinu , Z. Q. Mao

The magnetism in SrFe2As2 can be suppressed by electron doping through a small substitution of Fe by Co or Ni, giving way to superconductivity. We demonstrate that a massive substitution of Fe by isovalent ruthenium similarly suppresses the…

超导电性 · 物理学 2009-06-16 W. Schnelle , A. Leithe-Jasper , R. Gumeniuk , U. Burkhardt , D. Kasinathan , H. Rosner

We report the first experimental evidence for the intimate connection between superconductivity and antiferromagnetism in Rb0.8Fe2Se2-xTex single crystal under negative chemical pressure by substituting Se with isovalent Te atoms.…

超导电性 · 物理学 2012-05-25 Dachun Gu , Liling Sun , Qi Wu , Chao Zhang , Jing Guo , Peiwen Gao , Yue Wu , Xiaoli Dong , Xi Dai , Zhongxian Zhao

We investigated the evolution of the temperature-composition phase diagram of Fe$_{1+y}$Te upon Se substitution. In particular, the effect of Se substitution on the two-step, coupled magneto-structural transition in Fe$_{1+y}$Te single…

超导电性 · 物理学 2015-05-12 Dona Cherian , S. Rößler , S. Wirth , Suja Elizabeth

The Fe-based superconducting KxFe2-ySe2 (0.6 {\leg} x {\leg} 1, 0.2{\leg} y {\leg} 0.4) compounds, unlike the well-known RFe2As2 (R = Ba, Sr, Ca) superconductors, contain complex structural features and notable physical properties, such as…

超导电性 · 物理学 2011-04-29 J. Q. Li , Y. J. Song , H. X. Yang , Z. Wang , H. L. Shi , G. F. Chen , Z. W. Wang , Z. Chen , H. F. Tian

We report superconductivity, physical and structural properties of Ir1-xRhxTe2 (0<=x<=0.3). Superconducting transition with maximum Tc~2.6 K appears when the doping content of Rh x is in between 0.15 and 0.3. Further increasing the content…

超导电性 · 物理学 2013-07-29 Hechang Lei , Kefeng Wang , Milinda Abeykoon , Emil Bozin , J. B. Warren , C. Petrovic

[(Li0.8Fe0.2)OH]FeS and the series [(Li0.8Fe0.2)OH]Fe(S1-xSex) (0<x<1) were synthesized by hydrothermal methods and characterized by X-ray single crystal and powder diffraction, EDX and chemical analysis. Selenium-rich compounds show the…

超导电性 · 物理学 2015-03-04 Ursula Pachmayr , Dirk Johrendt

We report the evolution of thermal transport properties of iron-based superconductor K$_x$Fe$_{2-y}$Se$_2$ with sulfur substitution at Se sites. Sulfur doping suppresses the superconducting $T_c$ as well as the Seebeck coefficient. The…

超导电性 · 物理学 2015-05-28 Kefeng Wang , Hechang Lei , C. Petrovic

The influence of a partial substitution with sulphur into Te sites on the crystal, electronic and magnetic structures of FeTe is investigated by DFT calculations. The results reveal a phase transition from the antiferromagnetic…

超导电性 · 物理学 2015-01-26 A. Ciechan , M. J. Winiarski , M. Samsel-Czekała

We report our study of the evolution of superconductivity and the phase diagram of the ternary Fe(Se1-xTex)0.82 (0<=x<=1.0) system. We discovered a new superconducting phase with Tc,max = 14 K in the 0.3 < x < 1.0 range. This…

超导电性 · 物理学 2008-12-04 M. H. Fang , H. M. Pham , B. Qian , T. J. Liu , E. K. Vehstedt , Y. Liu , L. Spinu , Z. Q. Mao

We report the evolution of superconductivity and the phase diagram of the KxFe2-ySe2-zTez (z=0-0.6) crystals grown by a simple one-step synthesis. No structural transition is observed in any crystals, while lattice parameters exhibit a…

We have synthesized tetragonal iron selenide and telluride superconductors through solid state reaction at 450deg.C and 550deg.C respectively. These synthesis temperatures have been established by optimization. Electrical resistivity and…

Very recently (November, 2010, PRB, 82, 180520R), the first ThCr2Si2-type ternary superconductor K0.8Fe2Se2 with enhanced TC ~ 31 K has been discovered. This finding has stimulated much activity in search for related materials and triggered…

材料科学 · 物理学 2015-05-27 A. L. Ivanovskii

The superconducting and magnetic properties of Fe$_{y}$Se$_{0.25}$Te$_{0.75}$ single crystals ($0.9\leq y \leq1.1$) were studied by means of x-ray diffraction, SQUID magnetometry, muon spin rotation, and elastic neutron diffraction. The…

The effect of atomic substitution of Te in iron based superconductors FeSe (1:1 type), which exhibits the simplest crystal structure among the iron-based superconductors, has been investigated in terms of structural, electronic transport…

超导电性 · 物理学 2012-12-21 Muammer Yasin Hacisalihoglu , Ekrem Yanmaz

The influence of uniform pressures $P$ up to 5 kbar on the superconducting transition temperature $T_c$ was studied for the FeSe$_{1-x}$Te$_x$ ($x=0$, 0.85, 0.88 and 0.9) system. For the first time, we observed a change in sign of the…

CuAl2-type transition-metal (Tr) zirconides are superconductor family, and the Tr-site element substitution largely modifies its transition temperature (Tc). Here, we synthesized polycrystalline samples of Fe1-xNixZr2 by arc melting. From…

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