相关论文: Gas-grain models for interstellar anion chemistry
We present observational evidences that dust in the circumnuclear region of AGNs has different properties than in the Galactic diffuse interstellar medium. By comparing the reddening of optical and infrared broad lines and the X-ray…
The association reaction S + CO {\to} OCS + hnu has been identified as being particularly important for the prediction of gas-phase OCS abundances by chemical models of dark clouds. We performed detailed ab-initio calculations for this…
We use a high-temperature chemical network to derive the molecular abundances in axisymmetric accretion disk models around active galactic nuclei (AGNs) within 100 pc using simple radial and vertical density and temperature distributions…
We address disequilibrum abundances of some simple molecules in the atmospheres of solar composition brown dwarfs and self-luminous extrasolar giant planets using a kinetics-based 1D atmospheric chemistry model. Our approach is to use the…
We use Green Bank Ammonia Survey observations of NH$_3$ (1,1) and (2,2) emission with 32'' FWHM resolution from a ~ 10 pc$^{2}$ portion of the Cepheus-L1251 molecular cloud to identify hierarchical dense gas structures. Our dendrogram…
New SiO multi-transition millimetre line observations of a sample of carbon stars, including J=8-7 observations with the APEX telescope, are used to probe the role of non-equilibrium chemistry and the influence of grains in circumstellar…
We revisit the question of the ionization of the diffuse medium in late type galaxies, by studying NGC 891, the prototype of edge-on spiral galaxies. The most important challenge for the models considered so far was the observed increase of…
The formation of anionic species in the interstellar medium from interaction of linear molecules containing carbon, nitrogen and hydrogen as atomic components (polyynes) with free electrons in the environment is modelled via a quantum…
We present a millimetre molecular line survey of seven high mass loss rate carbon stars in both the northern and southern skies. A total of 196 emission lines (47 transitions) from 24 molecular species were detected. The observed CO…
We use spectra and maps of NH2D, ND2H, and ND3, obtained with the CSO, IRAM 30m and Arecibo telescopes, to study deuteration processes in dense cores. The data include the first detection of the hyperfine structure of ND2H. The emission of…
CO is thought to be the main reservoir of volatile carbon in protoplanetary disks, and thus the primary initial source of carbon in the atmospheres of forming giant planets. However, recent observations of protoplanetary disks point towards…
We constrain the iron abundance in a sample of 33 low-ionization Galactic planetary nebulae (PNe) using [Fe III] lines and correcting for the contribution of higher ionization states with ionization correction factors (ICFs) that take into…
In a companion paper, Maiolino et al. (2000) presented various observational evidences for "anomalous" dust properties in the circumnuclear region of AGNs and, in particular, the reduced E(B-V)/N_H and Av/N_H ratios, the absence of the…
The physical conditions of the earliest environment of high-mass star formation are currently poorly understood. To that end, we present observations of the carbon chain molecules HC$_5$N , CCS, and HC$_7$N in the 22-25 GHz band towards 12…
We present an extensive review of gas phase reactions producing methylacetylene and propene showing that these relatively abundant unsaturated hydrocarbons cannot be synthesized through gas-phase reactions. We explain the formation of…
(Abridged) We aim to enlarge the number of known hot corinos and carry out a first comparative study with hot cores. The ultimate goal is to understand whether complex organic molecules form in the gas phase or on grain surfaces, and what…
We have designed an improved algorithm that enables us to simulate the chemistry of cold dense interstellar clouds with a full gas-grain reaction network. The chemistry is treated by a unified microscopic-macroscopic Monte Carlo approach…
A combined mid-IR spectrum of five colliding-wind, massive, dust-producing Population I Wolf-Rayet (WR) binaries shows a wealth of absorption and emission details coming from the circumstellar dust envelopes, as well as from the…
The nitrogen chemical evolution during star and planet formation is still not fully understood. Ammonia (NH$_3$) is a key specie in the understanding of the molecular evolution in star-forming clouds and nitrogen isotope fractionation. In…
We investigate the formation of the recently detected HNSO molecule using quantum chemical calculations on ices and astrochemical models in tandem. Our results indicate that HNSO is efficiently produced on grain surfaces through reactions…